Abstract
The variety of recombination processes, leading to charge neutralization or molecule formation, is surveyed. Examples are provided of atom-atom, electron-ion and ion-ion recombination in both the two-body and many-body regimes, with species ranging from protons to ammonia clusters. The emphasis is on the theoretical development, with only brief references to experimental techniques.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
H. Abgrall, A. Guisti-Suzor and E. Roueff, 1976, Quantum effects in the formation of CH+ by radiative association, Astrophys. J., 207: L69.
S. Adelman and D. R. Herschbach, 1977, On the long range configuration-interaction between ionic and covalent states, Mol. Phys., 33: 793.
D. Auerbach, R. Cacak, R. Caudano, T. D. Gaily, C. J. Keyser, J. W. McGowan, J. B. A. Mitchell and S. F. J. Wilk, 1977, Merged electron-ion beam experiments I. Method of measurements of e−H2+ and e−H3+ dissociative recombination cross sections, J. Phys. B, 10: 3797.
R. A. Bain and J. N. Bardsley, 1972, Shape resonances in atom-atom collisions I. Radiative association, J. Phys. B, 5: 277.
J. N. Bardsley, 1968a, Configuration intereaction in the continuum states of molecules, J. Phys. B, 1: 349.
J. N. Bardsley, 1968b, The theory of dissociative recombination, J. Phys. B, 1: 365.
J. N. Bardsley, 1979, Molecular resonance phenomena, in “Electron-molecule and photon-molecule collisions”, T. Rescigno, V. McKoy, B. Schneider, eds., Plenum, New York.
J. N. Bardsley and B. R. Junker, 1973, Dissociative recombination of CH+ ions, Astrophys. J., 183: L135.
J. N. Bardsley and J. M. Wadehra, 1980, Monte Carlo simulation of three-body ion-ion recombination, Chem. Phys. Lett, (in press).
J. N. Bardsley, C. Derkits and J. M. Wadehra, 1980, Dissociative attachment in H2, F2 and Cℓ2 and dissociative recombination in H2+, to be published.
D. R. Bates, 1951, Rate of formation of molecules by radiative association, Mon. Not. Roy. Astron. Soc., 111: 303.
D. R. Bates, 1979a, Aspects of recombination, Adv. Atom. Molec. Phys. 15: 235.
D. R. Bates, 1979b, Dependence of the binary ionic recombination coefficient on the density of ambient gas at the low density limit, J. Phys. B, 12: L505.
D. R. Bates, 1980a, Dissociative recombination in an ambient electron gas, J. Phys. B, 13: L51.
D. R. Bates, 1980b, Classical theory of electron-ion recombination in an ambient gas, J. Phys. B, (in press).
D. R. Bates, 1980c, Mutual neutralization of ions in flames. J. Phys. B, 13: 205.
D. R. Bates and M. R. Flannery, 1968, Three-body recombination of positive and negative ions II. General third body. Proc. Roy. Soc. Lond. 302: 367.
D. R. Bates and S. P. Khare, 1965, Recombination of positive ions and electrons in a dense neutral gas, Proc. Phys. Soc. Lond., 35: 231.
D. R. Bates and A. E. Kingston, 1964, Collisional-radiative recombination at low temperatures and densities, Proc. Phys. Soc. Lond., 83: 43.
D. R. Bates and I. Mendas, 1978, Ionic recombination in an ambient gas, II. Computer experiment with specific allowance for binary recombination, Proc. Roy. Soc. Lond., A 359: 287.
D. R. Bates and R. J. Moffett, 1965, Three-body recombination of positive and negative ions I. Ions recombining in their parent gas, Proc. Roy. Soc. Lond., 291: 1
D. R. Bates, A. E. Kingston and R. W. P. McWhirter, 1962a, Recombination between electrons and atomic ions I. Optically thin plasmas, Proc. Rov. Soc. Lond.T 267: 297.
D. R. Bates, A. E. Kingston and R. W. P. McWhirter, 1962b, Recombination between electrons and atomicions II. Optically thick plasmas, Proc. Roy. Soc. Lond., A 270: 155.
D. R. Bates, V. Malaviya and N. A. Young, 1971, Electron-ion recombination in a dense molecular gas, Proc. Roy. Soc., A 320: 437.
I. L. Beigman and B. N. Chichkov, 1980, Dielectronic recombination through the forbidden levels, J. Phys. B, 13: 565.
F. Bely-Dubau, A. H. Gabriel and S. Volonte, 1979, Dielectronic satellite spectra for highly charged helium-like ions V. Effect of total satellite contribution on the solar flare iron spectra, Hon. Not. Roy. Astron. Soc., 189: 801.
