Skip to main content

Mechanism of Poly(Vinyl Chloride) Fire Retardance by Molybdenum(VI) Oxide. Further Evidence in Favor of the Lewis Acid Theory

  • Chapter
Polymer Additives

Abstract

Many recent investigations have been concerned with the mechanism of action of MoO3 as a smoke-suppressant and fire-retardant additive for poly(vinyl chloride) (PVC).1–14 These studies have shown that Mo03 functions within the polymer matrix1–14 and retards the production of the volatile aromatics (especially benzene) that are the principal fuel and source of smoke under low-enthalpy-input conditions.1–4,6–8,13,14 However, no consensus of opinion has been reached with regard to the nature of the chemical reactions that cause the aromatics suppression.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. W. H. Starnes, Jr., and D. Edelson, Macromolecules,12, 797 (1979).

    Article  ADS  Google Scholar 

  2. D. Edelson, V. J. Kuck, R. M. Lum, E. Scalco, W. H. Starnes, Jr., and S. Kaufman, Combust. Flame,38, 271 (1980).

    Article  Google Scholar 

  3. R. M. Lum, L. Seibles, D. Edelson and W. H. Starnes, Jr., Org. Coat. Plast. Chem.,43, 176 (1980).

    Google Scholar 

  4. R. P. Lattimer and W. J. Kroenke, J. Appl. Polym. Sci.,26, 1191 (1981).

    Article  Google Scholar 

  5. W. J. Kroenke, J. Appl. Polym. Sci.,26, 1167 (1981).

    Article  Google Scholar 

  6. A. Ballistreri, G. Montaudo, C. Puglisi, E. Scamporrino and D. Vitalini, J. Polym. Sci., Polym. Chem. Ed.,19, 1397 (1981).

    Article  ADS  Google Scholar 

  7. A. Ballistreri, S. Foti, P. Marav igna, G. Montaudo, and E. Scamp¬orrino, J. Polym. Sci., Polym. Chem. Ed.,18, 3101 (1980).

    Google Scholar 

  8. S. K. Brauman, J. Appl. Polym. Sci.,26, 353 (1981).

    Article  Google Scholar 

  9. S. K. Brauman, J. Fire Retard. Chem.,7, 119 (1980).

    Google Scholar 

  10. F. W. Moore, T. R. Weber and G. A. Tsigdinos, J. Vinyl Technol.,3, 139 (1981).

    Article  Google Scholar 

  11. F. W. Moore and G. A. Tsigdinos, Fire Retard., Proc. Int. Symp. Flammability Fire Retard. 1978, 160 (1978).

    Google Scholar 

  12. F. W. Moore and G. A. Tsigdinos, J. Less-Common Met.,54, 297 (1977).

    Article  Google Scholar 

  13. T. C. Rees, presented at the 7th International Symposium on Flammability and Fire Retardants, New Orleans, LA, May, 1980.

    Google Scholar 

  14. R. M. Lum, J. Appl. Polym. Sci.,23, 1247 (1979).

    Google Scholar 

  15. R. M. Lum, private communication, 1981.

    Google Scholar 

  16. S. Tsuge, T. Okumoto and T. Takeuchi, Macromolecules,2, 277 (1969).

    Article  ADS  Google Scholar 

  17. S. A. Liebman, D. H. Ahlstrom, E. J. Quinn, A. G. Geigley and J. T. Meluskey, J. Polym. Sci., Part A-1,9, 1921 (1971).

    Article  Google Scholar 

  18. N. Hultgren and L. Brewer, J. Phys. Chem.,60, 947 (1956).

    Article  Google Scholar 

  19. B. C. Gates, J. R. Katzer and G. C. A. Schu it, Chemistry of Catalytic Processes, McGraw-Hill, New York, 1979, Chapters 1 and 3.

    Google Scholar 

  20. C. D. Nenitzescu, Carbonium Ions,2, 463 (1970).

    Google Scholar 

  21. T. Iida and K. Goto, J. Polym. Sci., Polym. Chem. Ed.,15, 2427 (1977).

    Article  ADS  Google Scholar 

  22. R. P. Lattimer and W. J. Kroenke, J. Appl. Polym. Sci.,25, 101 (1980).

    Article  Google Scholar 

  23. R. P. Lattimer and W. J. Kroenke, J. Appl. Polym. Sci.,27, 1355 (1982).

    Article  Google Scholar 

  24. W. H. Starnes, Jr., L. D. Wescott, Jr., W. D. Reents, Jr., R. E. Cais, G. M. Villacorta, I. M. Plitz and L. J. Anthony, Org. Coat. Plast. Chem.,46, 556 (1982).

    Google Scholar 

  25. W. H. Starnes, Jr., L. D. Wescott, Jr., W. D. Reents, Jr., R. E. Cais, G. M. Villacorta, I. M. Plitz and L. J. Anthony, Org. Coat. Plast. Chem.,46, 556 (1982).

    Google Scholar 

  26. W. H. Starnes, Jr., Dev. Polym. Degradation,3, 135 (1981).

    Google Scholar 

  27. S. K. Brauman and I. J. Chen, J. Polym. Sci., Polym. Chem. Ed.,19, 495 (1981).

    Article  ADS  Google Scholar 

  28. P. Burille, M. Bert, A. Michel and A. Guyot, J. Polym. Sci., Polym. Lett. Ed.,16, 181 (1978).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1984 Plenum Press, New York

About this chapter

Cite this chapter

Starnes, W.H. et al. (1984). Mechanism of Poly(Vinyl Chloride) Fire Retardance by Molybdenum(VI) Oxide. Further Evidence in Favor of the Lewis Acid Theory. In: Kresta, J.E. (eds) Polymer Additives. Polymer Science and Technology, vol 26. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2797-4_18

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-2797-4_18

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9724-6

  • Online ISBN: 978-1-4613-2797-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics