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New Approaches to the Study of Lanthanide/Actinide Chloride - Aluminum Chloride Vapor Phase Complexes

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The Rare Earths in Modern Science and Technology

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Abstract

Recent interest in vapor phase complexes of lanthanide and actinide halides with aluminum halides has been focused on their dynamic optical properties, since these systems have potential as optical gain media. In addition, their thermodynamic properties indicate that elemental separation by chemical transport is potentially viable. The reaction for gas complexation is generally written as follows for lanthanide chlorides and aluminum chloride

$$ mLnCly\left( c \right) + nA{l_2}C{l_6}\left( g \right) \rightleftarrows L{n_m}A{l_2}_nC{l_{6n + my}}\left( g \right) $$
((1))

.

Work performed under the auspices of the Office of Basic Energy Sciences of the Department of Energy.

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Authors and Affiliations

  1. Chemistry Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois, 60439, USA

    E. J. Peterson, J. A. Caird, W. T. Carnall, Jan P. Hessler, H. R. Hoekstra & C. W. Williams

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  1. E. J. Peterson
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  2. J. A. Caird
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  3. W. T. Carnall
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  4. Jan P. Hessler
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  5. H. R. Hoekstra
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  6. C. W. Williams
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Editor information

Editors and Affiliations

  1. North Dakota State University, Fargo, North Dakota, USA

    Gregory J. McCarthy

  2. Pennsylvania State University, University Park, Pennsylvania, USA

    Gregory J. McCarthy

  3. National Bureau of Standards, Washington, D.C., USA

    James J. Rhyne

  4. University of Texas at San Antonio, San Antonio, Texas, USA

    Herbert B. Silber

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© 1980 Plenum Press, New York

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Peterson, E.J., Caird, J.A., Carnall, W.T., Hessler, J.P., Hoekstra, H.R., Williams, C.W. (1980). New Approaches to the Study of Lanthanide/Actinide Chloride - Aluminum Chloride Vapor Phase Complexes. In: McCarthy, G.J., Rhyne, J.J., Silber, H.B. (eds) The Rare Earths in Modern Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3054-7_20

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  • DOI: https://doi.org/10.1007/978-1-4613-3054-7_20

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3056-1

  • Online ISBN: 978-1-4613-3054-7

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