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Comprehensive Treatise of Electrochemistry pp 445–456Cite as

Electron Spectroscopy for Chemical Analysis (ESCA) and Electrode Surface Chemistry

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Abstract

The experimental objective of electrodic studies is to define electrode surface reactions through the measurable parameters of current, electrode potential, and reactant concentration at the electrode-electrolyte interface. However, the chemical characterization of electrosorbed and electrodeposited products on the electrode surface has been hampered by the lack of molecular specificity in the electrochemical measurements. In addition, the electro-catalytic behavior of electrode surfaces has remained a difficult parameter to quantify with conventional electrochemical measurements. The application of spectroscopic techniques such as ESCA, which can yield molecular information relevant to the electrode surface chemistry, is providing new insight into these problems.

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References

  1. K. Siegbahn, C. Nordling, A. Falham, R. Nordberg, K. Hamrin, J. Hedman, G. Johansson, T. Bergmark, S. Karlsson, I. Lindgreen, and B. Lindberg, ESCA-Atomic, Molecular and Solid State Structure Studied by Means of Electron Spectroscopy, Almqvist and Wiksell, Uppsala, Sweden (1967).

    Google Scholar 

  2. K. Siegbahn, C. Nordling, G. Johansson, J. Hedman, P. F. Heden, K. Hamrin, U. Gelius, T. Bergmark, L. O. Wermer, R. Manne, and Y. Baer, Esca Applied to Free Molecules, American Elsevier, New York (1969).

    Google Scholar 

  3. D. A. Shirley, Ed., Electron Spectroscopy, p. 47, North Holland Publishing, Amsterdam (1972).

    Google Scholar 

  4. a) D. W. Davis, M. S. Banna, and D. A. Shirley, J. Chem. Phys. 60, 237 (1974). (b) P. H. Citrin and D. R. Hamann, Phys. Rev. B 10, 4948 (1974). (c) F. O. Ellison and M. G. White, J. Chem. Educ. 53, 430 (1976).

    Google Scholar 

  5. a) D. W. Davis, M. S. Banna, and D. A. Shirley, J. Chem. Phys. 60, 237 (1974). (b) P. H. Citrin and D. R. Hamann, Phys. Rev. B 10, 4948 (1974). (c) F. O. Ellison and M. G. White, J. Chem. Educ. 53, 430 (1976).

    Article  CAS  Google Scholar 

  6. a) D. W. Davis, M. S. Banna, and D. A. Shirley, J. Chem. Phys. 60, 237 (1974). (b) P. H. Citrin and D. R. Hamann, Phys. Rev. B 10, 4948 (1974). (c) F. O. Ellison and M. G. White, J. Chem. Educ. 53, 430 (1976).

    Article  CAS  Google Scholar 

  7. J. H. Scofield, J. Electron Spectrosc. 8, 129 (1976).

    Article  CAS  Google Scholar 

  8. R. C. G. Lecky, Phys. Rev. A 13, 1043 (1976).

    Article  Google Scholar 

  9. C. J. Powell, Surf. Sci. 44, 29 (1974).

    Article  CAS  Google Scholar 

  10. R. S. Swingle II, Anal. Chem. 47, 21 (1975).

    Article  CAS  Google Scholar 

  11. . (a) D. M. Hercules, Anal. Chem. 42, 20A (1970). (b) C. A. Luchesi and J. E. Lester, J. Chem. Educ. A205, A269 (1973). (c) R. S. Swingle II and W. M. Riggs, CRC Crit. Rev. Anal. Chem. 267 (1975).

    Article  CAS  Google Scholar 

  12. . (a) D. M. Hercules, Anal. Chem. 42, 20A (1970). (b) C. A. Luchesi and J. E. Lester, J. Chem. Educ. A205, A269 (1973). (c) R. S. Swingle II and W. M. Riggs, CRC Crit. Rev. Anal. Chem. 267 (1975).

    Google Scholar 

  13. . (a) D. M. Hercules, Anal. Chem. 42, 20A (1970). (b) C. A. Luchesi and J. E. Lester, J. Chem. Educ. A205, A269 (1973). (c) R. S. Swingle II and W. M. Riggs, CRC Crit. Rev. Anal. Chem. 267 (1975).

    Google Scholar 

  14. K. S. Kim, N. Winograd, and R. E. Davis, J. Am. Chem. Soc. 93, 6296 (1971).

    Article  CAS  Google Scholar 

  15. G. C. Allen, P. M. Tucker, A. Capon, and R. Parsons, J. Electroanal. Chem. 50, 335 (1974).

    Article  CAS  Google Scholar 

  16. T. Dickinson, A. F. Povey, and P. M. A. Sherwood, J. Chem. Soc. Faraday I 71, 298 (1975).

    Article  CAS  Google Scholar 

  17. J. S. Hammond and N. Winograd, J. Electroanal. Chem., in press.

    Google Scholar 

  18. . T. A. Carlson and G. E. McGuire, J. Electron Spectrosc. 1, 161 (1972/73).

    Article  CAS  Google Scholar 

  19. K. S. Kim, C. D. Sell, and N. Winograd, Proc. Symp. Electrocatal. 242 (1974).

    Google Scholar 

  20. K. S. Kim, A. F. Gossmann, and N. Winograd, Anal. Chem. 46, 197 (1974).

    Article  CAS  Google Scholar 

  21. . S. Eguchi, T. Hamaguchi, S. Sawada, A. Aoki, and Y. Sato, Kinzoku Hyomen Gijutsu 25, 428 (1974), C. A. 82, 130892 (1975).

