Abstract
The adsorption of a molecule is the first step in the modification of the mechanical properties of a metal by the environment. Once adsorbed, the molecule can play a number of different roles that are relevant to the phenomena of fracture. It can react with the surface to form a coherent and stable layer that protects the solid from further influence from the environment; it can react with the solid to corrode it. This reaction can be activated by mechanical energy stored in locally enhanced stresses and lead to stress corrosion cracking. Hydrogen can dissociate and penetrate the metal and lead to hydrogen embrittlement. The molecule can displace from the surface, or react with, a potentially harmful adsorbate and stop the environmental degradation of the solid. Thus, the study of the physical and chemical interaction of fluids with solid surfaces is of importance to the understanding of environment effects on the fracture of a material under stress.
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References
T. E. Fischer in “Surface Effects in Crystal Plasticity,” R. M. Latanision and J. T. Fourie eds. Noordhoff Leyden, (1977), p. 127.
Z. L. Liau, B. Y. Tsaur and J. W. Mayer, J. Vac. Sei. Technol, 16: 121 (1979).
D. M. Heyes, M. Barber and J. H. R. Clarke, Surface Sci. 105: 225 (1981).
P. Williams, C. A. Evans Jr., M. L. Grosbeck and H. K. Birnbaum, Phys. Stat. Sol. A34: K97 (1976).
See for instance: “Methods and Phenomena: Methods of Surface Analysis,” S. P. Wolsky and A. W. Czanderna eds., McGraw Hill, New York (1975).
G. Dearnaley, in “Ion Implantation Metallurgy,” C. M. Preece and J. K. Hirvonen eds., AIME, New York (1980).
“Ion Beam Handbook for Material Analysis,” J. W. Mayer and E. Rimini eds., Academic Press (1977).
P. A. Redhead, Vacuum 12: 208 (1962).
J. L. Falconer and R. J. Madix, J. Cat. 48: 262 (1977).
“Channeling,” D. V. Morgan ed., J. Wiley and Sons, New York, (1973).
W. C. Turkenburg, W. Soszka, F. W. Saris, H. H. Kersten and B. G. Colenbranner, Nucl. Inst, and Meth. 132: 587 (1976).
W. C. Turkenburg Doctoral Thesis, Univ. Amsterdam (1976).
D. E. Sayers, F. W. Lytle and E. A. Stern, Phys. Rev. Lett. 27:1204 (1971), D. E. Sayers, E. A. Stern and F. W. Lytle, Phys. Rev. B35: 584 (1975).
J. H. Sinfelt, G. H. Via and F. W. Lytle, J. Chem. Phys. 72: 4832 (1980).
P. H. Citrin, P. Eisenberger and R. C. Hewitt, Phys. Rev. Lett. 45: 1948 (1980).
“Handbook of X-Ray and Ultraviolet Photoelectron Spectroscopy” D. Briggs ed., Heyden, London (1977).
H. Ibach in: Advances in Solid State Physics, Vol. 11 Pergamon (1971). H. Ibach, H. Hopster and B. Sexton, Appl. Surface Sei 1:1 (1977), H. Ibach, J. Vacuum Sei. Technol 15:407 (1978).
A. M. Bradshaw and F. M. Hoffmann, Surface Sci 72: 513 (1978).
“Ion Implantation Metallurgy,” C. M. Preece and J. K. Hirvonen eds., The Metall. Soc. of AIME, New York, (1980).
“Treatise on Materials Science and Technology, Vol. 18 Ion Implantation” J. K. Hirvonen ed., Academic Press, New York (1980).
