Abstract
The low valent organometallic chemistry of the lanthanide elements has been investigated by cocondensing lanthanide metal vapor with neutral unsaturated hydrocarbons at −196°C. Preparative-scale reactions of this type provide a variety of new classes of organolanthanide complexes as well as insight into the lanthanide metal unsaturated hydrocarbon interaction. The utility of this low valent approach in preparing divalent and trivalent organolanthanide hydrides and soluble divalent organosamarium complexes is also discussed.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
W. J. Evans, S. C. Engerer and A. C. Neville, J. Am. Chem. Soc, 100: 331 (1978).
W. J. Evans, A. L. Wayda, C. W. Chang and W. M. Cwirla, ibid, 100: 333 (1978).
W.J. Evans, S.C. Engerer, P.A. Piliero and A.L. Wayda, J. Chem. Soc. Chem. Commun., 1007 (1979).
W. J. Evans, S. C. Engerer, P. A. Piliero and A. L. Wayda, Fundamental Research in Homogeneous Catalysis, Vol. 3, M. Tsutsui, ed.. Plenum Publishing Corp., New York, 941 (1979).
H. A. Zinnen, J. J. Pluth and W. J. Evans, J. Chem. Soc. Chem. Commun., 810 (1980).
W. J. Evans, S. C. Engerer and P. A. Piliero, 178th ACS National Meeting, Washington, D.C., September, 1979, INOR 188.
W. J. Evans, K. M. Coleson, S. C. Engerer, A. L. Wayda and H. A. Zinnen, Second Chemical Congress of the North American Conti-nent, Las Vegas, Nevada, August, 1980, INOR 297.
P. S. Skell and M. J. McGlinchey, Angew. Chem., Internat. Ed., Engl., 14: 195 (1975); P. L. Timms and T. W. Turney, Adv. Organomet. Chem., 15: 53 (1977); K. J. Klabunde, Chemistry of Free Atoms and Particles, Academic Press, New York (1980).
J. R. Blackborrow and D. Young, Metal Vapor Synthesis in Organo-metallic Chemistry, Springer Verlag, Berlin, Germany (1979).
J. H. Burns, W. H. Baldwin, and F. H. Fink, Inorg. Chem, 13: 1916 (1974).
R. E. Maginn, S. Manastyrskyj and M. Dubeck, J. Am. Chem. Soc, 85: 672 (1963).
J. Holton, M. F. Lappert, D. G. H. Ballard, R. Pearce, J. L. Atwood and W. E. Hunter, J. Chem. Soc. Dalton, 54 (1979).
P. H. Kasai, D. McLeod, Jr. and T. Watanabe, J. Am. Chem. Soc, 99: 3521 (1977).
W. J. Evans and J. H. Meadows, unpublished results.
W. J. Evans, A. L. Wayda, W. E. Hunter and J. L. Atwood, J. Chem. Soc. Chem. Comm., in press (1981).
J. M. Manriquez, D. R. McAlister, R. D. Sanner and J. E. Bercaw, J. Am. Chem. Soc, 100: 2716 (1978).
P. J. Fagan, J. M. Manriquez, T. J. Marks, V. W. Day, S.H. Vollmer and C.S. Day, ibid, 102: 5393 (1980).
W. J. Evans and A. L. Wayda, I. Bloom and K. M. Coleson, 181st, ACS National Meeting, Atlanta, Ga., April, 1981, INOR 219.
J. L. Atwood, W. E. Hunter, A. L. Wayda and W. J. Evans, submitted.
P. L. Watson, J. Chem. Soc. Chem. Comm, 652 (1980).
T. D. Tilley, R.A. Andersen, B. Spencer, H. Ruben, A. Zalkin and D. H. Templeton, Inorg. Chem, 19: 2999 (1980).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1982 Plenum Press, New York
About this chapter
Cite this chapter
Evans, W.J. (1982). Recent Advances in the Low Valent Approach to f-Element Organo-Metallic Chemistry. In: McCarthy, G.J., Silber, H.B., Rhyne, J.J., Kalina, F.M. (eds) The Rare Earths in Modern Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3406-4_11
Download citation
DOI: https://doi.org/10.1007/978-1-4613-3406-4_11
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-3408-8
Online ISBN: 978-1-4613-3406-4
eBook Packages: Springer Book Archive