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Reactions of PVC with Organotin Stabilizers Under Controlled Conditions

  • G. Ayrey
  • S. Y. Hsu
  • R. C. Poller
Part of the Polymer Science and Technology book series (POLS, volume 26)

Abstract

Research and development work in this area often concentrates on attempts to reproduce in the laboratory conditions which approximate to those in the actual processing equipment where degradation and stabilization occur. Such experiments are successful in evaluating and development stabilizers but are less effective in clarifying the chemistry involved. Our own work, at first with model compounds1,2 and then with PVC itself,3–5 has been designed to show how the polymer reacts under carefully controlled conditions so that the various reaction parameters can be isolated.

Keywords

Maleic Anhydride Hydrogen Chloride Volatile Acid Degraded Polymer Dibutyltin Dilaurate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. G. Ayrey, R. C. Poller and I. H. Siddiqui, J. Polymer Sci. A-1 (1972) 10, 725CrossRefGoogle Scholar
  2. G. Ayrey, F. P. Man and and R. C. Poller, J. Organomet. Chem?., (1979), 173, 171CrossRefGoogle Scholar
  3. F. Alavi-Moghamdam, G. Ayrey and R. C. Poller, Europ. Polymer J., (1975), 11. 649.CrossRefGoogle Scholar
  4. F. Alavi-Moghamdam, G. Ayrey and R. C. Poller, Polymer (1975).CrossRefGoogle Scholar
  5. R. C. Poller, J. Macromol. Sci-Chem. (1978) A12, 373.Google Scholar

Copyright information

© Plenum Press, New York 1984

Authors and Affiliations

  • G. Ayrey
  • S. Y. Hsu
    • 1
  • R. C. Poller
    • 1
  1. 1.Queen Elizabeth CollegeLondonEngland

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