    CAS  Google Scholar 

  22. . S. Eguchi, T. Hamaguchi, S. Sawada, T. Minzuno, and Y. Sato, Kinzoku Hyomen Gijutsu 25, 437 (1974), C. A. 82, 130893 (1975).

    CAS  Google Scholar 

  23. H. Imoto, T. Nakajima, and N. Watanabe, Bull. Chem. Soc. Jpn. 48, 1633 (1975).

    Article  CAS  Google Scholar 

  24. . L. D. Hulett, A. L. Bacarella, L. LiDonnici, and J. C. Griess, J. Electron Spectrosc, 1, 169 (1972/73).

    Article  CAS  Google Scholar 

  25. Y. Takasu, S. Maru, Y. Matsuda, and H. Shimizu, Bull. Chem. Soc. Jpn. 48, 219 (1975)

    Article  CAS  Google Scholar 

  26. Y. Takasu, H. Shimizu, S. Maru, M. Tomori, and Y. Matsuda, Corrosion Sci. 16, 159 (1976).

    Article  CAS  Google Scholar 

  27. G. Blondeau, M. Froelicher, M. Froment, A. H. Goff, and C. Vignaud, C. R. Acad. Sci. Ser. C 282, 407 (1976).

    CAS  Google Scholar 

  28. G. Okamoto, Corrosion Sci. 13, 471 (1973).

    Article  CAS  Google Scholar 

  29. . G. Okamoto, K. Tachibana, T. Shibato, and K. Hoshino, Nippon Kinzoku Gakkaishi 38,117 (1974), C.A. 81, 67065 (1974).

    CAS  Google Scholar 

  30. . S. Eguchi, T. Hamaguchi, S. Sawada, T. Mizuno, and Y. Sato, Kinzoku Hyomen Gijutsu 25, 492(1974), C.A. 83, 68716 (1975).

    CAS  Google Scholar 

  31. J. E. Castle and D. C. Epler, Surf. Sci. 53, 286 (1975).

    Article  CAS  Google Scholar 

  32. J. E. Castle, D. C. Epler, and D. B. Peplow, Corrosion Sci. 16, 145 (1976).

    Article  CAS  Google Scholar 

  33. I. Olefjord, J. Appl. Electrochem. 5, 145 (1975).

    Article  CAS  Google Scholar 

  34. K. Asami, K. Hashimoto, and S. Shimodaira, Corrosion Sci. 16, 387 (1976).

    Article  CAS  Google Scholar 

  35. J. S. Brinen and J. E. McClure, Anal. Lett. 5, 737 (1972).

    Article  CAS  Google Scholar 

  36. J. S. Brinen and J. E. McClure, J. Electron Spectrosc. 4, 243 (1974).

    Article  CAS  Google Scholar 

  37. J. S. Brinen, J. Electron Spectrosc. 5, 377 (1974).

    Article  CAS  Google Scholar 

  38. R. Adzic, E. Yeager, and B. D. Cahan, J. Electrochem. Soc. 121, 474 (1974).

    Article  CAS  Google Scholar 

  39. J. S. Hammond and N. Winograd, J. Electroanal. Chem., submitted for publication.

    Google Scholar 

  40. J. S. Hammond and N. Winograd, unpublished results.

    Google Scholar 

  41. K. S. Kim, T. J. O’Leary, and N. Winograd, Anal. Chem. 45, 2214 (1973).

    Article  CAS  Google Scholar 

  42. T. Dickinson, A. F. Povey, and P. M. A. Sherwood, J. Chem. Soc. Faraday Trans. I 72, 686 (1976).

    Article  CAS  Google Scholar 

  43. J. F. Evans, N. N. Blount, and C. R. Ginnard, J. Electroanal. Chem., 59, 169 (1975).

    Article  CAS  Google Scholar 

  44. M. Savy, C. Bernard, and G. Magner, Electrochim. Acta 20, 383 (1975).

    Article  CAS  Google Scholar 

  45. P. R. Moses, L. Wier, and R. W. Murray, Anal. Chem. 47, 1881 (1975).

    Article  Google Scholar 

  46. C. M. Elliot and R. W. Murray, Anal. Chem. 48, 1247 (1975).

    Article  Google Scholar 

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Author information

Authors and Affiliations

  1. Physical Electronic Div., Perkin-Elmer Corp., 6509 Flying Cloud Dr., Eden Prairie, Minn., 55344, USA

    J. S. Hammond

  2. Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania, 16802, USA

    N. Winograd

Authors
  1. J. S. Hammond
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  2. N. Winograd
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Editor information

Editors and Affiliations

  1. Texas A&M University, College Station, Texas, USA

    Ralph E. White  & J. O’M. Bockris  & 

  2. University of Ottawa, Ottawa, Ontario, Canada

    Brian E. Conway

  3. Case Western Reserve University, Cleveland, Ohio, USA

    Ernest Yeager

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© 1984 Plenum Press, New York

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Hammond, J.S., Winograd, N. (1984). Electron Spectroscopy for Chemical Analysis (ESCA) and Electrode Surface Chemistry. In: White, R.E., Bockris, J.O., Conway, B.E., Yeager, E. (eds) Comprehensive Treatise of Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2679-3_8

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  • DOI: https://doi.org/10.1007/978-1-4613-2679-3_8

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9667-6

  • Online ISBN: 978-1-4613-2679-3

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