Abstract
Large quantities of chlorine are produced in the United States each year. A by-product of industrial use and manufacture is that some chlorine gas escapes into the atmosphere. However, a general lack of information exists on precipitation washout of these oxidant residuals despite recognized emissions into the atmosphere. It is hypothesized that acid precipitation is only an indicator of other less obvious phenomena,and the pH of precipitation may well serve as an index of a variety of atmospheric pollutant problems.
Significant inputs of chlorine gas are emitted into the atmosphere in New York State; the major source of chlorine emissions occurs in Niagara County, New York. Oxidant residuals have been measured in rainfall from Central New York. Maximum residuals in rainfall coincided with depressed pH values and maximum rainwater temperature. The observed chlorine residuals and dominance of NH3 ions in rainfall suggest the residual may be a combined form of the type NHxCly. One hypothesis is that industrial emissions of this gas combine with NH3 in the atmosphere to form NHxCly compounds or chloramines which are later removed by atmospheric washout.
Laboratory and field studies reported in the literature suggest that oxidant residuals are toxic to biological organisms and the impact is highly dependent on concentration and duration of exposure. In dilute aquatic systems of low buffering capacity, measured oxidant residuals can potentially affect biological organisms and may pose a new element of concern.
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References
American Public Health Association, 1971. Standard Methods for the Examination of Water and Wastewater. 13th ed. Amer. Public Health Assoc., Washington, D.C. 874 p.
Anonymous. 1976. Chlorine and hydrogen chloride. Medical and biologic effects of environmental pollutants. National Academy of Sciences. Washington, D.C. 1976.
Arthur, J. W. 1972. Progress Report. National Water Quality Lab., EPA, Duluth, Minn. (1971–1972)
Arthur, J. U. and J. G. Eaton, 1971. Chloramine toxicity to the amphjpod (Gammarus pseudolimnaeus)and the fathead minnow (Pinephales promelas) J. Fish. Res. Bd. Canada. 28: 1841–1845.
Arthur, J. W., R. Andrew, V. Mattson, D. Olson, G. Glass, B. Halligan, and C. Walbridge. 1975. Comparative toxicity of sewage-effluent disinfection to freshwater aquatic life. Environmental Protection Agency, Ecological Research Series, Dgluth, Minn. 62 pp.
Bash, R. E. and J. G. Truchan, 1976. Toxicity of chlorinated power plant cooling waters to fish. Environmental Protection Agency, Ecological Research Series R-800700. Duluth, Minn. 75 pp.
Brooks, A. S. and G. L. Seegert, 1976. Toxicity of chlorine to freshwater organisms under varying environmental conditions. Proc. Confr. on environmental impact of water chlorination, Oak Ridge Nat’l Lab., Oak Ridge, Tenn.
Brooks, A. S. and G. L. Seegert, 1978. The effects of intermittent chlorination on selected warmwater fishes. Center for Great Lakes Studies, Univ. of Wisconsin-Milwaukee. Special Report No. 35. 45 pp.
Brungs, W. A. 1973. Effects of residual chlorine on aquatic life. Jour. Water Pollution Control Fed. 45 (10): 2180–2193.
Buckley, J.A., L. M. Whitmore, and R. I. Matsuda. 1976. Changes in blood chemistry and blood cell physiology in Coho salmon (Oncorhynchus kisutch) following exposure to sublethal levels of total residual chlorine in municipal wastewater. J. Fish. Res. Board Can. 33: 776–782.
Coventry, F. L. 1935. The conditioning of a chloramine treated water supply for biological purposes. Ecology. 16: 60.
Dandy, J. W. T. 1972. Activity response to chlorine in the brook trout. Salvelinius fontinalis (Mitchell). Can. Jour. Zool. 50: 405.
Dondoroff, P. and M. Katz, 1950. Critical review of literature on the toxicity of industrial wastes and their components to fish. Sew. and Ind. Wastes 22: 1432.
Duce, R. A., J. W. Winchester, and T. W. Van Nohl, 1965. Iodine, bromine, and chlorine in the Hawaiian marine atmosphere. J. Geophys. Res. 70: 1775–1799.
Duce, R. A. 1969. On the source of gaseous chlorine in the marine atmosphere. J. Geophys. Res. 74: 4597–4599.
Environmental Protection Agency. 1969. Water Chlorine (Residual) Study No. 35. Cincinnati, Ohio.
Eppley, R. W., E. H. Renger, and P.M. Williams. 1976. Chlorine reactions with seawater constituents and the inhibition of photosynthesis of natural marine phytoplankton. Est. and Coastal Mar. Sci. 4 (2) 147–161.
Eren, Y. and Y. Langer, 1973. The effect of chlorination on Tilapia fish. Bamidgeh. 25: 56–60.
