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Dynamical Exchange Effects in the Dielectric Function of the Electron Gas

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Electron Correlations in Solids, Molecules, and Atoms

Part of the book series: NATO Advanced Study Institutes Series ((NSSB,volume 81))

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Abstract

This set of lectures is subdivided into 3 parts.

In part I, some elementary concepts related to the dielectric function of the electron gas are summarized, and related to the single-particle picture and the Hohenberg-Kohn formalism, in order to elucidate the meaning of the local field correction G(q,ω), describing exchange- and correlation effects in the dielectric function.

In part II, the dynamical exchange decoupling is applied on the equation of motion for the Wigner distribution function. A variational approach is used to treat the resulting integro-differential equation. An explicit expression for G(q, ω) is obtained as a sixfold integral, which is reduced to a double integral by analytical methods. Given the interest of this type of integral in related problems, the analytical methods are presented in quite some detail.

Finally, in part III, the numerical results obtained for the dielectric function and the dynamical structure factor are discussed. It is shown that dynamical exchange effects drastically lower the slope of the plasmon dispersion. Several sum rules and consistency requirements are examined. The variational result we derived is finally compared with the proper polarizability to first order in the electron-electron interaction.

Article Note

The formalism, presented in part II and part III, has been developed in collaboration with L.F. Lemmens.

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References

References

  1. F. Bloch, Z. Phys. 55, 545 (1929).

    ADS  Google Scholar 

  2. E.P. Wigner and F. Seitz, Phys. Rev. 43, 804 (1933); 46, 509 (1934).

    MATH  Google Scholar 

  3. M. Gell’Mann and K. Brueckner, Phys. Rev. 106, 364 (1957).

    Article  MathSciNet  ADS  MATH  Google Scholar 

  4. G.D. Mahan, Many-particle physics, Plenum Press, New York, 1981.

    Google Scholar 

  5. E.P. Wigner, Trans. Faraday Soc. 34, 678 (1938).

    Article  Google Scholar 

  6. C.C. Grimes and G. Adams, Phys. Rev. Lett. 42, 795 (1979).

    Article  ADS  Google Scholar 

  7. R.S. Crandall and R. Williams, Phys. Lett. 34A, 404 (1971).

    Article  Google Scholar 

  8. A.W. Overhauser, Phys. Rev. Lett. 4, 462 (1960).

    Article  ADS  Google Scholar 

  9. A.W. Overhauser, Adv. Phys. 27, 343 (1978) and references cited therein.

    Google Scholar 

  10. W.A. Harrison, Pseudopotentials in the theory of simple metals, Benjamin Inc., New York, 1966.

    Google Scholar 

  11. V. Heine, M.L. Cohen and D. Weaire, Solid State Phys. 24, Eds. F. Seitz and D. Turnbull, Academic Press, New York, 1964.

    Google Scholar 

  12. J, Lindhard, Kgl. Dan. Videnskab. Selsk. Mat. Fys. Medd. 28 (8) (1954).

    Google Scholar 

    Google Scholar 

  13. D. Pines and D. Bohm, Phys. Rev. 85, 338 (1952); 92, 609 (1953).

    Article  MathSciNet  ADS  Google Scholar 

  14. P. Nozieres and D. Pines, Phys. Rev. 111, 442 (1958).

    Article  ADS  MATH  Google Scholar 

  15. L. Kleinman, Phys. Rev. 160, 585 (1967); 172, 383 (1968).

    Article  ADS  Google Scholar 

  16. R.W. Shaw, Jr., J. Phys. C: Solid State Phys. 3, 1140 (1970).

    Article  ADS  Google Scholar 

  17. R. Lobo, Phys. Rev. B8, 5348 (1973).

    Article  ADS  Google Scholar 

  18. L. Hedin and B.I Lundqvist, J. Phys. C: Solid State Phys. 4, 2064 (1971).

    Article  ADS  Google Scholar 

  19. C.A. Kukkonen and A.W. Overhauser, Phys. Rev. B20, 550 (1979).

    ADS  Google Scholar 

  20. L.H. Thomas, Proc. Cambridge Philos. Soc. 23, 542 (1927).

    Article  ADS  MATH  Google Scholar 

  21. E. Fermi, Z. Phys. 48, 73 (1928).

    Article  ADS  Google Scholar 

  22. J. Hubbard, Proc. Roy. Soc. (London) A243, 336 (1957).

    MathSciNet  ADS  Google Scholar 

  23. F. Brosens, L.F. Lemmens and J.T. Devreese, Phys. Stat. Sol. (b) 74, 45 (1976); 81, 551 (1977). F. Brosens, J.T. Devreese and L.F. Lemmens, Phys. Stat. Sol. (b) 80, 99 (1979); Phys. Rev. B21, 1363 (1980). J.T. Devreese, F. Brosens, L.F. Lemmens, Phys. Stat. Sol. (b) 9j, 349 (1979); Phys. Rev. B21, 1349 (1980).

