Abstract
The thermodynamic description of alloy systems has been and still is in terms of phenomenological thermodynamics. The chemical potential, µ αi , of a component i in the alloy phase α as a function of composition and temperature is in principle a sufficient property to characterize the alloy system. Hence the development of experimental methods specific to alloy thermodynamics has been in obtaining more reliable chemical potential data over wider temperature and composition ranges. No single experimental method has been proved suitable for the study of the varieties of alloys encountered in practice.
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Chandrasekharaiah, M.S., Sreedharan, O.M., Chattopadhyay, G. (1980). Thermodynamic Studies of Alloys and Intermetallic Compounds. In: Subbarao, E.C. (eds) Solid Electrolytes and Their Applications. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3081-3_3
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