Abstract
Despite the extensive chemistry reported for the complexes between a host of macrocyclic compounds and the alkali metal ions (1), only a limited number of lanthanide (Ln) complexes have been studied so far. Some unusual features of the complexation of Ln ions in anhydrous propylene carbonate by the eighteen-membered cycle di-tert-butylbenzo-18-crown-6, 4, have recently been reported by the authors (2). This study has now been extended to the macrocycles 1–5(see Figures 1 and 2 for the structure of the ligands).
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References
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© 1982 Plenum Press, New York
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Desreux, J.F., Massaux, J. (1982). A Systematic Study of the Complexation of Di- and Tri-Valent Lanthanide Ions by Macrocycles of Varying Size. In: McCarthy, G.J., Silber, H.B., Rhyne, J.J., Kalina, F.M. (eds) The Rare Earths in Modern Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3406-4_15
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DOI: https://doi.org/10.1007/978-1-4613-3406-4_15
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