    Article  ADS  Google Scholar 

  24. A. Holas, P.K. Aravind and K.S. Singwi, Phys. Rev. B20, 4912 (1979).

    Article  ADS  Google Scholar 

  25. F. Brosens and J.T. Devreese, to be published.

    Google Scholar 

  26. P. Hohenberg and W. Kohn, Phys.Rev. 136, B864 (1964).

    Article  MathSciNet  ADS  Google Scholar 

  27. L. Hedin and B.I. Lundqvist, J. Phys. C: Solid State Phys. 4, 2064 (1971).

    Article  ADS  Google Scholar 

  28. W. Kohn and L.J. Sham, Phys. Rev. 140, A1133 (1965).

    Article  MathSciNet  ADS  Google Scholar 

  29. D. Pines, Elementary Excitations in Solids, W.A. Benjamin, New York, 1963. P. Nozieres, Theory of Interacting Fermi Systems, W.A. Benjamin, New York, 1963. P. Nozieres and D. Pines, Theory of Quantum Liquids, W.A. Benjamin, New York, 1966. L. Hedin and S. Lundqvist, Solid State Physics 239 1969.

    Google Scholar 

  30. D.J.W. Geldart and S.H. Vosko, Canad. J. Phys. 44, 2137 (1966).

    Article  ADS  Google Scholar 

  31. G. Niklasson, Phys. Rev. B10, 3052 (1974).

    Article  ADS  Google Scholar 

  32. A.J. Glick and R.A. Ferrell, Ann. of Phys. H, 359 (1960).

    Google Scholar 

  33. P. Nozieres and D. Pines, Phys. Rev. 109, 1009 (1958); 111, 442 (1958); II Nuovo Cimento 9, 470 (1958).

    Article  ADS  MATH  Google Scholar 

  34. J.C. Kimball, Phys. Rev. A7, 1648 (1973); J. Phys. A: Math, Gen. 8, 1513 (1975); Phys. Rev. BL4, 2371 (1976).

    Article  ADS  Google Scholar 

  35. L.P. Kadanoff and P.C. Martin, Ann. Phys. (N.Y.) 24, 419 (1963).

    Article  MathSciNet  ADS  MATH  Google Scholar 

  36. R.A. Ferrell, Phys. Rev. 107, 450 (1957).

    Article  ADS  MATH  Google Scholar 

  37. R.D. Puff, Phys. Rev. 137, A406 (1967).

    Article  ADS  Google Scholar 

  38. A.A. Kugler, J. Stat. Phys. 12, 35 (1975).

    Article  ADS  Google Scholar 

References

  1. D. Bohm and D. Pines, Phys. Rev. 609 (1958).

    Google Scholar 

  2. J. Lindhard, Kgl. Danske Videnskab. Selskab, Mat.-Fys. Medd. 28 (8) (1954).

    MathSciNet  Google Scholar 

  3. A.J. Glick and R.A. Ferrell, Ann. Phys. (USA) H, 359 (1960).

    Google Scholar 

  4. J. Hubbard, Proc. Roc. Soc. A243, 336 (1957); Phys. Letters 25A, 709 (1967).

    Article  MathSciNet  ADS  Google Scholar 

  5. D.J.W. Geldart and S.H. Vosko, Canad. J. Phys. 44, 2137 (1966).

    Article  ADS  Google Scholar 

  6. L. Kleinman, Phys. Rev. 160, 585 (1967); 172, 383 (1968).

    Article  ADS  Google Scholar 

  7. K.S. Singwi, M.P. Tosi, R.H. Land and A. Sjolander, Phys. Rev. 176, 589 (1968).

    Article  ADS  Google Scholar 

  8. K.S. Singwi, A. Sjölander, M.P. Tosi and R.H. Land, Sol. Stat. Comra. 7, 1503 (1969); Phys. Rev. IH, 1044 (1970).

    Article  ADS  Google Scholar 

  9. M.P. Tosi, Nuovo Cimento 160 (1969).

    Google Scholar 

  10. D.C. Langreth, Phys. Rev. 181, 753 (1969).

    Article  ADS  Google Scholar 

  11. L. Hedin and S. Lundqvist, in “Solid State Physics”, F. Seitz and D. Turnbull, eds., Vol. 23, Academic Press, New York (1969), p. 1.