K. M. Ho, M. L. Cohen and M. Schlüter, Phys. Rev. B15: 3999 (1977).
S. G. Louie, Phys. Rev. Lett. 42: 476 (1979).
K. H. Johnson, Int. J. Quantum Chem. 11:39 (1977), also these proceedings.
C. L. Briant and R. P. Messmer, Phil. Mag. 342: 569 (1980).
C. F. Melius, B. D. Olafson and W. A. Goddard III., Chem. Phys. Lett. 28: 457 (1974).
T. H. Upton and W. A. Goddard, III, Phys. Rev. Lett. 42: 472 (1979).
W. Kohn and L. J. Sham, Phys. Rev. 140, A 1133 (1965); P. Hohenberg and W. Kohn, Phys. Rev. B136: 864 (1964).
V. L. Moruzzi, A. R. Williams and J. F. Janak, Phys. Rev. B15: 2854 (1977).
C. D. Gelatt, E. Ehrenreich and R. E. Watson, Phys. Rev. B15: 1613 (1977).
N.D. Lang, Solid State Comm. 7, 1047 (1969).
A. R. Miedema, Philips Tech. Rev. 36: 217 (1976).
D. G. Pettifor CALPHAD 4: 305 (1977).
A. J. Wilson and C. M. Varma, Phys. Rev. B22: 3805 (1980).
J. Toyoshima and G. A. Somorjai, Catal. Rev. Sci., Eng. 19: 105, (1979).
M. El-Batanouny, M. Strongin, G. P. Williams and J. Colbert, Phys. Rev. Lett. 46: 269 (1981).
R. P. Gangloff and R. P. Wei, Metallurgical Trans. 8A: 1043 (1977).
J. Benziger and R. J. Madix, Surface Sci. 94: 119 (1980).
F. Boszo, G. Ertl, M. Grunze and M. Weiss, Appl. of Surf. Sci. 1: 103 (1977).
J. E. Demuth, Surf. Sci. 65: 369 (1977).
F. J. Himpsel, J. A. Knapp and D. E. Eastman, Phys. Rev. B19: 2873 (1979).
W. Eberhardt, F. Greuter and E. W. Plummer, Phys. Rev. Lett. 46: 1085 (1981).
W. Eberhardt, F. Greuter and E. W. Plummer, Phys. Rev. Lett. 46: 1085 (1981).
S. R. Kelemen, private communication.
B. J. Berkowitz and H. H. Horowitz, J. Electrochem Soc. in press.
B. J. Berkowitz, J. J. Burton, C. R. Helms and R. S. Polizzotti, Scripta Met. 10: 871 (1976).
T. E. Fischer and S. R. Kelemen, J. Catal. 53: 24 (1978).
J. A. Schwarz, Surface Sci. 87: 525 (1979).
S. R. Kelemen and T. E. Fischer, Surface Sci. 87: 53 (1979).
P. Cremaschi and J. L. Whitten, Phys. Rev. Lett. 46: 1242 (1981).
R. A. Oriani, Ber. d. Bunsen, Ges. f. Phys. Chem. 76:301 (1971), Ann. Rev. Mater. Sci. 8: 327 (1978).
C. R. Helms, H. P. Bonzel and S. Kelemen, J. Chem. Phys. 65: 1773 (1976).
H. D. Shih, F. Jona, D. W. Jepsen and P. M. Marcus, Phys. Rev. Lett. 46: 731 (1981).
R. Ugo, Catal. Rev. Sci. Eng. 11: 225 (1975).
E. D. Muettertis, Transition Metal Hydrides, ( Dekker, New York 1971 ).
K. H. Johnson, unpublished.
J. Oudar, Mater. Sci. and Eng. 42: 101 (1980).
P.S. Pao and R.P. Wei, Scripta Met., Vol. 11, p. 515 (1977).
S.J. Hudak and R.P. Wei, Met. Trans., Vol. 7A, p. 235 (1976).
R.P. Gang1off and R.P. Wei, Met. Trans., Vol. 8A, p. 1043 (1977). -
N.H. Chan, K. Klier and R.P. Wei, Scripta Met., Vol. 12, p. 1043 (1978).
R.P. Gangloff and R.P. Wei, ASTM STP 645, p. 87 (1978).
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Fischer, T.E. (1983). General Overview: Atomistics of Surface Reactions. In: Latanision, R.M., Pickens, J.R. (eds) Atomistics of Fracture. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3500-9_2
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