Abstract
The occurrence of intramolecular ligand-ligand interactions in ternary complexes in solution leads to an intramolecular equilibrium between two isomeric complexes, i.e. between an ‘open’ and a ‘closed’ species. The source of the ligand-ligand interaction in the ‘closed’ isomer may be (aside from covalent bond formation, ionic interactions and hydrogen bond formation) a hydrophobic or aromatic-ring stacking interaction between suitable groups of the two different ligands already coordinated to the same metal ion, e.g. between the indole moiety of tryptophanate and the purine moiety of adenosine 5′-triphosphate. More such example are listed and discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
H. Sigel, ed., “Mixed-Ligand Complexes”, Vol., 2 of the Series “Metal Ions in Bioligical Systems”, Marcel Dekker, Inc., New York and Basel (1973).
H. Sigel, Plenary Lecture, Conference Volume of the XXth Internat. Conf. on Coord. Chem.( Dec. 1979, Calcutta), D. Banerjea, ed., published by I.U.P.A.C through Pergamon Press, Oxford.
H. Sigel, Chimia, 21: 489 (1967).
R. B. Martin and R. Prados, J. Inorg. Nucl. Chem. 36: 1665 (1974).
H. Sigel, Angew. Chem. 87:391 (1975); Angew. Chem. Internat. Edit. 14: 394 (1975).
G. Brookes and L. D. Pettit, J.C.S. Dalton Trans. 1918 (1977).
H. Sigel, “Structural Aspects of Mixed-Ligand Complex Formation in Solution”, p. 63 or ref. 1.
H. Sigel, B. E. Fischer, and B. Prijs, J. Am. Chem. Soc. 99: 4489 (1977).
H. Sigel, Inorg. Chem. 19: 1411 (1980).
D. L. Leussing, “The Formation of Schiff Bases in the Coordination Sphere of Metal Ions” in Vol. 5 of “Metal Ions in Biological Systems”, H. Sigel ed., Marcel Dekker, Inc., New York and Basel, p.l (1976).
T. Sakurai, O. Yamauchi, and A. Nakahara, Bull. Chem. Soc. Jpn. 51: 3203 (1978).
KH. Scheller, THJ. Abel, PE. Polanyi, PK. Wenk, BE. Fischer, and H. Sigel, Eur. J. Biochem. in press (1980).
L. G. Marzilli and T. J. Kistenmacher, Accounts Chem. Res. 10: 146 (1977).
Y. H. Mariam and R. B. Martin, Inorg. Chim. Acta, 35: 23 (1979).
H. Sigel, K. H. Scheller, V. M. Rheinberger, and B. E. Fischer, J.C.S. Dalton Trans. 1022 (1980).
J. B. Orenberg, B. E. Fischer, and H. Sigel, J. inorg. Nucl. Chem. 42: 785 (1980).
B. E. Fischer and H. Sigel, J. Am. Chem. Soc. 102: 2998 (1980).
P. R. Mitchell, B. Prijs, and H. Sigel, Helv. Chim. Acta, 62: 1723 (1979).
C. F. Naumann, B. Prijs, and H. Sigel, Eur. J. Biochem. 41: 209 (1974).
C. F. Naumann and H. Sigel, J. Am. Chem. Soc. 96: 2750 (1974).
P. Chaudhuri and H. Sigel, J. Am. Chem. Soc. 99: 3142 (1977).
H. Sigel and C. F. Naumann, J. Am. Chem. Soc. 98: 730 (1976).
R. Basosi, E. Gaggelli, and E. Tiezzi, J. Chem. Research (S), 278 (1977).
Y. Fukuda, P. R. Mitchell, and H. Sigel, Helv. Chim. Acta, 61: 638 (1978).
J.-J. Toulmé, Bioinorg. Chem. 8: 319 (1978).
P. R. Mitchell and H. Sigel, J. Am. Chem. Soc. 100: 1564 (1978).
E. Farkas, B. E. Fisher, R. Griesser, V. M. Rheinberger, and H. Sigel, Z. Naturforsch, 34: 208 (1979).
R. Basosi, E. Gaggelli, and G. Valensin, J. Inorg. Biochem. 10: 101 (1979).
B. E. Fischer and R. Bau, J.C.S. Chem. Commun. 272 (1977).
K. Aoki, J.C.S. Chem. Commun. 600 (1977).
R. W. Geliert and R. Bau, “X-Ray Structural Studies of Metal-Nucleoside ond Metal-Nucleotide Complexes” in Vol. 8 of “Metal Ions in Biological Systems”, H. Sigel, ed., Marcel Dekker, Inc., New York and Basel, p. 1 (1979).
P. Orioli, R. Cini, D. Donati and S. Mangani, Nature, 283: 691 (1980).
K. Aoki, J. Am. Chem. Soc. 100: 7106 (1978).
C. -Y. Wei, B. E. Fischer, and R. Bau, J.C.S. Chem. Commun. 1053 (1978).
K. H. Scheller, Ph. D. Thesis, University of Basel, 1978.
U. K. Häring, K. H. Scheller, and H. Sigel, details to be published.
P. R. Mitchell and H. Sigel, Angew. Chem. 88:585 (1976); Angew. Chem. Internat. Edit. 15: 548 (1976).
P. R. Mitchell, J.C.S. Dalton, 771 (1979).
K. H. Scheller and H. Sigel, to be published.
B. E. Fischer and H. Sigel, XIXth Internat. Conf. Coord. Chem. Prague, Proceedings II, p. 42a (1978).
H. A. Scheraga, Accounts Chem. Res. 12: 7 (1979).
A. Gergely, I. Sovago, I. Nagypal, and R. Kiraly, Inorg. Chim. Acta, 6: 435 (1972).
L. M. Jackman and S. Sternhell, “Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry”, 2nd ed., Pergamon Press, Oxford, p. 94 (1969).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1981 Plenum Press, New York
About this chapter
Cite this chapter
Sigel, H. (1981). Intramolecular Hydrophobic and Aromatic-Ring Stacking Interactions in Ternary Complexes in Solution. In: Bertini, I., Lunazzi, L., Dei, A. (eds) Advances in Solution Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3225-1_11
Download citation
DOI: https://doi.org/10.1007/978-1-4613-3225-1_11
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-3227-5
Online ISBN: 978-1-4613-3225-1
eBook Packages: Springer Book Archive