Skip to main content

Recent Advances in Alcohol Homologation: The Effect of Promoters

  • Chapter

Abstract

Alcohol homologation is a general term describing a process in which an alcohol with n carbon atoms is converted into an n+1 carbon alcohol, i.e. an additional methylene unit has been added to the starting alcohol. As commonly used, alcohol homologation refers to the reaction of an alcohol with carbon monoxide and hydrogen to give higher carbon number oxygenates:

$${\text{ROH}} + {\text{CO}} + 2{{\text{H}}_2} \to {\text{RC}}{{\text{H}}_2}{\text{OH}} + {{\text{H}}_2}{\text{O}}$$

.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. G. Wietzel, et al., German Patent 867, 849 (1941).

    Google Scholar 

  2. G. Wietzel, O. Vorbach, and A. Scheuermann, German Patent 875,346 (1953).

    Google Scholar 

  3. I. Wender, R. Levine, and M. Orchin, J. Am. Chem. Soc., 71:4160 (1949).

    Article  CAS  Google Scholar 

  4. D. W. Slocum, in “Catalysis in Organic Chemistry,” W. H. Jones, ed., Academic Press, Inc., New York, pp 245–276 (1980).

    Google Scholar 

  5. F. Piacenti and M. Bianchi, in “Organic Synthesis via Metal Carbonyls,” I. Wender and P. Pino, eds., Vol. 2, John Wiley & Sons, New York, pp 13–18 (1977).

    Google Scholar 

  6. H. Bahrmann and B. Cornils, in “New Syntheses with Carbon Monoxide,” J. Falbe, ed., Springer-Verlag, New York, pp 226–242 (1980).

    Google Scholar 

  7. I. Wender, R. A. Friedel, and M. Orchin, Science, 113:206 (1951).

    Article  CAS  Google Scholar 

  8. K. H. Ziesecke, Brennstoff-Chem., 33:385 (1952).

    CAS  Google Scholar 

  9. W. F. Gresham, U.S. Patent 2,623,906 (1952); assigned to E. I. du Pont de Nemours & Co.

    Google Scholar 

  10. J. Berty, L. Marko, and D. Kallo, Chem. Techn., 8:260 (1956).

    CAS  Google Scholar 

  11. A. D. Riley and W. O. Bell, U.S. Patent 3,248,432 (1966); assigned to Commercial Solvents Corp.

    Google Scholar 

  12. G. N. Butter, U.S. Patent 3,285,948 (1966); assigned to Commercial Solvents Corp.

    Google Scholar 

  13. M. Kuraishi, S. Asano, and A. Takahashi, U.S. Patent 3,356,734 (1967); assigned to Commercial Solvents Corp.

    Google Scholar 

  14. M. Kuraishi, S. Asano, and Y. Shinozaki, U.S. Patent 3,387,043 (1968); assigned to Commercial Solvents Corp.

    Google Scholar 

  15. K. H. Keim, J. Korff, W. Keim, and M. Roper, Erdoel Kohle, Erdgas, Petrochem. Brennst-Chem., 35:297 (1982).

    CAS  Google Scholar 

  16. W. W. Paudler and T. E. Walton, J. Org. Chem., 46:4306 (1981).

    Article  CAS  Google Scholar 

  17. I. Abis, A. Sen, and J. Halpern, J. Am. Chem. Soc., 100:2915 (1978).

    Article  CAS  Google Scholar 

  18. D. J. Drury, M. J. Green, D. J. M. Ray, and A. J. Stevenson, J. Organometal. Chem., 236:C23 (1982).

    Article  CAS  Google Scholar 

  19. W. R. Pretzer and T. P. Kobylinski, Ann. NY Acad. Sci., 333:58 (1980).

    Article  CAS  Google Scholar 

  20. a. W. R. Pretzer, T. P. Kobylinski, and J. E. Bozik, U.S. Patent 4,133,966 (1979); assigned to Gulf Research & Development Co.

    Google Scholar 

  21. b. W. R. Pretzer, T. P. Kobylinski, and J. E. Bozik, U.S. Patent 4,239.924 (1980); assigned to Gulf Research & Development Co.

    Google Scholar 

  22. c. R. A. Fiato, U.S. Patent 4,233,466 (1980); assigned to Union Carbide Corp.

    Google Scholar 

  23. d. B. R. Gane and D. G. Stewart, U.S. Patent 4,262,154 (1981); assigned to The British Petroleum Co.

    Google Scholar 

  24. e. W. R. Pretzer, T. P. Kobylinski, and J. E. Bozik, U.S. Patent 4,346,020 (1982); assigned to Gulf Research & Development Co.

    Google Scholar 

  25. f. M. M. Habib and W. R. Pretzer, U.S. Patent 4,352,947 (1982) assigned to Gulf Research & Development Co.

    Google Scholar 

  26. G. R. Burns, J. Am. Chem. Soc., 77:6615 (1955).

    Article  CAS  Google Scholar 

  27. W. Cornely and B. Fell, J. Mol. Catal., 16:89 (1982).

    Article  CAS  Google Scholar 

  28. W. Hieber and H. Schulten, Z. anorg. u. allgem. Chem., 243:145 (1939).

    Article  CAS  Google Scholar 

  29. M. Basato, M. Bressan, and P. Rigo, J. Organometal. Chem., 232:81 (1982).

    Article  CAS  Google Scholar 

  30. J. Gauthier-Lafaye and R. Perron, U.S. Patent 4,306,091 (1981) assigned to Rhone-Poulenc Industries.

    Google Scholar 

  31. J. Gauthier-Lafaye and R. Perron, U.S. Patent 4,324,927 (1982) assigned to Rhone-Poulenc Industries.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1984 Plenum Press, New York

About this chapter

Cite this chapter

Pretzer, W.R., Habib, M.M. (1984). Recent Advances in Alcohol Homologation: The Effect of Promoters. In: Herman, R.G. (eds) Catalytic Conversions of Synthesis Gas and Alcohols to Chemicals. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2737-0_15

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-2737-0_15

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9696-6

  • Online ISBN: 978-1-4613-2737-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics