Skip to main content
SpringerLink
Log in
Book cover

Solution Behavior of Surfactants pp 803–831Cite as

Kinetic Concepts in Reversed Micellar Systems

  • Chapter

  • 248 Accesses

Abstract

Reversed micellar systems have borrowed extensively from the nomenclature and concepts used in aqueous detergent systems, and much of the early work on surfactant aggregates in nonpolar solvents arose from the concept of modelling the active site of proteolytic enzymes. Moreover, the readiness with which quite large concentrations of water and substrate were solubilized in the polar interior of reversed micelles led to the attractive possibility of determining reaction order with respect to water.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J. W. McBain, Trans. Faraday Soc., 9, 99 (1913).

    Google Scholar 

  2. G. S. Hartley, “Aqueous Solutions of Paraffin Chain Salts,” Hermann et Cie., Paris, 1936.

    Google Scholar 

  3. G. S. Hartley, in “Micellization, Solubilization and Microemulsions,” K. Mittal, Editor, Vol. 1, pp 23–43, Plenum Press, New York, 1977.

    Google Scholar 

  4. N. Muller, in “Reaction Kinetics in Micelles,” E. Cordes, Editor, pp 1–23, Plenum Press, New York-London, 1973.

    Google Scholar 

  5. K. L. Mittal and P. Mukerjee, in “Micellization, Solubilization and Microemulsions,” K. Mittal, Editor, Vol. 1, pp 1–21, Plenum Press, New York, 1977.

    Google Scholar 

  6. P. Mukerjee, Adv. Colloid Interface Sci., 1, 241 (1967).

    Article  Google Scholar 

  7. P. Mukerjee, Ber. Bunsenges. Phys. Chem., 82, 931 (1978).

    Google Scholar 

  8. B. Lindman, G. Lindblom, H. Wennerström and H. Gustavsson, in “Micellization, Solubilization and Microemulsions,” K. Mittal, Editor, Vol. 1, pp 195–227, Plenum Press, New York, 1977.

    Google Scholar 

  9. A. T. Florence, in “Micellization, Solubilization and Microemul-sions,” K. Mittal, Editor, Vol. 1, pp 55–74, Plenum Press, New York, 1977.

    Google Scholar 

  10. D. Piszkiewicz, J. Am. Chem. Soc., 99, 1550 (1977).

    Article  PubMed  Google Scholar 

  11. S. I. Goldberg, N. Baba, R. L. Green, R. Pandian, J. Stowers and R. B. Dunlop, J. Am. Chem. Soc., 100, 6768 (1978).

    Article  Google Scholar 

  12. C. A. Bunton, Catal. Rev.-Sci. Eng., 20 (1), 1 (1979).

    Article  Google Scholar 

  13. F. M. Menger, Accounts Chem. Res., 12 (4), 111 (1979).

    Article  Google Scholar 

  14. E.A.G. Anianssen and S. N. Wall, J. Phys. Chem., 78, 1024 (1974).

    Article  Google Scholar 

  15. E.A.G. Sudhölter, G. B. van de Langkruis and J.B.F.N. Engberts, Receuil, 99 (3), 73 (1980).

    Google Scholar 

  16. T. Sugimoto and N. Baba, Israel J. Chem., 18 (3), 215 (1980).

    Google Scholar 

  17. C. R. Singleterry, J. Am. Oil Chemists’ Soc., 32, 446 (1955).

    Article  Google Scholar 

  18. H. F. Eicke, in “Micellization, Solubilization and Microemulsions,” K. Mittal, Editor, Vol. 1, pp 429–443, Plenum Press, New York, 1977.

    Google Scholar 

  19. J. H. Hildebrand and R. L. Scott, “Regular Solutions,” Prentice- Hall, Englewood Cliffs, New Jersey, 1962.

    Google Scholar 

  20. R. C. Little and C. R. Singleterry, J. Phys. Chem., 68, 3453 (1964).

    Article  Google Scholar 

  21. J. H. Fendler and E. J. Fendler, “Catalysis in Micellar and Macromolecular Systems,” Chapter 10, Academic Press, New York, 1975.

    Google Scholar 

  22. A. Kitahara, in “Cationic Surfactants,” E. Jungermann, Editor, Marcel Dekker, New York, 1970.

    Google Scholar 

  23. K. Shinoda and E. Hutchinson, J. Phys. Chem., 66, 577 (1962).

    Article  Google Scholar 

  24. F. M. Fowkes, J. Phys. Chem., 66, 1843 (1962).

    Article  Google Scholar 

  25. K. Kon-no and A. Kitahara, J. Colloid Interface Sci., 35, 409, 636 (1971).

    Article  Google Scholar 

  26. H. F. Eicke, Topics in Current Chemistry, 87, 85 (1980).

    Article  PubMed  Google Scholar 

  27. F.Y.-F. Lo, B. M. Escott, E. J. Fendler, E. T. Adams, R. D. Larson and P. W. Smith, J. Phys. Chem., 79, 2609 (1975).

    Article  Google Scholar 

  28. K. Shinoda, Bull. Chem. Soc. Japan, 26, 101 (1953).

    Article  Google Scholar 

  29. F. M. Batson and C. A. Kraus, J. Am. Chem. Soc., 56, 2017 (1934).

    Article  Google Scholar 

  30. D. T. Copenhafer, J. Am. Chem. Soc., 73, 4557 (1951).

    Article  Google Scholar 

  31. A. S. Kertes, in “Micellization, Solubilization and Microemulsions,” K. Mittal, Editor, Vol. 1, pp 445–454, Plenum Press, New York, 1977.

    Google Scholar 

  32. J. H. Fendler, E. J. Fendler, R. T. Medary and O. A. El Seoud, J. Chem. Soc. Faraday Trans. I, 69, 280 (1973).

    Article  Google Scholar 

  33. A. S. Kertes and H. Gutmann, in “Surface and Colloid Science,” E. Matijevic, Editor, Vol. 8, pp 193–295, Wiley-Interscience, New York, 1975.

    Google Scholar 

  34. Y. C. Jean and H. J. Ache, J. Am. Chem. Soc., 100, 6320 (1978).

    Article  Google Scholar 

  35. H. F. Eicke, R.F.W. Hopmann and H. Christen, Ber. Bunsenges. Phys. Chem., 79, 667 (1975).

    Google Scholar 

  36. H. F. Eicke and A. Denss, J. Colloid Interface Sci., 64, 386 (1978).

    Article  Google Scholar 

  37. A. Kitahara, Bull. Chem. Soc. Japan, 31, 288 (1958).

    Article  Google Scholar 

  38. K. Kon-no, T. Masuyama, M. Mizuno and A. Kitahara, Nippon Kagaku Kaishi, 11, 1857 (1975).

    Article  Google Scholar 

  39. E. J. Fendler, J. H. Fendler, R. T. Medary and O. A. El Seoud, J. Phys. Chem., 77, 1432 (1973).

    Article  Google Scholar 

  40. O. A. El Seoud, E. J. Fendler, J. H. Fendler and R. T. Medary, J. Phys. Chem., 77, 1876 (1973).

    Article  Google Scholar 

  41. O. A. El Seoud, E. J. Fendler and J. H. Fendler, J. Chem. Soc. Faraday Trans. I, 70, 459 (1974).

    Article  Google Scholar 

  42. U. Hermann and Z. A. Schelly, J. Am. Chem. Soc., 101, 2665 (1979).

    Article  Google Scholar 

  43. H. F. Eicke and H. Christen, Helv. Chim. Acta., 61, 2258 (1978).

    Article  Google Scholar 

  44. H. F. Eicke, (1977), personal communication.

    Google Scholar 

  45. M. Seno, K. Araki and S. Shiraishi, Bull. Chem. Soc. Japan, 49, 899 (1976).

    Article  Google Scholar 

  46. A. Kitahara, Bull. Chem. Soc. Japan, 28, 234 (1955).

    Article  Google Scholar 

  47. S. R. Palit and V. Venkateswarlu, Proc. Roy. Soc., Ser. A 208, 542 (1951).

    Article  Google Scholar 

  48. G. D. Correll, R. N. Cheser III, F. Nome and J. H. Fendler, J. Am. Chem. Soc., 100, 1254 (1978).

    Article  Google Scholar 

  49. J. H. Fendler, F. Nome and H. C. van Woert, J. Am. Chem. Soc., 96, 6745 (1974).

    Article  PubMed  Google Scholar 

  50. J. H. Fendler and L.-J. Liu, J. Am. Chem. Soc., 97, 999 (1975).

    Article  Google Scholar 

  51. O. A. El Seoud, A. Ifertins, L. P. Barbur, M. J. Da Silva and V. Aldrigue, J. Chem. Soc. Perkin Trans. II, 1674 (1977).

    Google Scholar 

  52. J. Sunamoto, T. Hamada, T. Seto and S. Yamamoto, Bull. Chem. Soc Japan, 53, 583 (1980).

    Article  Google Scholar 

  53. C. J. O’Connor, E. J. Fendler and J. H. Fendler, J. Chem. Soc. Dalton Trans., 625 (1974).

    Google Scholar 

  54. C. J. O’Connor, E. J. Fendler and J. H. Fendler, J. Am. Chem. Soc., 96, 370 (1974).

    Article  Google Scholar 

  55. T. D. Lomax and C. J. O’Connor, J. Am. Chem. Soc., 100, 5910 (1978).

    Article  Google Scholar 

  56. C. J. O’Connor and R. E. Ramage, Aust. J. Chem., 33, 771 (1980).

    Article  Google Scholar 

  57. H. F. Eiche and A. Denss, (1978), personal communication.

    Google Scholar 

  58. T. C. Bruice and S. Benkovic, “Bioorganic Mechanisms,” Vol. 1, W. A. Bengamin Inc., New York, 1966.

    Google Scholar 

  59. W. P. Jencks, “Catalysis in Chemistry and Enzymology,” McGraw- Hill, New York, 1969.

    Google Scholar 

  60. C. K. Ingold, “Structure and Mechanism in Organic Chemistry,” Cornell University Press, Ithaca, 2nd ed., 1969.

    Google Scholar 

  61. M. L. Bender, “Mechanisms of Homogeneous Catalysis from Protons to Proteins,” Wiley-Interscience, New York, 1971.

    Google Scholar 

  62. A. Kitahara, in “Micellization, Solubilization and Microemulsions,” K. Mittal, Editor, Vol. I, pp 429–443, Plenum Press, New York, 1977.

    Google Scholar 

  63. J. H. Fendler and E. J. Fendler, “Catalysis in Micellar and Macromolecular Systems,” Chapter 4, Academic Press, New York, 1975.

    Google Scholar 

  64. F. M. Menger and C. E. Portnoy, J. Am. Chem. Soc., 89, 4698 (1967).

    Article  Google Scholar 

  65. T. C. Bruice, J. Katzhendler and L. R. Fedor, J. Am. Chem. Soc., 90, 133 (1968 ).

    Google Scholar 

  66. C. A. Bunton, E. J. Fendler, L. Sepulveda and K.-U. Yang, J. Am. Chem. Soc., 90, 5512 (1968).

    Article  Google Scholar 

  67. C. A. Bunton and L. Robinson, J. Org. Chem., 34, 773 (1969).

    Article  Google Scholar 

  68. E. J. Fendler, R. R. Liechti and J. H. Fendler, J. Org. Chem., 35, 1658 (1970).

    Article  Google Scholar 

  69. J. H. Fendler, E. J. Fendler and L. W„ Smith, J. Chem. Soc. Perkin Trans. II, 2097 (1972).

    Google Scholar 

  70. C. J. O’Connor and R. E. Ramage, Aust. J. Chem., 33, 757 (1980).

    Article  Google Scholar 

  71. C. J. O’Connor, E. J. Fendler and J. H. Fendler, J. Org. Chem., 38, 3371 (1973).

    Article  Google Scholar 

  72. J. R. Escabi-Perez and J. H. Fendler, J. Am. Chem. Soc., 100, 2234 (1978).

    Article  Google Scholar 

  73. F. M. Menger and A. C. Vitale, J. Am. Chem. Soc., 95, 4931 (1973).

    Article  Google Scholar 

  74. M. L. Bender, Chem. Rev., 60, 53 (1960).

    Article  Google Scholar 

  75. F. M. Menger and J. H. Smith, J. Am. Chem. Soc., 94, 3824 (1972)

    Article  Google Scholar 

  76. C. J. O’Connor and R. E. Ramage, Aust. J. Chem., 33, 0000 (1980) in press.

    Google Scholar 

  77. The pKa values of the amines in benzene were assumed to follow the trend of the pKa values in water, as found in reference 78 and reference 79.

    Google Scholar 

  78. R. C. Weast, Editor, “Handbook of Chemistry and Physics,”

    Google Scholar 

  79. A. Albert and E. P. Serjeant, “The Determination of Ionisation Constants,” Chapman and Hall, Lit, 2nd ed., 1971.

    Google Scholar 

  80. C. L. Bell and G. M. Barrow, J. Chem. Phys., 31, 1158 (1959).

    Article  Google Scholar 

  81. F. Rivetti and U. Tonellato, J. Chem. Soc. Perkin Trans. II, 1176 (1976).

    Google Scholar 

  82. H. Anderson, C.-W. Su, and J. W. Watson, J. Am. Chem. Soc., 91, 482 (1969).

    Article  Google Scholar 

  83. F. M. Menger, J. Am. Chem. Soc., 88, 3081 (1966).

    Article  Google Scholar 

  84. W. P. Jencks and J. Carriuolo, J. Am. Chem. Soc., 84, 1778 (1962).

    Article  Google Scholar 

  85. T. C. Bruice and R. Lapinski, J. Am. Chem. Soc., 86, 2265 (1964).

    Google Scholar 

  86. D. G. Oakenf ull, T. Riley and V. Gold, Chem. Commun., 385 (1966).

    Google Scholar 

  87. M. M Davis and M. Paabo, J. Am. Chem. Soc., 82, 5081 (1960).

    Article  Google Scholar 

  88. B. W. Clare, D. Cook, E.C.F. Ko and A. J. Parker, J. Am. Chem. Soc., 88, 1911 (1966).

    Article  Google Scholar 

  89. A. A. Frost and R. G. Pearson, “Kinetics and Mechanism,” Wiley, New York, 2nd ed., 1961.

    Google Scholar 

  90. M. Kilpatrick (Jr) and M. L. Kilpatrick, J. Am. Chem. Soc., 52, 1418 (1930).

    Article  Google Scholar 

  91. F. D. Chattaway, J. Chem. Soc., 2495 (1931).

    Google Scholar 

  92. P. J. Lillford and D.P.N. Satchell, J. Chem. Soc.(B), 360 (1967).

    Google Scholar 

  93. H. Kondo, K. Fujiki and J. Sunamoto, J. Org. Chem., 43, 3584 (1978).

    Article  Google Scholar 

  94. K. Blàha and J. Rudinger, Collection Czech. Chem. Commun., 30, 585 (1965).

    Google Scholar 

  95. R. B. Homer, R. B. Moodie and H. N. Rydon, J. Chem. Soc., 4403 (1965).

    Google Scholar 

  96. F. C. McKay and N. F. Alberton, J. Am. Chem. Soc., 79 4686 (1957).

    Article  Google Scholar 

  97. K. Blàha and J. Rudinger, Collection Czech. Chem. Commun., 30, 599 (1965).

    Google Scholar 

  98. C. J. O’Connor and R. E. Ramage, Aust. J. Chem., 33, 779 (1980).

    Article  Google Scholar 

  99. C. J. O’Connor and T. D. Lomax, 1979, unpublished data.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, University of Auckland, Private Bag, Auckland, New Zealand

    Charmian J. O’Connor, Terence D. Lomax & Robyn E. Ramage

Authors
  1. Charmian J. O’Connor
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Terence D. Lomax
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Robyn E. Ramage
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. IBM Corporation, Hopewell Junction, New York, USA

    K. L. Mittal

  2. The Standard Oil Company (Ohio), Cleveland, Ohio, USA

    E. J. Fendler

Rights and permissions

Reprints and permissions

Copyright information

© 1982 Plenum Press, New York

About this chapter

Cite this chapter

O’Connor, C.J., Lomax, T.D., Ramage, R.E. (1982). Kinetic Concepts in Reversed Micellar Systems. In: Mittal, K.L., Fendler, E.J. (eds) Solution Behavior of Surfactants. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3494-1_4

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-3494-1_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3496-5

  • Online ISBN: 978-1-4613-3494-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation