Abstract
This chapter deals with phases, phase diagrams and phase transitions in chemisorption systems. Chemisorbed phases are phases in which the bonding energy Eo of the adsorbate to the substrate is higher than about 1eV per atom or molecule. The lateral adsorbate-adsorbate interaction energy Eaa is usually more than an order of magnitude smaller. Therefore, phase transitions within the layer which are determined to a large extent by Eaa can be studied conveniently over a wide temperature range without loss of material to the environment. A phase transition is defined here as a discontinuous or continuous change of the pair correlation function as evidenced, for example, by changes of the long range order (“structure”) or of quantities which are sensitive to the short range order. Only transitions in the adsorbate alone or in the adsorbate and the topmost layer of the substrate are considered here. Transitions in which an exchange with the bulk of the substrate occurs will be excluded as well as transitions from 2- to 3-dimensional phases.
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References
W.B. Webb and M.G. Lagally, in Solid State Physics 28 (1973) 302
J.B. Pendry, Low Energy Electron Diffraction, Academic Press, London 1974
E. Bauer, in R. Gomer: Interactions on Metal Surfaces, Springer, Berlin 1975, p.227
F. Jona, J. Phys. C: Solid State Phys. 11 (1978) 4271
M.A. van Hove and S.Y. Tong, Surface Crystallography by LEED, Springer, Berlin 1979
M. Henzler, in H. Ibach: Electron Spectroscopy for Surface Analysis, Springer, Berlin 1977, p. 117
T. Engel, H. Niehus and E. Bauer, Surface Sci. 52 (1975) 237
D.V. Morgan, edit., Channeling, John Wiley, London 1973
I. Stensgaard, L.C. Feldman and P.J. Silverman, Phys. Rev. Letters 42 (1979) 247
W. Heiland and E. Taglauer, Surface Sci. 68 (1977) 96
S. Prigge, H. Niehus and E. Bauer, Surface Sci. 65 (1977) 141
A. Benninghoven , CRC Critical Reviews in Solid State Physics 6 (1976) 291
S. Prigge, M.S. Thesis, Clausthal 1975
E. Bauer, J. Electron Spectrosc. Related Phenom. 15 (1979) 1 19
S. Prigge, H. Niehus and E. Bauer, Surface Sci. 75 (1978) 635
E. Bauer and H. Poppa, Surface Sci., in print
J. Hölzl and F.K. Schulte, in Springer Tracts in Modern Physics, Vol.85, p.1 Springer, Berlin, 1979
D.A. Gorodetsky and Yu.P. Melnik, Sov. Phys.- Solid State 16 (1975) 1805
M. Kramer, unpublished
E.A. Bas and U. Bänninger, Surface Sci. 41 (1974) 1
G.-C. Wang, T.-M. Lu and M.G. Lagally, J. Chem. Phys. 69 (1978) 479
K. Christmann, O. Schober, G. Ertl and M. Neumann, J. Chem. Phys. 60 (1974) 4528
T. Engel, private communication
D.A. King, CRC Critical Reviews in Solid State Mater. Sci. 7 (1978)
A.K. Green, S. Prigge and E. Bauer, Thin Solid Films 52 (1978) - 163
E. Bauer, H. Poppa and Y. Viswanath, Surface Sci. 58 (1976) 517
E. Bauer, F. Bonczek, H. Poppa and G. Todd, Surface Sci. 53 (1975) 87
H. Ibach , W. Erley and H. Wagner, preprint
E. Bauer, H. Poppa, G. Todd, F. Bonczek, J. Appl. Phys. 45 (1974) 5164
D.A. King, Surface Sci. 47 (1975) 384
J.L. Taylor and W.H. Weinberg, Surface Sci. 78(1978) 259
W. Schlenk and E. Bauer, in preparation