K. Berrington and M. Crees, 1979, R-matrix calculations for electron-molecule scattering, Comp. Phys. Commun., 17: 181.
C. Bottcher, 1976, Dissociative recombination of the hydrogen molecular ion, J. Phys. B, 9: 2899.
C. Bottcher, 1978, Dissociative recombination of large molecular ions, J. Phys. B, 11: 3887.
N. A. Burdett and A. N. Hayhurst, 1979, Determination of the rate coefficients of ion-pair production and ion-ion recombination in flames, Phil. Trans. Roy. Soc. Lond., 290: 300.
A. Burgess, 1964, Hydrogenic photoionization cross sections and recombination coefficients, Mem. Roy. Astron. Soc., 69: 1.
A. Burgess, 1964, Dielectronic recombination and the temperature of the solar corona, Astrophys. J., 139: 776.
A. Burgess, 1965, A general formula for the estimation of dielectronic recombination coefficients in low-density plasmas, Astrophys. J., 141: 1588.
A. Burgess and H. P. Summers, 1976, The recombination and level populations of ions I. Hydrogen and hydrogenic ions, Mon. Not. Roy. Astron. Soc., 174: 345.
A. Burgess and A. S. Tworkowski, 1976, Dielectronic recombination to form helium-like ions, Astrophys. J., 205: L105.
S. Byron, R. C. Stabler and P. I. Bortz, Electron-ion recombination by collisional and radiative processes, 1962, Phys. Rev. Lett., 8: 376.
T. Carrington, 1972, Radiative recombination of atoms as a resonance scattering process, J. Cliem. Phys., 57: 2033.
J. S. Cohen and J. N. Bardsley, 1978, Calculation of radiative single-charge-transfer cross sections for collisions of He++ with He at low energy, Phys. Rev. A, 18: 1004.
C. B. Collins, 1965, Collisional-dissociative recombination of electrons with molecular ions, Phys. Rev. A, 140: 1850.
P. C. Cosby, H. Helm and J. T. Moseley, 1980, Observation of pre-dissociated levels of CH+(A 1π) Astrophys. J., 235: 52.
J. Davis and J. Lewis, 1973, Continuum emission from recombining oxygen and nitrogen plasmas, J. Quant. Spectrosc. Radiat. Transfer 13: 871.
H. W. Drawin and F. Emard, 1978, Ground state populations of hydrogenic atoms in nonthermal plasmas, and collisional-radiative recombination and ionization coefficients, Physica, 94C: 134.
J. Dubau and S. Volonte, 1980, Dielectronic recombination and its applications in astronomy, Rep. Prog. Phys., 43: 199.
J. Dubau, M. Loulergue and L. Steenman-Clark, 1980, Calculations of the atomic parameters for the dielectronic satellite lines of the Mg Xll resonance line, Mon. Not. Roy. Astron. Soc. 190: 125.
M. Elitzur and W. D. Watson, 1978, Formation of molecular CH+ in interstellar shocks, Astrophys. J., 222: L141
U. Fano, 1961, Effects of configuration interaction on intensities and phase shifts, Phys. Rev., 124: 1866.
F. Fiquet-Fayard, 1974, Theoretical problems in the interpretation of dissociative attachment cross sections, Vacuum, 24: 533.
M. R. Flannery, 1976, Ionic Recombination, in “Atomic processes and applications”, P. G. Burke and B. L. Moiseiwitsch, eds., North-Holland, Amsterdam.
M. R. Flannery, 1978, Three-body ion-ion recombination in mercury- halide gas lasers, Chem. Phys. Lett., 56: 143.
M. R. Flannery, 1979, Atomic and molecular collision processes in rare-gas-halide lasers and rare-gas excimer lasers, Int. J. Quant. Chem. Symp., 13: 501.
M. R. Flannery and T. P. Yang, 1978a, Ionic recombination of rare-gas atomic ions X+ with F− in a dense gas X, Appl. Phys. Lett., 32: 327.
M. R. Flannery and T. P. Yang, 1978b, Ionic recombination of Kr+ and Kr2+ with F− in dense buffer rare gases, Appl. Phys. Lett., 33: 574.
L. Frommhold and H. M. Pickett, 1978, Rates of radiative recombination to form HD+ and HeH+, Chem. Phys., 28: 441.
J. N. Gau, Y. Hahn and J. A. Retter, 1980, Dielectronic recombination of positive ions III. Rate coefficients for Mo32+, J. Quant. Spectrosc. Radiat. Transfer, 23: 147.
A. Giusti-Suzor and H. Lefebvre-Brion, 1977, The dissociative recombination of CH+ ions, Astrophys. J. 214: L101.
A. Giusti-Suzor, E. Roueff and H. van Regeraorter, 1976, Comparison-between semi-classical and quantal calculations of the radiative association rate for CH+, J. Phys. B, 9: 1021.
