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Transport in Nonstoichiometric Compounds pp 297–313Cite as

Defect Structure and Transport Properties of the Manganese Oxides Manganosite (Mn1−ΔO) and Hausmannite (Mn3−δO4)

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Part of the book series: NATO ASI Series ((NSSB,volume 129))

Abstract

The effect of temperature and oxygen partial pressure on the nonstoichiometry of two manganese oxides, manganosite (Mn1−ΔO) and hausmannite (Mn3−δO4), has been studied by thermogravimetry between 900 and 1400°C. It is concluded that cation vacancies and holes are the dominant defect species in manganosite over at least most of its stability range at high temperatures. For the low and also for the high temperature phase of hausmannite it was found that cation vacancies predominate at high oxygen activity, while manganese interstitials are the prevailing point defects at low oxygen activity. The relationships between thedefect structure of manganosite and its transport properties are discussed briefly.

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Authors and Affiliations

  1. Institute for Physical Chemistry and Electrochemistry, University of Hannover, Callinstrasse 3-3a, D 3000, Hannover 1, Federal Republic of Germany

    Rüdiger Dieckmann & Michael Keller

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  1. Rüdiger Dieckmann
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  2. Michael Keller
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  1. Pennsylvania State University, University Park, Pennsylvania, USA

    George Simkovich  & Vladimir S. Stubican  & 

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© 1985 Plenum Press, New York

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Dieckmann, R., Keller, M. (1985). Defect Structure and Transport Properties of the Manganese Oxides Manganosite (Mn1−ΔO) and Hausmannite (Mn3−δO4). In: Simkovich, G., Stubican, V.S. (eds) Transport in Nonstoichiometric Compounds. NATO ASI Series, vol 129. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2519-2_23

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  • DOI: https://doi.org/10.1007/978-1-4613-2519-2_23

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9522-8

  • Online ISBN: 978-1-4613-2519-2

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