H. Froitzheim, in Ibach: Electron Spectroscopy for Surface Analysis, Springer, Berlin 1977, p.205
E. Erley, H. Wagner and H. Ibach, Surface Sci. 80 (1979) 612
J. Pritchard, in H. Ibach and S. Lehwald, edit. , Vibrations in adsorbed layers, KFA Jülien 1978, p. 114
A.M. Bradshaw and F.M. Hoffmann, Surface Sci. 72 (1978) 513
J.-R. Chen and R. Gomer , Surface Sci. 79 (1979) 413
R. Butz and H. Wagner, Surface Sci. 63 (1977) 448
M. Bowker and D.A. King, Surface Sci. 72 (1978) 208
P.P. Auer and W. Mönch, Surface Sci. 80 (1979) 45
M, Henzler, J. Appl. Phys. 40 (1969) 3758
J.V. Florio and W.D. Robertson, Surface Sci. 24 (1971) 173
P.W. Palmberg, Surface Sci. 11 (1968) 153
D.G. Fedak and N.A. Gjostein, Phys. Rev. Letters 16 (1966) 171
E. Bauer, in Structure et Propiétés des Surfaces des Solides, CNRS Colloqu. No. 187, Paris 1970, p. 11 1
H.P. Bonzel, C.R. Helms and S. Kelemen, Phys. Rev. Letters 35 (1975) 1237
T.N. Rhodin and G. Broden, Surface Sci. 60 (1976) 466
J. Küppers and H. Michel, Appl. Surface Sci, in press
T.E. Felter, R.A. Barker and P.J. Estrup, Phys. Rev. Letters 38 (1977) 1138
M.K. Debe and D.A.King, J. Phys. C: Solid State Phys. 10(1977), L303; Phys. Rev. Letters 39 (1977) 708
M.K. Debe and D.A. King, Surface Sci. 81 (1979)193
K. Yonehara and L.F. Schmidt, Surface Sci. 25 (1971) 238
E. Bauer, H. Poppa and G. Todd, Thin Solid Films 28 (1975) 19
S. Nishigaki and S. Nakamura, Jap. J. Appl. Phys. 15 (1976) 19
T. Adachi and S. Nakamura, Surface Sci. 59 (1976) 61
E. Tosatti, Solid State Commun. 25 (1978) 637
J.E. Inglesfield, J. Phys. C11 (1978) L69
L.C. Feldman, P.J. Silverman and I. Stensgaard, preprint
J. Behm, K. Christmann and G. Ertl, Solid State Commun. 25 (1978) 763
K. Christmann, R.J. Behm, G. Ertl, M.A. van Hove and W.H. Weinberg, J. Chem. Phys., in print
M. Schick, private communication
L.H. Germer and J.M. May, Surface Sci. 4 (1966) 452
E. Bauer and T. Engel, Surface Sci. 71 (1978) 695
J.C. Buchholz and M.G. Lagally, Phys. Rev. Letters 35 (1975) 442
G. Ertl and D. Schillinger, J. Chem. Phys. 66 (1977) 2569
T.-M. Lu, G.-C. Wang and M.G. Lagally, Phys. Rev. Letters 39 (1977) 411
E.D. Williams, S.L. Cunningham and W.H. Weinberg, J. Vac. Sci. Technol. 15 (1978) 417; J. Chem. Phys. 68 (1978) 4688
W. Y. Ching, D.L. Huber, M. Fishkis and M.G. Lagally J. Vac. Sci. Technol. 15 (1978) 653
G.-C. Wang, T.-M. Lu and M.G. Lagally, J. Chem. Phys. 69 (1978) 479
W.Y. Ching, D.L. Huber, M.G. Lagally and G.-C.Wang, Surface Sci. 77 (1978) 550
T.L. Einstein, CRC Critical Reviews in Solid State Materials Sci. 7 (1978) 260
T.L. Einstein, preprint
T. Engel, T.v.d. Hagen and E.Bauer, Surface Sci. 62 (1977) 361
G.-C. Wang and M.G. Lagally, Surface Sci. 81 (1979) 69
M.G. Lagally, G.-C. Wang and T.-M. Lu, CRC Critical Reviews in Solid State Materials Sci. 7 (1978) 233
T.L. Einstein, Surface Sci. 83 (1979) 141
V.K. Medvedev, A.G. Naumovets and A.G. Fedorus, Sov. Phys. Solid State 12 (1970 301
M. Kaburagi and J. Kanamori, J. Phys. Soc. Japan 43 (1977) 1686
V.K. Medvedev and I.N. Yakovkin, Sov. Phys. Solid State 19 (1977) 1515
E. Bauer, J. de physique 38 (1977) C4-146
L.A. Bol’shov, A.P. Napartovich, A.G. Naumovets and A.G. Fedorus, Sov. Phys. Usp. 20 (1977) 432
