Abstract
It is probably in this field of unsaturated hydrocarbons polymerization by transition metal complexes, that coordination catalysis has most convincingly demonstrated its amazing ability to govern the rates and particularly the selectivities of complicated organic reactions. This is true at four different levels
-
in terms of selectivity towards different substrates;
-
in terms of regioselectivity in a given molecule;
-
in terms of stereoselectivity and enantioselectivity;
-
and finally in terms of a very recent developement for which we have coined the name “chronoselectivity” or, as suggested by Professor T.H. Esch, “troposteric control”: in other words, the “coding” ability of a catalyst controlling the statistics of placement of two different units in the same polymer chain. This might be the most refined type of control to data, since it includes at the same time both a structural and a kinetic programming.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
For a review, see Ph. Teyssié and F. Dawans, in “Stereo Rubbers”; p.79 sq., W.M. Saltman Editor, J. Wiley and Sons, New York (1977).
A. Yamamoto, Bull. Chem. Soc. Jap., 45, 1 1 1 1 (1972).
a. Ph. Teyssié, T. Ouhadi, and J.P. Bioul, Intern. Review of Science, Phys. Chem. Ser. 2, Vol.8, p. 212, Butterworths, London 1975.
P. Pino et al. and F. Ciardelli et al., in “Coordination Polymerization”, J.C.W. Chien Editor, p.25, Academic Press, 1975.
N. Spassky, ACS Symposium Series, n°59, Ring-Opening Polymerisation, T. Saegusa and E. Goethals Editors, p. 191 (1977).
D.G.H. Ballard, in “Coordination Polymerization”, J.C.W. Chien Editor, p.223, Academic Press, 1975.
P. Cossee, in “Stereochemistry of Macromolecules”, Vol.1, p. 145 sq., A.D. Ketley Editor, M. Dekker, New York (1967).
L. Rodriguez and H. Van Looy, J. Polymer Sci., Al, 4, 1971.
P. Pino, private communication.
Yu. Yermakov and V.A. Zakharov, in “Coordination Polymerization”, J.C.W, Chien Editor, p.91, Academic Press 1975.
G. Henrici Olivé and S. Olivé, Adv. Polym. Sci., 6, 421 (1969).
A. Zambelli et al., Makromol. Chem., 112, 160 (1968).
D.R. Armstrong, P.G. Perkins and J.J.P. Stewart, J.C.S. Dalton, 1972 (1972).
K.J. Ivin et al., and M.L.H. Green et al., J.C.S., Chem. Com., 604 (1978).
For a review, see “The control of diolefins selective polymerization”, Ph. Teyssie, A. Devaux, P. Hadjiandreou, M. Julemont, J.M. Thomassin, E. Walckiers and R. Warin, in Nato Advanced Study Institute on Stereoregular Polymers, F. Ciardelli and R.W. Lenz Editors, in press, Plenum, 1979.
R. Warin et al., J. Polymer Sci., B11, 177 (1973);
R. Warin, M. Julemont and Ph. Teyssié, unpublished results.
R.P. Hughes and J. Powell, J. Am. Chem. Soc., 94, 7723 (1972).
E.J. Arlman, J. Catalysis, 5, 178 (1966).
L. Porri and M. Aglietto, Makromol. Chem., 177, 1465 (1976).
L. Porri, Colloque Section Sud G.F.P., La Grande Motte, Editor F. Schué, Octobre 1978.
M. Julémont et al., Makromol. Chem., 175, 1673 (1974).
M. Julémont, Ph. D. Thesis, University of Liège, 1976.
Ph. Teyssié, F. Dawans and J.P. Durand, J. Polymer Sci., C22, 221 (1968).
J.P. Durand and Ph. Teyssié, J. Polymer Sci., B6, 299 (1968).
b. J.P. Durand, F. Dawans and Ph. Teyssié, J. Polymer Sci., A1, 987, (1970).
c. J. Furukawa, K. Haga, E. Kobayashi, Y. Iseda, T. Youshimoto, and K. Sakamoto, Polymer J., 2, 371 (1971).
d. J. Furukawa, E. Kobayashi and T. Kawagoe, Polymer J., 5, 231 (1973).
F. Dawans and Ph. Teyssié, Makromol. Chem., 109, 68 (1967).
F. Dawans and Ph. Teyssié, Europ. Polym. J., 5, 541 (1969).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1979 Plenum Press, New York
About this chapter
Cite this chapter
Teyssié, P. (1979). Coordination Polymerization of Olefins and Diolefins. In: Tsutsui, M. (eds) Fundamental Research in Homogeneous Catalysis. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2958-9_8
Download citation
DOI: https://doi.org/10.1007/978-1-4613-2958-9_8
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-2960-2
Online ISBN: 978-1-4613-2958-9
eBook Packages: Springer Book Archive