Skip to main content
SpringerLink
Log in

Intramolecular Hydrophobic and Aromatic-Ring Stacking Interactions in Ternary Complexes in Solution

  • Chapter
Advances in Solution Chemistry

Abstract

The occurrence of intramolecular ligand-ligand interactions in ternary complexes in solution leads to an intramolecular equilibrium between two isomeric complexes, i.e. between an ‘open’ and a ‘closed’ species. The source of the ligand-ligand interaction in the ‘closed’ isomer may be (aside from covalent bond formation, ionic interactions and hydrogen bond formation) a hydrophobic or aromatic-ring stacking interaction between suitable groups of the two different ligands already coordinated to the same metal ion, e.g. between the indole moiety of tryptophanate and the purine moiety of adenosine 5′-triphosphate. More such example are listed and discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. H. Sigel, ed., “Mixed-Ligand Complexes”, Vol., 2 of the Series “Metal Ions in Bioligical Systems”, Marcel Dekker, Inc., New York and Basel (1973).

    Google Scholar 

  2. H. Sigel, Plenary Lecture, Conference Volume of the XXth Internat. Conf. on Coord. Chem.( Dec. 1979, Calcutta), D. Banerjea, ed., published by I.U.P.A.C through Pergamon Press, Oxford.

    Google Scholar 

  3. H. Sigel, Chimia, 21: 489 (1967).

    CAS  Google Scholar 

  4. R. B. Martin and R. Prados, J. Inorg. Nucl. Chem. 36: 1665 (1974).

    Article  CAS  Google Scholar 

  5. H. Sigel, Angew. Chem. 87:391 (1975); Angew. Chem. Internat. Edit. 14: 394 (1975).

    Article  Google Scholar 

  6. G. Brookes and L. D. Pettit, J.C.S. Dalton Trans. 1918 (1977).

    Google Scholar 

  7. H. Sigel, “Structural Aspects of Mixed-Ligand Complex Formation in Solution”, p. 63 or ref. 1.

    Google Scholar 

  8. H. Sigel, B. E. Fischer, and B. Prijs, J. Am. Chem. Soc. 99: 4489 (1977).

    Article  CAS  Google Scholar 

  9. H. Sigel, Inorg. Chem. 19: 1411 (1980).

    Article  CAS  Google Scholar 

  10. D. L. Leussing, “The Formation of Schiff Bases in the Coordination Sphere of Metal Ions” in Vol. 5 of “Metal Ions in Biological Systems”, H. Sigel ed., Marcel Dekker, Inc., New York and Basel, p.l (1976).

