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Chemistry and Structure in Amorphous Materials: The Shapes of Things to Come

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Physics of Disordered Materials

Part of the book series: Institute for Amorphous Studies Series ((IASS))

Abstract

On Sir Nevill’s 80th birthday, I wish to continue the discussion which I outlined in my contributions to his 65th and 75th birthday festschrifts [1,2], and I look forward to further exploring these concepts in the festschrift for his 85th.

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References

  1. Ovshinsky, S.R. and Ovshinsky, I.M., “Analog Models for Information Storage and Transmission in Physiological Systems,” Mat. Res. Bull. 5, 681–690 (1970). (Mott Festschrift.)

    Article  Google Scholar 

  2. Ovshinsky, S.R., “The Shape of Disorder,” J. Non-Cryst. Solids 32, 17–28 (1979). (Mott Festschrift.)

    Article  ADS  Google Scholar 

  3. Adler, D., ed., Disordered Materials: Science and Technology, Selected Papers by S.R. Ovshinsky, Bloomfield Hills, Michigan, Amorphous Institute Press, (1982) 1–296. (See for more complete references.)

    Google Scholar 

  4. Ovshinsky, S.R., “Fundamentals of Amorphous Materials,” in Physical Properties of Amorphous Materials, Institute for Amorphous Studies Series, vol. 1, D. Adler, B.B. Schwartz, and M.C. Steele, eds., Plenum Press, New York, (1985) 105–155.

    Google Scholar 

  5. Ovshinsky, S.R. and Sapru, K., “Three Dimensional Model of Structure and Electronic Properties of Chalcogenide Glasses,” in Proc. of the Fifth Int. Conf. on Amorphous and Liquid Semiconductors, Garmisch-Partenkirchen, Germany, (1974) 447–452.

    Google Scholar 

  6. Ovshinsky, S.R. and Adler, D., “Local Structure, Bonding, and Electronic Properties of Covalent Amorphous Semiconductors,” Contemp. Phys. 19, 109–126 (1978).

    Article  ADS  Google Scholar 

  7. Ovshinsky, S.R. and Fritzsche, H., “Amorphous Semiconductors for Switching, Memory and Imaging Applications,” IEEE Trans. Electron Devices ED-20, 91–105 (1973).

    Google Scholar 

  8. Ovshinsky, S.R., “The Chemical Basis of Amorphicity: Structure and Function,” Rev. Roum. Phys 26, 893–903 (1981). (Grigorovici Festschrift.)

    Google Scholar 

  9. Ovshinsky, S.R., “Localized States in the Gap of Amorphous Semiconductors,” Phys. Rev. Lett. 36, 1469–1472 (1976).

    Article  ADS  Google Scholar 

  10. Ovshinsky, S.R., “Amorphous Materials as Interactive Systems,” in Proc. of the Sixth Int. Conf. on Amorphous and Liquid Semiconductors, Leningrad, USSR, (1975): Structure and Properties of Non-Crystalline Semiconductors, B.T. Kolomiets, ed., Nauka, Leningrad (1976) 426–436.

    Google Scholar 

  11. Ovshinsky, S.R., “Principles and Applications of Amorphicity, Structural Change, and Optical Information Encoding,” J. de Physique 42, C4-1095–1104 (1981).

    Google Scholar 

  12. Ovshinsky, S.R., “Lone-Pair Relationships and the Origin of Excited States in Amorphous Chalcogenides,” in Proc. of the Int. Conf. on Structure and Excitation of Amorphous Solids, Williamsburg, Virginia, (1976) 31–36.

    Google Scholar 

  13. Ovshinsky, S.R., “An Introduction to Ovonic Research,” J. Non-Cryst. Solids 2, 99–106 (1970).

    Article  ADS  Google Scholar 

  14. Mandelbrot, B.B., The Fractal Geometry of Nature, W.H. Freeman, New York, (1983).

    Google Scholar 

  15. Ovshinsky, S.R., “Reversible Electrical Switching Phenomena in Disordered Structures,” Phys. Rev. Lett. 21, 1450–1453 (1968).

    Article  ADS  Google Scholar 

  16. Ovshinsky, S.R., “Compositionally Varied Materials and Method for Synthesizing the Materials,” U.S. Patent Application Serial No. 422, 155, filed 9/23/82.

    Google Scholar 

  17. Ovshinsky, S.R., “Chemical Modification of Amorphous Chalcogenides,” in Proc. of the Seventh Int. Conf. on Amorphous and Liquid Semiconductors, Edinburgh, Scotland, (1977) 519–523.

    Google Scholar 

  18. Fritzsche, H., “Summary Remarks,” in Proc. of the Sixth Int. Conf. on Amorphous and Liquid Semiconductors, Leningrad, USSR, (1975): Electronic Phenomena in Non-Crystalline Semiconductors, B.T. Kolomiets, ed., Nauka, Leningrad (1976) 65–68.

