Skip to main content
SpringerLink
Log in

Direct NMR Studies of Ionic Solvation

  • Chapter
Advances in Solution Chemistry

Abstract

The nuclear magnetic resonance of quadrupolar ions provides a wealth of information about solvation thermodynamics and dynamics. In this contribution, we consider the local ordering induced by an ion, surrounding itself with neutrals, solute or solvent molecules, in competition with its counter-ion. Examples include determination of the solvent electron-accepting, or hydrogen bond donor, abilities, anionic activation, and hydrophobic interactions involving Q+ cations, preferential solvation, and cation chelation, including that by calciproteins. Our approach is to describe the first solvation shell of an ion such as Na+ in specific terms, i.e. there are solvent molecules truly coordinated to the ion. Beyond this coordination sphere, we treat the solvent as a continuum, whose effects are estimated through bulk parameters such as the macroscopic viscosity η or the dielectric constant ε.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. For reviews, see:

    Google Scholar 

  2. B. Lindman ans S. Forsen, “The Alkali Metals”, in “NMR and the Periodic Table”, R. K. Harris and B. E. Mann, eds., Academic Press, London, p. 129 (1978).

    Google Scholar 

  3. P. Laszlo, Nachricthen Chem. Tech. Lab. 27: 710 (1979).

    Article  CAS  Google Scholar 

  4. P. Laszlo, Bull. Magn. Resonance, in press.

    Google Scholar 

  5. J. B. Hubbard, P. Colonomos, and P. G. Wolynes, J. Chem. Phys. 71: 2652 (1979).

    Article  CAS  Google Scholar 

  6. B. P. Fabricand, S. S. Goldberg, R. Leifer, and S. G. Ungar, Mol. Phys. 7: 425 (1964).

    Article  CAS  Google Scholar 

  7. L. Lanatowicz and Z. Pajak, Chem. Phys. Lett. 38: 166 (1976)

    Article  Google Scholar 

  8. Z. Pajak and L. Lanatowicz, Acta Phys. Pol. A53: 555 (1978).

    Google Scholar 

  9. A. Delville, C. Detellier, A. GerStmans, and P. Laszlo, J. Am. Chem. Soc. submitted for publication.

    Google Scholar 

  10. A. Delville, C. Detellier, A. Gerstmans, and P. Laszlo, J. Am. Chem. Soc. submitted for publication.

    Google Scholar 

  11. A. V. Hill, J. Physiol. (London), 40: IV (1910).

    Google Scholar 

  12. R. H. Erlich and A. I. Popov, J. Am. Chem. Soc. 93: 5620 (1971).

    Article  CAS  Google Scholar 

  13. R. J. P. Williams, Biol. Rev. 54: 389 (1979).

    Article  CAS  Google Scholar 

  14. J. Grandjean, P. Laszlo, and C. Gerday, FEBS Letters, 81: 376 (1977).

    Article  CAS  Google Scholar 

  15. J. Grandjean and P. Laszlo, in “Ions and Protons Involved in Fast Dynamic Phenomena”, P. Laszlo, ed., Elsevier, Amsterdam, p. 373 (1978).

    Google Scholar 

  16. C. Gerday, J. Grandjean, and P. Laszlo, FEBS Letters, 105: 384 (1979).

    Article  CAS  Google Scholar 

  17. A. Delville, J. Grandjean, P. Laszlo, C. Gerday, Z. Grabarek, and W. Drabikowski, Eur. J. Biochem. 105: 289 (1980).

    Article  CAS  Google Scholar 

  18. A. Delville, J. Grandjean, P. Laszlo, C. Gerday, H. Brzeska, and W. Drabikowski, Eur. J. Biochem. submitted for publication.

    Google Scholar 

  19. A. Paris and P. Laszlo, A.C.S. Symposium Series, N. 34, H. A. Resing and Ch. G. Wade, eds., Washington, p. 418 (1976).

    Google Scholar 

  20. T. J. Pinnavaia, H. T. Miles, and E. D. Becker, J. Am. Chem. Soc. 97: 7198 (1975).

    Article  CAS  Google Scholar 

  21. W. Guschlbauer and J. F. Chantot, in “Proceedings of the International Conference” held in Dymaczewo near Poznan, 13–17.9.1976, Poznan, p. 96.

    Google Scholar 

  22. H. T. Miles and J. Frazie, Biochem. Biophys. Res. Comm. 49: 199 (1972).

    Article  CAS  Google Scholar 

  23. D. M. Gray and F. J. Bollum, Biopolymers, 13: 2087 (1974).

    Article  CAS  Google Scholar 

  24. M. Hattri, J. Frazier, and H. T. Miles, Biochemistry, 14: 5033 (1975).

    Article  Google Scholar 

  25. T. Golas, M. Fikus, Z. Kazimerczuk, and D. Shugar, Eur. J. Biochem. 65: 183 (1976).

    Article  CAS  Google Scholar 

  26. F. B. Howard, J. Frazier, and H. T. Miles, Biopolymers, 16: 791 (1977).

    Article  CAS  Google Scholar 

  27. A. Yamada, K. Akasaka, and H. Hatano, Biopolymers, 17: 749 (1978).

    Article  CAS  Google Scholar 

  28. S. Arnott, R. Chandrasekaran, and C. M. Martilla, Biochem. J. 141: 537 (1974).

    CAS  Google Scholar 

  29. S. B. Zimmerman, G. H. Cohn, and D. J. Davies, J. Mol. Biol. 92: 181 (1975).

    Article  CAS  Google Scholar 

  30. S. B. Zimmerman, J. Mol. Biol. 106: 663 (1976).

    Article  CAS  Google Scholar 

  31. M. Calvin, Angew. Chem. Int. Ed. Engl. l2: 12L (1975).

    Google Scholar 

  32. M. Calvin, “Chemical Evolution. Molecular Evolution towards the Origin of Living Systems on the Earth and Elsewhere”, Clarendon Press, Oxford (1969).

    Google Scholar 

  33. C. C. Price, ed., “Synthesis of Life”, Dowden, Hutchinson, and Ross, Stroudsburg, Pa. (1974).

    Google Scholar 

  34. T. H. Jukes, R. Holmquist, and H. Moise, Science, 189: 50 (1975).

    Article  CAS  Google Scholar 

  35. F. T. Mackenzie, in “Chemical Oceanography”, 2nd ed., Vol. 1, J. P. Riley and G. Skirrow, eds., Academic Press, London, p. 309 (1975).

    Google Scholar 

  36. J. D. Burton, Chem. Ind. (London), 550 (1977).

    Google Scholar 

  37. P. Laszlo and A. Paris, Compt. Rend. Acad. Sci. Paris, 286D: 717 (1978).

    CAS  Google Scholar 

  38. M. Borzo, C. Detellier, P. Laszlo, and A. Paris, J. Am. Chem. Soc. 102: 1124 (1980).

    Article  CAS  Google Scholar 

  39. T. J. Pinnavia, C. L. Marshall, C. M. Mettler, C. L. Fisk, H. T. Miles, and E. D. Becker, J. Am. Chem. Soc. 100: 3625 (1978).

    Article  Google Scholar 

  40. C. Detellier, A. Paris, and P. Laszlo, Compt. Rend. Ac. Sci. Paris, 286D: 781 (1978).

    CAS  Google Scholar 

  41. M. Borzo and P. Laszlo, Compt. Rend. Ac. Sci. Paris, 287C: 475 (1978).

    CAS  Google Scholar 

  42. A. Delville, C. Detellier, and P. Laszlo, J. Magn. Res., 34: 301 (1979).

    CAS  Google Scholar 

  43. C. Detellier and P. Laszlo, J. Am. Chem. Soc. 102: 1135 (1980).

    Article  CAS  Google Scholar 

  44. A. W. Hanson, Acta Cryst. 17: 559 (1964).

    Article  CAS  Google Scholar 

  45. B. T. Kilbourn, J. D. Dunitz, L. A. R. Pioda, and W. Simon, J. Mol. Biol. 30:559 (1967); M. Pinkerton, L. K. Stein- rauf, and P. Dawkins, Biochem. Biophys. Res. Comm. 35: 512 (1969); M. Dobler, J. D. Dunitz, and J. Krajewski, J. Mol. Biol. 42:603 (1969).

    Article  CAS  Google Scholar 

  46. P. Laszlo and P. Rinaldi, unpublished results.

    Google Scholar 

  47. C. Detellier and P. Laszlo, Helv. Chim. Acta, 62: 1559 (1979).

    Article  CAS  Google Scholar 

  48. R. H. Lemmon, Chem. Rev. 70: 95 (1979).

    Article  Google Scholar 

  49. A. Brack dnd L. E. Orgel, Nature (London), 256: 383 (1975).

    Article  CAS  Google Scholar 

  50. M. F. Perutz, Science, 201: 1187 (1978).

    Article  CAS  Google Scholar 

  51. A. Cornelis and P. Laszlo, J. Chem. Res. (S) 462 (1978); (M) 5457 (1978).

    Google Scholar 

  52. C. L. Liotta, E. E. Grisdale, and H. P. Hopkins, Jr., Tet. Letters (48), 4205 (1975).

    Google Scholar 

  53. G. W. Gokel and W. P. Weber, J. Chem. Ed. 55: 350; 429 (1978).

    Article  Google Scholar 

  54. A. W. Herriott and D. Picker, J. Am. Chem. Soc. 97: 2345 (1975).

    Article  CAS  Google Scholar 

  55. E. M. Arnett, M. Ho, and L. L. Schaleger, J. Am. Chem. Soc. 92: 7039 (1970).

    Article  CAS  Google Scholar 

  56. S. J. Rehfeld, J. Am. Chem. Soc. 95: 4489 (1973).

    Article  CAS  Google Scholar 

  57. R. Zana, J. Phys. Chem. 81: 1817 (1977).

    Article  CAS  Google Scholar 

  58. P. Laszlo and A. Stockis, to be published.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut de Chimie et de Biochimie (B6), Université de Liège, Sart-Tilman, B-4000, Liège, Belgium

    Pierre Laszlo, André Cornélis, Alfred Delville, Christian Detellier, André Gerstmans & Armel Stockis

Authors
  1. Pierre Laszlo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. André Cornélis
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Alfred Delville
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Christian Detellier
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. André Gerstmans
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Armel Stockis
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. University of Florence, Florence, Italy

    I. Bertini  & A. Dei  & 

  2. University of Bologna, Bologna, Italy

    L. Lunazzi

Rights and permissions

Reprints and permissions

Copyright information

© 1981 Plenum Press, New York

About this chapter

Cite this chapter

Laszlo, P., Cornélis, A., Delville, A., Detellier, C., Gerstmans, A., Stockis, A. (1981). Direct NMR Studies of Ionic Solvation. In: Bertini, I., Lunazzi, L., Dei, A. (eds) Advances in Solution Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3225-1_13

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-3225-1_13

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3227-5

  • Online ISBN: 978-1-4613-3225-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation