Abstract
Previously1 we have reported the new reaction of poly(alkyl vinyl ketone)s with active chlorides such as phosphoryl chloride, to obtain the corresponding poly(acyl actylene)s and later the changes in the electric conductivities of poly(ethyl vinyl ketone) films during the reaction with phosphoryl chloride were reported.2 The poly(ethyl vinyl ketone) film showed its specific conductivity of up to 10−2 Ω−1 cm−1 when reacted at 0°C after about 200 hours of reaction in petroleum ether. In this paper the electric conductivities of poly(methyl vinyl ketone), poly (ethyl vinyl ketone) and poly(phenyl vinyl ketone), which were reacted with phosphoryl chloride and thiophosphoryl chloride in solution and in the form of a film in non-solvent, are reported.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
T. Ogawa, R. Cedeño, T.E. Herrera; Makromol. Chem., 180, 785 (1979)
T. Ogawa, R. Cedeño, M. Inoue; Polymer Bulletin, 2, 275 (1980)
E.M. McMahon, J.N. Roper Jr, R.H. Harris, R.C. Brant; J.Am. Chem. Soc., 70, 2971 (1958)
C.H. Allen, W.E. Baker; J.Am.Chem.Soc., 54, 740 (1932)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1981 Plenum Press, New York
About this chapter
Cite this chapter
Ogawa, T., Cedeño, R., Herrera, T.E., Almaráz, B., Inoue, M. (1981). Electric Conductivities of Poly(Vinyl Ketone)S Reacted with Phosphoryl Chloride. In: Seymour, R.B. (eds) Conductive Polymers. Polymer Science and Technology, vol 15. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3309-8_9
Download citation
DOI: https://doi.org/10.1007/978-1-4613-3309-8_9
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-3311-1
Online ISBN: 978-1-4613-3309-8
eBook Packages: Springer Book Archive