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Extended Linear Chain Compounds pp 333–356Cite as

Structural Aspects of Iodine-Containing Low-Dimensional Materials

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Abstract

This chapter concerns the structural aspects of iodine-containing low-dimensional solids with particular emphasis on the arrangement of the iodine atoms. Many of the solids under consideration are cation radical salts with a high anisotropic conductivity. An impressive variety of cations occurs, ranging from transition metal complexes like Ni(dpg)2, Ni(bqd)2 and Pd(bqd)2 (dpg = diphenylglyoxime; bqd = 1,2-benzoquinonedigly-oxime) to organic molecules like tetrathiotetracene, trimesic acid, and perylene. Most known phases are binary, but multicomponent systems such as TMA+TCNQ2/3−(I3 −)1/3 (TMA = trimethylammonium, N(CH3)3H+; TCNQ = 7,7,8,8-tetracyano-p-quinodimethane) and K2Bz9I9·CHCl3(Bz = benzophenone) offer further variation in structural and physical properties. Though the conductivity process is frequently electronic, it appears predominantly ionic in the alkali-iodine-benzophenone complexes.1

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Authors and Affiliations

  1. Department of Chemistry, State University of New York, Buffalo, New York, 14214, USA

    Philip Coppens

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  1. Philip Coppens
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Editors and Affiliations

  1. Occidental Research Corporation, Irvine, California, USA

    Joel S. Miller

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© 1982 Plenum Press, New York

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Coppens, P. (1982). Structural Aspects of Iodine-Containing Low-Dimensional Materials. In: Miller, J.S. (eds) Extended Linear Chain Compounds. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3249-7_7

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  • DOI: https://doi.org/10.1007/978-1-4613-3249-7_7

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3251-0

  • Online ISBN: 978-1-4613-3249-7

  • eBook Packages: Springer Book Archive

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