    Google Scholar 

  12. D.J.W. Geldart and R. Taylor, Canad. J. Phys. 48, 155 (1970).

    Article  ADS  Google Scholar 

  13. R.W. Shaw, Jr., J. Phys. C3, 1140 (1970).

    ADS  Google Scholar 

  14. A.W. Overhauser, Phys. Rev. B3, 1888 (1971).

    Article  ADS  Google Scholar 

  15. T. Schneider, Physica 52, 481 (1971).

    Article  ADS  Google Scholar 

  16. P. Vashishta and K.S. Singwi, Phys. Rev. B6, 875 (1972).

    Article  ADS  Google Scholar 

  17. L.J. Sham, Phys. Rev. B7, 4357 (1973).

    Article  ADS  Google Scholar 

  18. K.N. Pathak and P. Vashishta, Phys. Rev. B7, 3649 (1973).

    Article  ADS  Google Scholar 

  19. A.K. Gupta, P.K. Aravind and K.S. Singwi, Sol. Stat. Comm. 26, 49 (1978).

    Article  ADS  Google Scholar 

  20. R. Dekeyser, Physica (Utrecht) 38, 189 (1968).

    Article  ADS  Google Scholar 

  21. F. Toigo and T.O. Woodruff, Phys. Rev. B2, 3958 (1970); 4, 371 (1971).

    Google Scholar 

  22. A.K. Rajagopal and K.P. Jain, Phys. Rev. A5, 1475 (1972).

    Article  ADS  Google Scholar 

  23. A.K. Rajagopal, Phys. Rev. A6, 1239 (1972).

    ADS  Google Scholar 

  24. A.R.P. Rau and A.K. Rajagopal, Phys. Rev. B11, 3604 (1975); 3052 (1976).

    Google Scholar 

  25. G. Niklasson, Phys. Rev. B10, 3052 (1974).

    Article  ADS  Google Scholar 

  26. A.A. Kugler, J. Stat. Phys. 12., 35 (1975).

    Google Scholar 

  27. F. Brosens, L.F. Lemmens and J.T. Devreese, Phys. Stat. Sol. (b), 74, 45 (1976).

    Article  ADS  Google Scholar 

  28. D.N. Tripathy and S.S. Mandal, Phys. Rev. B16, 231 (1977).

    ADS  Google Scholar 

  29. J.C. Kimball, Phys. Rev. A7, 1648 (1973); B14, 2371 (1976).

    Article  ADS  Google Scholar 

  30. F. Brosens, L.F. Lemmens and J.T. Devreese, Phys. Stat. Sol. (b) 81, 551 (1977).

    Article  ADS  Google Scholar 

  31. F. Brosens, J.T. Devreese and L.F. Lemmens, Phys. Stat. Sol. (b) 80, 99 (1977).

    Article  ADS  Google Scholar 

  32. F. Brosens, L.F. Lemmens and J.T. Devreese, Phys. Stat. Sol. (b) 32, 117 (1977).

    Article  Google Scholar 

  33. J.T. Devreese, F. Brosens and L.F. Lemmens, Phys. Stat. Sol. (b) 91, 349 (1979).

    Article  ADS  Google Scholar 

  34. P.E. Batson, C.H. Chen and J. Silcox, Phys. Rev. Letters 37, 937 (1976).

    Article  ADS  Google Scholar 

  35. W.E. Brittin and W.R. Chappell, Rev. Mod. Phys. 34, 620 (1962).

    Article  MathSciNet  ADS  MATH  Google Scholar 

  36. D.R. Hamann and A.W. Overhauser, Phys. Rev. B143, 183 (1966).

    Article  ADS  Google Scholar 

  37. N.E. Brener and J.L. Fry, Phys. Rev. B19, 1720 (1979); 22, 2737 (1980).

    Google Scholar 

  38. M. Gell-Mann and K.A. Brueckner, Phys. Rev. 106, 364 (1957).

    Article  MathSciNet  ADS  MATH  Google Scholar 

  39. P. Nozieres and D. Pines, Nuovo Cimento 470 (1958).

    Google Scholar 

  40. A. Holas, P.K. Aravind and K.S. Singwi, Phys. Rev. B20, 4912 (1979).

    Article  ADS  Google Scholar 

  41. J.T. Devreese, F. Brosens and L.F. Lemmens, Phys. Rev. B21, 1349 (1980).

    Article  ADS  Google Scholar 

  42. F. Brosens, J.T. Devreese and L.F. Lemmens, Phys. Rev. B21, 1363 (1980).

    Article  ADS  Google Scholar 

References