    Google Scholar 

  11. T. Sakurai, O. Yamauchi, and A. Nakahara, Bull. Chem. Soc. Jpn. 51: 3203 (1978).

    Article  CAS  Google Scholar 

  12. KH. Scheller, THJ. Abel, PE. Polanyi, PK. Wenk, BE. Fischer, and H. Sigel, Eur. J. Biochem. in press (1980).

    Google Scholar 

  13. L. G. Marzilli and T. J. Kistenmacher, Accounts Chem. Res. 10: 146 (1977).

    Article  CAS  Google Scholar 

  14. Y. H. Mariam and R. B. Martin, Inorg. Chim. Acta, 35: 23 (1979).

    Article  CAS  Google Scholar 

  15. H. Sigel, K. H. Scheller, V. M. Rheinberger, and B. E. Fischer, J.C.S. Dalton Trans. 1022 (1980).

    Google Scholar 

  16. J. B. Orenberg, B. E. Fischer, and H. Sigel, J. inorg. Nucl. Chem. 42: 785 (1980).

    Article  CAS  Google Scholar 

  17. B. E. Fischer and H. Sigel, J. Am. Chem. Soc. 102: 2998 (1980).

    Article  CAS  Google Scholar 

  18. P. R. Mitchell, B. Prijs, and H. Sigel, Helv. Chim. Acta, 62: 1723 (1979).

    Article  CAS  Google Scholar 

  19. C. F. Naumann, B. Prijs, and H. Sigel, Eur. J. Biochem. 41: 209 (1974).

    Article  CAS  Google Scholar 

  20. C. F. Naumann and H. Sigel, J. Am. Chem. Soc. 96: 2750 (1974).

    Article  CAS  Google Scholar 

  21. P. Chaudhuri and H. Sigel, J. Am. Chem. Soc. 99: 3142 (1977).

    Article  CAS  Google Scholar 

  22. H. Sigel and C. F. Naumann, J. Am. Chem. Soc. 98: 730 (1976).

    Article  CAS  Google Scholar 

  23. R. Basosi, E. Gaggelli, and E. Tiezzi, J. Chem. Research (S), 278 (1977).

    Google Scholar 

  24. Y. Fukuda, P. R. Mitchell, and H. Sigel, Helv. Chim. Acta, 61: 638 (1978).

    Article  CAS  Google Scholar 

  25. J.-J. Toulmé, Bioinorg. Chem. 8: 319 (1978).

    Article  Google Scholar 

  26. P. R. Mitchell and H. Sigel, J. Am. Chem. Soc. 100: 1564 (1978).

    Article  CAS  Google Scholar 

  27. E. Farkas, B. E. Fisher, R. Griesser, V. M. Rheinberger, and H. Sigel, Z. Naturforsch, 34: 208 (1979).

    Google Scholar 

  28. R. Basosi, E. Gaggelli, and G. Valensin, J. Inorg. Biochem. 10: 101 (1979).

    Article  CAS  Google Scholar 

  29. B. E. Fischer and R. Bau, J.C.S. Chem. Commun. 272 (1977).

    Google Scholar 

  30. K. Aoki, J.C.S. Chem. Commun. 600 (1977).

    Google Scholar 

  31. R. W. Geliert and R. Bau, “X-Ray Structural Studies of Metal-Nucleoside ond Metal-Nucleotide Complexes” in Vol. 8 of “Metal Ions in Biological Systems”, H. Sigel, ed., Marcel Dekker, Inc., New York and Basel, p. 1 (1979).

    Google Scholar 

  32. P. Orioli, R. Cini, D. Donati and S. Mangani, Nature, 283: 691 (1980).

    Article  CAS  Google Scholar 

  33. K. Aoki, J. Am. Chem. Soc. 100: 7106 (1978).

    Article  CAS  Google Scholar 

  34. C. -Y. Wei, B. E. Fischer, and R. Bau, J.C.S. Chem. Commun. 1053 (1978).

    Google Scholar 

  35. K. H. Scheller, Ph. D. Thesis, University of Basel, 1978.

    Google Scholar 

  36. U. K. Häring, K. H. Scheller, and H. Sigel, details to be published.

    Google Scholar 

  37. P. R. Mitchell and H. Sigel, Angew. Chem. 88:585 (1976); Angew. Chem. Internat. Edit. 15: 548 (1976).

    Article  Google Scholar 

  38. P. R. Mitchell, J.C.S. Dalton, 771 (1979).

    Google Scholar 

  39. K. H. Scheller and H. Sigel, to be published.

    Google Scholar 

  40. B. E. Fischer and H. Sigel, XIXth Internat. Conf. Coord. Chem. Prague, Proceedings II, p. 42a (1978).

    Google Scholar 

  41. H. A. Scheraga, Accounts Chem. Res. 12: 7 (1979).

    Article  CAS  Google Scholar 

  42. A. Gergely, I. Sovago, I. Nagypal, and R. Kiraly, Inorg. Chim. Acta, 6: 435 (1972).

    Article  CAS  Google Scholar 

  43. L. M. Jackman and S. Sternhell, “Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry”, 2nd ed., Pergamon Press, Oxford, p. 94 (1969).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Inorganic Chemistry, University of Basel, Spitalstrasse 51, CH-4056, Basel, Switzerland

    Helmut Sigel

Authors
  1. Helmut Sigel
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. University of Florence, Florence, Italy

    I. Bertini  & A. Dei  & 

  2. University of Bologna, Bologna, Italy

    L. Lunazzi

Rights and permissions

Reprints and permissions

Copyright information

© 1981 Plenum Press, New York

About this chapter

Cite this chapter

Sigel, H. (1981). Intramolecular Hydrophobic and Aromatic-Ring Stacking Interactions in Ternary Complexes in Solution. In: Bertini, I., Lunazzi, L., Dei, A. (eds) Advances in Solution Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3225-1_11

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-3225-1_11

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3227-5

  • Online ISBN: 978-1-4613-3225-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation