Abstract
The nuclear magnetic resonance of quadrupolar ions provides a wealth of information about solvation thermodynamics and dynamics. In this contribution, we consider the local ordering induced by an ion, surrounding itself with neutrals, solute or solvent molecules, in competition with its counter-ion. Examples include determination of the solvent electron-accepting, or hydrogen bond donor, abilities, anionic activation, and hydrophobic interactions involving Q+ cations, preferential solvation, and cation chelation, including that by calciproteins. Our approach is to describe the first solvation shell of an ion such as Na+ in specific terms, i.e. there are solvent molecules truly coordinated to the ion. Beyond this coordination sphere, we treat the solvent as a continuum, whose effects are estimated through bulk parameters such as the macroscopic viscosity η or the dielectric constant ε.
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Laszlo, P., Cornélis, A., Delville, A., Detellier, C., Gerstmans, A., Stockis, A. (1981). Direct NMR Studies of Ionic Solvation. In: Bertini, I., Lunazzi, L., Dei, A. (eds) Advances in Solution Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3225-1_13
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DOI: https://doi.org/10.1007/978-1-4613-3225-1_13
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