R. J. Gould, 1978, Radiative recombination of complex ions, Astrophys. J., 219: 250.
G. Gousset, BVSayer and J. Berlande, 1977, Electron-Cs+-ion recombination in the presence of neutral helium atoms, Phys. Rev., A 16: 1070.
R. Grice and D. R. Herschbach, 1974, Long range configuration interaction of ionic and covalent states, Mol. Phys, 27: 159.
Y. Hahn and D. W. Rule, 1977, Direct radiative capture of high-energy electrons by atomic ions, J. Phys. B, 10: 2689.
Y. Hahn, J. N. Gau, R. Luddy and J. A. Retter, 1980, Scaling properties of the dielectronic recombination rate for the Ne-sequence, J. Quant. Spectrosc. Radlat. Transfer, 23: 65.
A. U. Hazi, 1978, A purely L2 method for calculating resonance widths, J. Phys. B., 11: L259.
A. P. Hickman, 1979, Approximate scaling formula for ion-ion mutual neutralization rates, J. Chem. Phys., 70: 4872.
C. M. Huang, M. A. Biondi and R. Johnsen, 1976, Recombination of electrons with NH4+ ·(NH3)n series ions, Phys. Rev. A 14: 984.
V. L. Jacobs and J. Davis, 1978, Effects of collisions on level populations and dielectronic recombination rates of multiply charged ions, Phys. Rev. A, 18: 697.
V. L. Jacobs, J. Davis, P. C. Kepple and M. Blaha, 1977a, The influence of autoionization accompanied by excitation on dielectronic recombination and ionization equilibrium, Astrophys. J., 211: 605.
V. L. Jacobs, J. Davis, P. C. Kepple and M. Blaha, 1977b, Dielectronic recombination and the ionization equilibrium of silicon ions, Astrophys. J., 215: 690.
R. K. Janev, 1976, On the long-range configuration interaction between ionic and covalent states, J. Chem. Phys. 64: 1891.
R. K. Janev and Z. M. Radulovic, 1977, Recombination of alkali positive and halogen negative ions, J. Chem. Phys., 67: 2856.
P. S. Julienne, J. Davis and E. Oran, 1974, Oxygen recombination in the tropical nightglow, J. Geophys. Res., 75: 3862.
K. Kirby, S. Guberman and A. Dalgarno, 1979, Resonant dissociative photoionization of H2, J. Chem. Phys., 70: 4635.
M. Krauss and P. S. Julienne, 1973, Dissociative recombination of e + CH+(X +1Σ+), Astrophys. J., 183: L139.
P. Langevin, 1902, Recherches sur les gaz ionisés, C.R. Acad. Sci., 134: 414.
C. M. Lee and R. H. Pratt, 1975, Radiative capture of high energy electrons, Phys. Rev. A, 12: 1825.
C. M. Lee and R. H. Pratt, 1976, Radiative capture of electrons by Mo ions, Phys. Rev. A., 14: 990.
M. T. Leu, M. A. Biondi and R. Johnsen, 1973, Measurements of the recombination of electrons with H30+·(H20)n — series ions, Phys. Rev. A, 7: 292.
R. Johnsen and M. A. Biondi, 1978, Measurements of radiative-charge transfer reactions of doubly and singly charged rare-gas ions with rare gas atoms at thermal energies, Phys. Rev. A, 18: 996.
L. C. Johnson and E. Hinnov, 1973, Ionization, recombination, and population of excited levels in hydrogen plasmas, J. Quant. Spectrosc. Radiat. Transfer, 13: 333.
P. Mansbach and J. Keck, 1969, Monte Carlo trajectory calculations of atonic excitation and ionization by thermal electrons, Phys. Rev., 181: 275.
T. M. Miller, 1980, Parametrization of ion-ion mutual neutralization rate coefficients, J. Chem. Phys., 72: 4659.
J. B. A. Mitchell and J. W. McGowan, 1978, The dissociative recombination of CH+ X 1Σ+ (v = 0), Astrophys. J., 222: L77.
J. T. Moseley, W. Aberth and J. R. Peterson, 1970, The H+−H− mutual neutralization cross section obtained with superimposed beams, Phys. Rev. Lett. 24: 435.
J. T. Moseley, R. E. Olson and J. R. Peterson, 1975, Ion-ion mutual neutralization, Case Studies in Atomic Physics, 5: 1.
G. L. Natanson,]959, The theory of volume recombination of ions, Sov. Phys.-Tech. Phys., 4: 1263.
W. L. Nighan, 1977, Influence of recombination and ion chemistry on the stability of externally sustained molecular discharges, Phys. Rev., A 16: 1209.
R. E. Olson, 1972, Absorbing sphere model for calculating ion-ion recombination total cross sections, J. Chem. Phys., 56: 2979.
R. E. Olson, 1977, Theoretical chemi-ionization and recombination cross sections for reactions of Na and K with Cℓ, Comb. Flame, 30: 243.
