Abstract
The absorption spectroscopy of the surfactant-sensitized Chrome Azural S (CAS) complex of beryllium has been examined in detail, in order to ascertain its sensitivity to various solution parameters (preliminary to an investigation of the fundamental sensitization mechanism). Surprisingly, sensitization was observed with at least one anionic surfactant (sodium dodecyl sulfate) and one nonionic surfactant (dimethyloctynediol) in addition to the effects expected for cationic surfactants (benzyldimethyl-hexadecylammonium chloride and cetyItrimethylammonium bromide). However, sensitization was not observed with three other nonionic surfactants (3,5-dimethyl-l-hexyn-3-ol, 3-hydroxy-l-propanesulfonic acid γ-sultone, and polyvinyl alcohol), even though sensitization has been reported elsewhere for one of these (PVA).
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
W. L. Hinze, in “Solution Chemistry of Surfactants,” K. L. Mittal, Editor, Vol. 1, p. 79, Plenum Press, New York, 1979; and references therein.
G. S. Hartley, Trans. Faraday Soc., 30, 444 (1934).
F. W. C. Strelow and C. H. S. Weinert, Anal. Chem., 47, 2292 (1975).
L. Sommer and V. Kuban, Anal. Chim. Acta, 44, 333 (1969).
H. Nishida, Bunseki Kagaku, 20, 1080 (1971).
H. Kohara, Bunseki Kagaku, 24, 525 (1975).
H. R. Mulwani and R. M. Sathe, Analyst, 102, 137 (1977).
H. Nishida, T. Nishida, and H. Ohtomo, Bull. Chem. Soc. Japan, 49, 571 (1976).
Y. Horiuchi and H. Nishida, Bunseki Kagaku, 18, 180 (1969).
Y. Shijo and T. Takeuchi, Bunseki Kagaku, 20, 137 (1971).
R. M. Dagnall, T. S. West, and P. Young, Analyst, 92, 27 (1967).
H. B. Corbin, Anal. Chem., 45, 534 (1973).
F. H. Quina and H. Chaimovich, J. Phys. Chem., 83, 1844 (1979).
J. Inczedy, “Analytical Applications of Equilibria,” J. Tyson, Translation Editor, John Wiley, New York, 1976.
K. J. Mysels and P. Mukerjee, “Critical Micelle Concentrations of Aqueous Surfactant Systems,” NSRDS-NBS 36, U. S. Dept. of Commerce, Washington, D. C., 1971.
J. Baxter-Hammond, C. R. Powley, K. D. Cook, and T. A. Nieman, J. Colloid Interface Sci., (1980), in press.
B. W. Bailey, J. E. Chester, R. M. Dagnall, and T. S. West, Talanta, 15, 1359 (1968).
S. B. Savvin, R. K. Chernova, V. V. Belousova, L. K. Sukhova, and S. N. Shtykov, Zh. Anal. Khim., 33, 1473 (1978).
R. M. Dagnall, T. S. West, and P. Young, Analyst, 92, 27 (1967)
A. Ashton, A. G. Fogg, and D. T. Burns, Analyst, 98, 202 (1973)
L. Sommer and V. Kuban, Coll. Czech. Chem. Commun., 32, 4355 (1967).
W. G. Baldwin and D. R. Stranks, Aust. J. Chem., 21, 603 (1968)
C. Tanford, “The Hydrophobic Effect: Formation of Micelles and Biological Membranes,” 2nd ed., Wiley-Interscience, New York, 1980.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1982 Plenum Press, New York
About this chapter
Cite this chapter
Baxter-Hammond, J., Cook, K.D. (1982). Probing the Mechanism of Micellar Sensitization of Photometric Analysis. In: Mittal, K.L., Fendler, E.J. (eds) Solution Behavior of Surfactants. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3494-1_37
Download citation
DOI: https://doi.org/10.1007/978-1-4613-3494-1_37
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-3496-5
Online ISBN: 978-1-4613-3494-1
eBook Packages: Springer Book Archive