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Thermodynamics of Aqueous Dilute Solutions of Non-Charged Molecules

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Advances in Solution Chemistry

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Abstract

The thermodynamic aspects of the dilute aqueous solutions of non-electrolytes have been largely investigated in the last years and many data are now at disposal concerning the thermodynamics functions \(\mathop {\Delta X}\nolimits_h^ \circ \) (X = G, H, S, Cp) for the transfer from gas to water and the limiting partial molar properties Φj° (j = v, Cp, Cv, E,k) in water on non-charged organic molecules. The state of the present knowledge of experimental data for classes of compounds is considered and the empirical or semiempirical ways the \(\mathop {\Delta X}\nolimits_h^ \circ \) and the Φj° quantities can be correlated with the molecular structure are analyzed and discussed. A short survey is finally given of the recent developments of the theories of the aqueous solutions and of the results obtained by applying the Monte Carlo and the molecular dynamics simulation methods to the study of water and aqueous solutions.

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  1. Istituto di Chimica Fisica dell’Università, Pisa, Italy

    Sergio Cabani

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  1. University of Florence, Florence, Italy

    I. Bertini  & A. Dei  & 

  2. University of Bologna, Bologna, Italy

    L. Lunazzi

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Cabani, S. (1981). Thermodynamics of Aqueous Dilute Solutions of Non-Charged Molecules. In: Bertini, I., Lunazzi, L., Dei, A. (eds) Advances in Solution Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3225-1_2

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