  1. J. Hubbard, Proc. Roy. Soc. A 243, 336 (1957).

    MathSciNet  ADS  Google Scholar 

  2. D.R. Hamann and A.W. Overhauser, Phys. Rev. B 143, 183 (1966).

    Article  ADS  Google Scholar 

  3. A. Holas, P.K. Aravind and K.S. Singwi, Phys. Rev. B 20, 4912 (1979).

    Article  ADS  Google Scholar 

  4. A.K. Rajagopal, Phys. Rev. A 6, 1239 (1972).

    Article  ADS  Google Scholar 

  5. F. Brosens, L.F. Lemmens and J.T. Devreese, Phys. Stat. Sol. (b), 74, 45 (1976).

    Article  ADS  Google Scholar 

  6. D.N. Tripathy and S.S. Mandal, Phys. Rev. B 16, 231 (1977).

    Article  ADS  Google Scholar 

  7. D.J.W. Geldart and R. Taylor, Canad. J. Phys. 48, 155 (1970).

    Article  ADS  Google Scholar 

  8. F. Toigo and T.O. Woodruff, Phys. Rev. B 2, 3958 (1970); 4, 371 (1971).

    Article  ADS  Google Scholar 

  9. D.J.W. Geldart, R. Taylor and M. Rasolt, Phys. Rev. B. 5, 2740 (1972).

    Article  ADS  Google Scholar 

  10. J.C. Kimball, Phys. Rev. A 7, 1648 (1973); B 14, 2371 (1976).

    Article  ADS  Google Scholar 

  11. G. Niklasson, Phys. Rev. B 10, 3052 (1974).

    Article  ADS  Google Scholar 

  12. J.T. Devreese, F. Brosens and L.F. Lemmens, Phys. Rev. B 21, 1349 (1980).

    Article  ADS  Google Scholar 

  13. F. Brosens, J.T. Devreese, L.F. Lemmens, Phys. Rev. B 21, 1363 (1980).

    Article  ADS  Google Scholar 

  14. F. Brosens, L.F. Lemmens and J.T. Devreese, Phys. Stat. Sol. (b) 82, 117 (1977).

    Article  Google Scholar 

  15. F. Brosens, L.F. Lemmens and J.T. Devreese, Phys. Stat. Sol. (b), 81, 551 (1977).

    Article  ADS  Google Scholar 

  16. A.W. Overhauser, Phys. Rev. B 2, 874 (1970).

    Article  ADS  Google Scholar 

  17. A.W. Overhauser, Adv. Phys. 27, 343 (1978).

    Article  ADS  Google Scholar 

  18. F. Brosens, J.T. Devreese and L.F. Lemmens, Phys, Stat. Sol. (b) 80, 99 (1977).

    Article  ADS  Google Scholar 

  19. P.E. Batson, C.H. Chen and J. Silcox, Phys. Rev. Letters 37, 937 (1976).

    Article  ADS  Google Scholar 

  20. E.P. Wigner, Trans. Faraday Soc. 34, 678 (1938).

    Article  Google Scholar 

  21. N. Wiser and M.M. Cohen, J. Phys. C (Solid State Physics) 2, 193 (1969).

    Article  ADS  Google Scholar 

  22. A.W. Overhauser, Phys. Rev. 128, 1437 (1962).

    Article  ADS  MATH  Google Scholar 

  23. B.K. Rao, S.S. Mandal and D.N. Tripathy, J. Phys. F: Metal Phys. 9 L51 (1979); 10, L32 (1980).

    Article  ADS  Google Scholar 

  24. F. Brosens, J.T. Devreese, L.F. Lemmens, J. Phys. F: Metal Phys. 10, L27 (1980).

    Article  ADS  Google Scholar 

  25. K.J. Duff and A.W.Overhauser, Phys. Rev. B 5, 2799 (1972).

    Article  ADS  Google Scholar 

  26. P. Vashishta and K.S. Singwi, Phys. Rev. B 6, 875 (1972).

    Article  ADS  Google Scholar 

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Devreese, J.T., Brosens, F. (1983). Dynamical Exchange Effects in the Dielectric Function of the Electron Gas. In: Devreese, J.T., Brosens, F. (eds) Electron Correlations in Solids, Molecules, and Atoms. NATO Advanced Study Institutes Series, vol 81. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3497-2_5

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