R. E. Olson, J. R. Peterson and J. T. Moseley, 1970, Ion-ion recombination total cross sections — atomic species, J. Chem. Phys., 53: 3391.
R. E. Olson, F. T. Smith and E. Bauer, 1971, Estimation of the coupling matrix elements for one-electron transfer systems, Appl. Optics, 10: 1848.
T. F. O’Mailey, A. J. Cunningham and R. M. Hobson, 1972, Dissociative recombination at elevated temperatures II. Comparison between theory and experiment in neon and argon afterglow, J. Phys. 3, 5: 2126.
R. T. Pack, R. L. Snow and W. D. Smith, 1972, On the mechanism of low-temperature termolecular atomic recombination, J. Chem. Phys., 56: 926.
L. P. Pitaevskii, 1962, Electron recombination in a monatomic gas, Soviet Phys. JETP, 15: 919.
D. E. Ramaker and J. M. Peek, 1976, Molecule formation in tenuous media:Quantum effects in spontaneous radiative association, Phys. Rev. A, 13: 58.
J. C. Raymond, 1978, On dielectronic recombination and resonances in excitation cross sections, Astrophys. J., 222: 1114.
M. J. Seaton, 1978, Calculated intensities of He II recombination lines in the ultraviolet, Mon. Not. Roy. Astron. Soc., 185: 5 p.
M. J. Seaton and.P. J. Storey, 1976, Dielectronic recombination, in “Atomic Processes and Applications”, P. G. Burke and B. L. Moiseiwitsch, eds., North Holland, Amsterdam, p. 133.
V. H. Shui and J. P. Appleton, 1971, Gas phase recombination of hydrogen. A comparison between theory and experiment, J. Chem. Phys., 55: 3126.
B. M. Smirnov, 1965, Formation and decay of negative ions, Sov. Phys.-Dokl., 10: 218.
B. M. Smirnov, 1977, Recombination of an electron and a complex ion, Sov. Phys. JETP, 45: 731.
W. H. Smith, H. S. Liszt and B. L. Lutz, 1973, Diatomic processes leading to CH and CH+ formation in the interstellar medium, Astrophys. J., 153: 69.
N. Snider, 1978, Bound complex and triple collision mechanisms for diatom dissociation and recombination, Can. J. Chem., 57: 1167.
P. M. Solomon and V. Klemperer, 1972, The formation of diatomic molecules in interstellar clouds, Astrophys. J., 178: 389.
J. Stevefelt, J. Boulmer and J. F. Delpech, 1975, Collisional-radiative recombination in cold plasmas, Phys. Rev. A, 12: 1246.
H. P. Summers, 1977, The recombination and level populations of ions II. Resolution of angular momentum states, Mon. Not. Roy. Astron. Soc., 178: 101.
H. Takagi and H. Nakamura, 1980, Elastic scattering of electrons from H2 +:Phaseshifts, quantum defects and two-electron excited states, J. Phys. B (in press).
J. J. Thomson, 1924, Recombination of gaseous ions, the chemical combination of gases and monomolecular reactions, Phil. Mag. Ser 6, 47: 337.
B. A. Tinsley, A. B. Christensen, J. Bittencourt, H. Gouvela, P. D. Andreji and H. Takahashi, 1973, Excitation of oxygen permitted line emissions in the tropical nightglow, J. Geophys. Res. 78: 1174.
J. M. Wadehra and J. N. Bardsley, 1978, Calculations of ion-ion recombination rates at high pressures, Appl. Phys. Lett., 32: 76.
L. P. Walkauskas and F. Kaufman, 1976, Measurement of ortho-para ratio in gas phase hydrogen atom recombination, J. Chem. Phys., 64: 3885.
J. C. Weisheit, 1975, Recombination in dense plasmas, J. Phys. B, 8: 2556.
J. C. Weisheit and N. F. Lane, 1971, Low energy elastic and fine-structure excitation scattering of ground state C+ ions by hydrogen atoms, Phys. Rev. A, 4: 171.
P. A. Whitlock, J. T. Muckerman and R. E. Roberts, 1974, Classical mechanics of recombination via the resonance mechanism: H + H + M → H2 + M, J. Chem. Phys., 60: 3658.
V. P. Zhdanov and M. I. Chibisov, 1978, Dissociative recombination of electrons with molecular ions involving the formation of excited states, Sov. Phys. JETP, 47: 38.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1982 Plenum Press, New York
About this chapter
Cite this chapter
Bardsley, J.N. (1982). Recombination Processes in Atomic and Molecular Physics. In: Gianturco, F.A. (eds) Atomic and Molecular Collision Theory. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3312-8_3
Download citation
DOI: https://doi.org/10.1007/978-1-4613-3312-8_3
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-3314-2
Online ISBN: 978-1-4613-3312-8
eBook Packages: Springer Book Archive