Abstract
Recently a number of studies have shown that coordinatively unsaturated transition metal complexes, which are capable of serving as catalysts for a variety of reactions involving olefins, may be generated by photolysis.1–6 Coordinative unsaturation can be obtained by light-induced ligand dissociation or metal-metal bond dissociation. Light-generated catalysts may be genuinely unique since the catalyst is the result of an excited state decay process.
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Pittman, C.U., Honnick, W.D., Wrighton, M.S., Sanner, R.D., Austin, R.G. (1979). Photogeneration of Polymer-Anchored Catalytic Species from Iron Carbonyls. In: Tsutsui, M. (eds) Fundamental Research in Homogeneous Catalysis. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2958-9_40
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DOI: https://doi.org/10.1007/978-1-4613-2958-9_40
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