Abstract
Multicomponent molybdate catalysts are currently used for the industrial oxidation and ammoxidation of propylene1–11. Most of the studies reported in literature concern simple molybdates taken as suitable model catalysts and structural defects have been invoked as responsible for the catalytic activity of such materials. Their nature has been investigated mainly by X-ray diffraction technique5–7. It appears evident that a more detailed study of the structural and related bulk properties as well as systematic measurements of the collective properties of such materials could contribute to the explanation of their catalytic properties. In the frame of this view, the electrical conductivity of a “pure”12 Fe2(MoO4)3 polycrystalline specimen was previously investigated and in the present work, electrical conductivity measurements as a function of temperature and oxygen partial pressure have been carried out on the Fe2 (MoO4)3 catalyst.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
K. Aykan, O. Halvorson, A. W. Sleight, D. B. Rogers,J. Catal. 35:401 (1974).
A. W. Sleight, Crystal Chemistry and Catalytic Properties of Oxides with Scheelite Structure,in: “Advanced Materials in Catalysis,” J. J. Burton, R. L. Garten, Eds., Academic Press, New York (1977).
A. W. Sleight K. Aykan, D. B. Rogers,J. Solid State Chem. 13:231 (1975).
P. L. Villa, A. Szabo, F. Trifiro, M. Carbucicchio,J. Catal. 47:122 (1977)
F. Veath, J. L. Callahan, J. D. Idol, E. D. Milberger,Chem. Engl. Prog. 5b (10): 65 (1960).
J. Y. Robin, Y. Arnaud, J. Guidot, J. E. Germain,R. Acad. Sci. Ser. C 280: 921 (1975).
W. J. Linn, A. W. Sleight,J. Catal. 41:134 (1976).
P. Forzatti, I. Pasquon, P. Trifiro, Tellurium as a Specific Component in New Molybdenum-Based Catalysts for the Selective Oxidation and Ammoxidation of Olefins, in: “Proceeding of the Climax 3rd International Conference on the Chemistry and Uses of Molybdenum,” H. F. Barry, P. C. H. Mitchell, Eds., Ann Arbor, Mich. (1979).
P. Forzatti. P. Tittarelli,J. Solid State Chem. 33:421 (1980).
M. W. J. Wolf, P. A. Batist,J. Catal. 32:25 (1974).
I. Matsuura, M. W. J. Wolf,J. Catal. 37:174 (1975).
P. Forzatti, P. L. Villa, C. M. Mari,Mat. Chem. Phys. 10:385 (1984).
P. Forzatti, P. L. Villa, N. Ferlazzo, D. Jones,J. Catal. 76: 188 (1982).
P. V. Klevtsov, R. F. Klevtsova, L. M. Kefeli, L. M. Plyasova,Inorg. Mater. 1:843 (1965).
L. M. Plyasova, R. F. Klevtsova, S. V. Borisov, L. M. Kefeli,Dokl. Akad. Nauk. 167:84 (1966).
G. Fagherazzi, N. Pernicone,J. Catal. 16: 321 (1970).
H. Chen,Mater. Res. Bull. 14:1583 (1979).
A. V. Gur’ev, G. Fior, A. Marini, V. Massarotti, R. Riccardi,Z. Naturforsch. 36a:280 (1981).
A. W. Sleight, L. H. Brixner,J. Solid State Chem. 7:172 (1973).
V. Massarotti, G.Fior, A. Marini, J. Appl. Crystallogr. 14:64 (1981).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1985 Plenum Press, New York
About this chapter
Cite this chapter
Mari, C.M., Forzatti, P., Villa, P.L. (1985). Electrical Properties of a Fe2(MoO4)3 Catalyst. In: Simkovich, G., Stubican, V.S. (eds) Transport in Nonstoichiometric Compounds. NATO ASI Series, vol 129. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2519-2_4
Download citation
DOI: https://doi.org/10.1007/978-1-4613-2519-2_4
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-9522-8
Online ISBN: 978-1-4613-2519-2
eBook Packages: Springer Book Archive