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Conversion of Synthesis Gas to Olefins over Physical Mixtures of High SiO2/Al2O3 ZSM-5 And Fe(K)

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Catalytic Conversions of Synthesis Gas and Alcohols to Chemicals

Abstract

The intimate combination of zeolite ZSM-5 with CO reducing metals for conversion of synthesis gas to gasoline boiling range hydrocarbons has been previously reported. Chang et al [1] combined the metal function with the zeolite in the same particle by impregnation with metal nitrate solutions or mixing with hydroxide gel, while Caesar et al [2] used a composite catalyst of separate 700 to 1500µm diameter particles of ZSM-5 and the Fischer-Tropsch component. The latter paper showed that a mixture of potassium-promoted fused iron catalyst with a volume excess of ZSM-5 generated a C5-200°C aromatic gasoline with a research octane number of 92.

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© 1984 Plenum Press, New York

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Dwyer, F.G., Garwood, W.E. (1984). Conversion of Synthesis Gas to Olefins over Physical Mixtures of High SiO2/Al2O3 ZSM-5 And Fe(K). In: Herman, R.G. (eds) Catalytic Conversions of Synthesis Gas and Alcohols to Chemicals. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2737-0_9

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  • DOI: https://doi.org/10.1007/978-1-4613-2737-0_9

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9696-6

  • Online ISBN: 978-1-4613-2737-0

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