Erikson, E. 1960. The yearly circulation of chloride and sulfur in nature; meteorological, geochemical, and pedological implications. Part II. Tellus 12: 63–109.
Giddings, J. and J. N. Galloway, 1976. The effects of acid precipitation on aquatic and terrestrial ecosystems, p. 1 - 32. In Literature reviews on acid precipitation. Center for environmental quality management, and the water resources and Marine Sciences Center. Cornell University, Ithaca, N.Y.
Heath, A. G. 1977. Toxicity of intermittent chlorina- tion to freshwater fish; influence of temperature and chlorine form. Hydrobiologia 56: 39–47.
Holland, G. A., J. E. Lasater, E. D. Newmann, and W. E. Eldridge, 1960. Toxic effects of organic and inorganic pollutants on young salmon and trout. State of Wash., Dept. Fish; Res. Bull. (5) 198–214.
Junge, C. E. 1956. Recent investigations in air chemistry. Tellus 8: 127–139.
Junge, C. E. 1957. Chemical analysis of aerosol particles and of gas traces on the island of Hawaii, Tellus. 9: 528–537.
Lamb, N. J. 1978. The effects of experimental chlorination on freshwater organisms in McCorVi Creek, New York. PhD. Thesis. Cornell University. Ithaca, New York. 198 pp.
Lawrence, C. A. and S. S. Block, 1968. Disinfection, sterilization, and preservation. Lea and Febiger. 808 pp.
Lunde, G., J. Gether, N. Gjjzfs, and M. B. S. Lande. 1977. Organic micro pollutants in precipitation in Norway. Atmos. Environ. 11 (11) 1007–1014.
Merkens, J. C. 1958. Studies on the toxicity of chlorine and chloramines to the rainbow trout. Water and Waste Trt. Jour. 7: 150.
Moore, E. N., 1951. Fundamentals of chlorination of sewage and waste. Water and Sewage Works. 98: 130.
Morris, J. C. 1971. Chlorination and disinfection - State-of-the-Art. Jour. Amer. Water Works Assn. 63: 769.
Neiburger, M., Edinger, J. G., W. D. Bonner, 1973. Under-standing Our Atmospheric Environment. W. H. Freeman and Co., San Francisco.
Palen, A. T. 1957. The determination of free and combined chlorine in water by the use of diethyl-p-phenylene diamine. J. Amer. Water Works Assoc. 49 (873).
Petriconi, G. L. and H. M. Papee, 1972. On the photolytic separation of halogens from sea water concentrates. Water, Air, Soil Pollut. 1: 117–131.
Schofield, C. L. 1976. Acid precipitation. Effects on Fish. Ambio. 5 (5–6): 228–230.
Sprague, J. B. and D. E. Drury, 1969. Avoidance reactions of salmonid fish to representative pollutants. In Advances in Water Pollution Research. Proc. 14th Intl. Conf. Water Poll. Res. Pergamon Press, London, England, 169 pp.
Stahl, Q. R. 1969. Preliminary air pollution survey of chlorine gas. A literature review. National Air Pollution Control Administration Publication No. APTD69-33. Springfield, Virginia: Clearinghouse for Federal Scientific and Technical Information. 79 pp.
Stoler, Q. J. and C. H. Hanson. 1974. Toxicity of chlorine and heat to pink (Oncorhynchus gorbuscha) and chinook (0. tshawytscha) salmon. Trans. Amer. Fish. Soc. 103: 569–576.
Strom, G. H. 1968. Atmospheric dispersion of stack effluents p. 227–274. In A. C. Stern, ed. Air Pollution. Vol. I. Air Pollution and its effects ( 2d Ed.) Academic Press, New York.
Wanta, R. C. 1968. Meteorology and air pollution, p. 187–226. In A. C. Stern, ed. Air pollution. Vol. I. Air Pollution and its effects ( 2d ed.) Academic Press, New York.
Zafiriow, 0. C. 1974. Photochemistry of halogens in the marine atmosphere. J. Geophys. Res. 79: 1730–2732.
Zillich, J. A. 1972. Toxicity of combined chlorine residuals to freshwater fish. J. Water Poll. Control Fed. 44: 212–220.
Zimmerman, G. and F. C. Strong. 1957. Equilibria and Spectra of Aqueous Chlorine Solutions. J. Phys. Chem. 79: 2063.
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Mills, E.L., Murphy, C.B., Bloomfield, J.A. (1980). Oxidants in Precipitation. In: Toribara, T.Y., Miller, M.W., Morrow, P.E. (eds) Polluted Rain. Environmental Science Research. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3060-8_19
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DOI: https://doi.org/10.1007/978-1-4613-3060-8_19
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