Abstract
A modified mass-action distribution model, the so-called shell model for micellar systems, has been recently published by the author. This model simulates the critical micelle concentration behavior of such systems. An internally self-consistent closed form solution for the relaxation kinetics of the initial process immediately following perturbation, in micellar systems following this model, has been published by the author during the year of this Symposium. This has also for the first time fit the relaxation time behavior down to infinite dilution. With the aid of this equilibrium distribution and application of the standard rate equations of chemical kinetics for the interaction of a monomer molecule with another monomer and each oligomer unit, the instantaneous rate of change of the molar and equivalent concentration of every oligomer throughout the distribution has been computed numerically with a digital computer.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
K. H. Meyer and A. van der Wyk, Helv. Chim. Acta, 20, 1321 (1937).
C. A. Hoeve and G. C. Benson, J. Phys. Chem., 61, 1149 (1957).
P. Mukerjee, J. Phys. Chem., 76, 565 (1972).
P. J. Mijnlieff and R. Ditmarsch, Nature (London), 208, 899 (1965).
G. C. Kresheck, E. Hamori, G. Davenport and H. A. Scheraga, J. Amer. Chem. Soc., 88, 246 (1966).
N. Muller, J. Phys. Chem. 76, 3017 (1972).
T. Nakagawa, Colloid Polymer Sci., 252, 56 (1974).
J. Lang, C. Tondre, R. Zana, R. Bauer, H. Hoffmann, and W. Ulbricht, J. Phys. Chem., 79, 276 (1975).
E. Graber, J. Lang and R. Zana, Kolloid-Z. u Z. Polym., 238, 470 (1970).
R. Folger, H. Hoffmann and W. Ulbricht, Ber. Bunsenges. Phys. Chem., 78, 986 (1974).
P. J. Sams, E. Wyn-Jones and J. Rassing, Chem. Phys. Lett., 13, 233 (1972).
E. A. G. Aniansson and S. N. Wall, J. Phys. Chem., 78, 1024 (1974).
E. A. G. Aniansson and S. N. Wall, J. Phys. Chem., 79, 857 (1975).
E. A. G. Aniansson, S. N. Wall, M. Almgren, H. Hoffmann, I. Kielmann, W. Ulbricht, R. Zana, J. Lang and C. Tondre, J. Phys. Chem., 80, 905 (1976).
M. Almgren, E. A. G. Aniansson and K. Holmåker, Chem. Phys., 19, 1 (1977).
S. N. Wall and E. A. G. Aniansson, J. Phys, Chem,, 84, 727 (1980).
G. Kegeles, J. Phys. Chem., 83, 1728 (1979).
G. Kegeles, Arch. Biochem. Biophys., 200, 279 (1980).
G. Kegeles, to be published.
W. Baumüller, H. Hoffmann, W. Ulbricht, C. Tondre and R. Zana, J. Colloid Interface Sci., 64, 418 (1978).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1982 Plenum Press, New York
About this chapter
Cite this chapter
Kegeles, G. (1982). Frequency Distribution Shifts in Micellar Kinetics. In: Mittal, K.L., Fendler, E.J. (eds) Solution Behavior of Surfactants. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3491-0_15
Download citation
DOI: https://doi.org/10.1007/978-1-4613-3491-0_15
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-3493-4
Online ISBN: 978-1-4613-3491-0
eBook Packages: Springer Book Archive