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Defect Structure and Transport Properties

  • Chapter
Solid Electrolytes and Their Applications

Abstract

Point defects are primarily responsible for electrical conduction in solid electrolytes. Ionic solids contain these defects at all temperatures above 0°K. Aliovalent impurities also introduce excess defects whose concentration is fixed mainly by composition and is often independent of temperature. Presence of ionic defects gives rise to ionic conductivity, while that of electronic defects results in electronic conductivity, which is undesirable in a solid electrolyte. In practice, for a solid electrolyte to be useful, the ratio of ionic to electronic conductivity should be 100 or greater.

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Author notes

  1. C. B. Choudhary

    Present address: Research and Development, Hindustan Steel Ltd., 834002, Ranchi, India

  2. H. S. Maiti

    Present address: Materials Science Centre, Indian Institute of Technology, 721302, Kharagpur, India

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  1. Department of Metallurgical Engineering, Indian Institute of Technology, Kanpur, 208016, India

    C. B. Choudhary, H. S. Maiti & E. C. Subbarao

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    E. C. Subbarao

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Choudhary, C.B., Maiti, H.S., Subbarao, E.C. (1980). Defect Structure and Transport Properties. In: Subbarao, E.C. (eds) Solid Electrolytes and Their Applications. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3081-3_1

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