A.G. Naumovets and A.G. Fedorus, Sov. Phys. JETP 46 (1977) 575
O.V. Kanash, A.G. Naumovets and A.G. Fedorus, Sov. Phys. JETP 40 (1975) 903
D.A. Gorodetsky and Yu. P. Melnik, Surface Sci. 62 (1977) 647
L.A. Bol’shov, Sov. Phys. Solid State 13 (1971)1404
L.A. Bol’shov and A.P.Napartovich, Sov. Phys. JETP 37 (1973) 713
G. Ertl and J. Küppers, Surface Sci. 21 (1970) 61
P.H. Kleban, Surface Sci. 83 (1979) L 335
P. Ducros, Surface Sci. 10 (1968) 118
G. Theodorou, Surface Sci. 81 (1979) 379
J.C. Buchholz, G.C. Wang and M.G. Lagally, Surface Sci. 49 (1975) 508
M.A. Van Hove and S.Y. Tong, Phys. Rev. Letters 35 (1975) 1092
M.R. Barnes and R.F. Willis, Phys. Rev. Letters 41(1978) 1729
P.J. Estrup, J. Vac. Sci. Technol. 16 (1979) 635
G. Doyen, G. Ertl and M. Plancher, J. Chem. Phys. 62 (1975) 2957
R.A. Barker and P.J. Estrup, Phys. Rev. Letters 41 (1978) 1307
M. Kramer and E. Bauer, submitted the Surface Sci.
E. Bauer, J. Japan. Assoc. Crystal Growth 5 (1978) 49
G. LeLay, M. Manneville and R. Kern, Surface Sci. 72 (1978) 405
R. Kern and G.LeLay, J. de Physique 38 (1977) C4-155 and private communication
E. Bauer, H. Poppa, G. Todd and P.R. Davis, J. Appl. Phys. 48 (1977) 3773
F.C. Frank and J.H. van der Merwe, Proc. Roy. Soc. (London)A 198 (1949) 205, 216; A 200 (1950) 125; Disc. Faraday Soc. 5 (1949) 201
M. Schick, this conference
K.H. Lau and W. Kohn, Surface Sci. 65 (1977) 607
W. Kappus, Z. Physik B 29 (1978) 239
D.W. Bassett, Surface Sci. 53 (1975) 74
D.L. Kellogg and T.T. Tsong, Surface Sci. 62 (1977) 343
T.L. Einstein, Surface Sci. 75 (1978) L161
A.M. Gabovich and E.A. Pashitskii, Sov. Phys. Solid State 18 (1976) 220
P. Johansson and H. Hjelmberg, Surface Sci. 80 (1979) 171
N.R. Burke, Surface Sci. 58 (1976) 349
H. Gollisch and L. Fritsche, Z. Physik B 33 (1979) 13
L.C.A. Stoop, Thin Solid Films 42 (1977) 33 and references therein; preprint
T.T. Tsong, Phys. Rev. Letters 31 (1973) 1207
D.W. Bassett and D.R. Tice, in E. Drauglis and R.I. Jaffee, edit., The physical basis of heterogeneous catalysis, Plenum press, New York, 1975, p. 231
H.-W. Fink, M.S. thesis, Clausthal 1979
G.L. Kellogg, T.T. Tsong and P. Cowan, Surface Sci. 70 (1978) 485
D.W. Bassett, Thin Solid Films 48 (1978) 237 and references therein
R. Butz and H. Wagner, Proc. 7th Intern. Vac. Congr. & 3rd Internat. Conf. on Solid Surfaces, Vienna 1977 , p. 1289
J.G. Dash, Films on Solid Surfaces, Academic Press, New York 1975
G. Ertl, J. Vac. Sci. Technol. 14 (1977) 435; in L. Fiermans, J. Vennik and W. Dekeyser, edit. Electron and Ion Spectroscopy of Solids, Plenum Press, New York 1978, p. 144
D.P. Landau, in K. Binder, edit. Monte Carlo Methods in Statistical Physics, Springer, Berlin 1979, p. 337
H. Wagner, in Springer Tracts in Modern Physics, Springer, Berlin 1979, Vol. 85, p. 151
A.M. Bradshaw and M. Scheffler, J. Vac. Sci. Technol. 16 (1979) 447
L.D. Roelofs, R.L. Park and T.L. Einstein, J.Vac. Sci. Technol. 16 (1979) 478
A.R. Kortan, P.I. Cohen and R.L. Park, J. Vac. Sci. Technol. 16 (1979) 541
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Bauer, E. (1980). Chemisorbed Phases. In: Dash, J.G., Ruvalds, J. (eds) Phase Transitions in Surface Films. NATO Advanced Study Institutes Series, vol 51. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3057-8_9
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DOI: https://doi.org/10.1007/978-1-4613-3057-8_9
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