    Google Scholar 

  19. Internal ECD Report, January 1, 1983.

    Google Scholar 

  20. Ovshinsky, S.R., “Roll-to-Roll Mass Production Process for a-Si Solar Cell Fabrication,” in Technical Digest of the First International Photovoltaic Science and Engineering Conference, November 13–16, 1984, Kobe, Japan (in oral presentation).

    Google Scholar 

  21. Ovshinsky, S.R. and Madan, A., “Properties of Amorphous Si:F:H Alloys,” in Proc. of 1978 Meeting of the American Section of the International Solar Energy Society, K.W. Boer and A.F. Jenkins, eds., As of ISES, University of Delaware, (1978) 69–73.

    Google Scholar 

  22. Ovshinsky, S.R. and Madan, A., “A New Amorphous Silicon-Based Alloy for Electronic Applications,” Nature 276, 482–484 (1978).

    Article  ADS  Google Scholar 

  23. Ovshinsky, S.R. and Izu, M., “Amorphous Semiconductors Equivalent to Crystalline Semiconductors,” U.S. Patent No. 4,217,374, filed 3/8/78; Ovshinsky, S.R. and Madan, A., “Amorphous Semiconductors Equivalent to Crystalline Semiconductors Produced by Glow-Discharge Process” U.S. Patent No. 4,226,898, filed 3/16/78; Ovshinsky, S.R. and Izu, M., “Method for Optimizing Photoresponsive Amorphous Alloys and Devices,” U.S. Patent No. 4,342,044, filed 9/9/80.

    Google Scholar 

  24. Guha, S., “Light-Induced Effects in Amorphous Silicon Alloys - Design of Solar Cells with Improved Stability,” to be presented at the Eleventh Int. Conf. on Amorphous and Liquid Semiconductors, Rome, Italy, September 2–6, 1985.

    Google Scholar 

  25. Yang, J., Mohr, R., Ross, R., and Fournier, J., to be published.

    Google Scholar 

  26. Yang, J., Mohr, R., Ross, R., and Fournier, J., to be published.

    Google Scholar 

  27. Ovshinsky, S.R., “The Chemistry of Glassy Materials and Their Relevance to Energy Conversion,” J. Non-Cryst. Solids 42, 335–344 (1980).

    Article  ADS  Google Scholar 

  28. Ovshinsky, S.R.and Flasck, R.A., “Method and Apparatus for Making a Modified Amorphous Glass Material,” U.S. Patent No. 4,339,255, filed 9/9/80.

    Google Scholar 

  29. Tachibana, A., Yamabe, T., Miyake, M., Tanaka, K., Kato, H., and Fukui, K., “Electronic Behavior of Amorphous Chalcogenide Models,” J. Phys. Chem. 82, 272–277 (1978).

    Article  Google Scholar 

  30. Tanaka, K., Yamabe, T., and Fukui, K., “A Role of the Lowest Unoccupied Molecular Orbital of the Local Structure of Amorphous Materials,” Solar Energy Mats. 8, 9–13 (1982).

    Article  ADS  Google Scholar 

  31. Fukui, K., “Role of Frontier Orbitals of Chemical Reactions,” Science 218, 747–754 (1982).

    Article  ADS  Google Scholar 

  32. Ovshinsky, S.R., “Intuition and Quantum Chemistry,” to be published by D. Reidel in Proc. of the Nobel Laureate Symposium of Applied Quantum Chemistry, 1984 Int. Chemical Congress of Pacific Basin Societies, Honolulu, Hawaii, December 18, 1984.

    Google Scholar 

  33. See, for example, Ovshinsky, S.R., “The Role of Free Radicals in the Formation of Amorphous Thin Films,” in Proc. Int. Ion Engineering Congress (ISIAT ’83 & IPAT ’83), Kyoto, Japan, (1983) 817–828. Ovshinsky, S.R. and Izu, M., “Amorphous Semiconductors Equivalent to Crystalline Semiconductors,” U.S. Patent No. 4,217,374, filed 3/8/78; Ovshinsky, S.R., Allred, D., Walter, L., and Hudgens, S., “Method of Making Amorphous Semiconductor Alloys and Devices Using Microwave Energy,” U.S. Patent No. 4,504,518, filed 4/30/84.

    Google Scholar 

  34. Cohen, M.H., Fritzsche, H., and Ovshinsky, S.R., “Simple Band Model for Amorphous Semiconducting Alloys,” Phys. Rev. Lett. 22, 1065–1068 (1969).

    Article  ADS  Google Scholar 

  35. Ovshinsky, S.R., “The Ovshinsky Switch,” in Proc. of the Fifth Annual National Conf. on Industrial Research, Chicago, (1969) 86–90.

    Google Scholar 

  36. Ovshinsky, S.R. and Klose, P.H., “Imaging in Amorphous Materials by Structural Alteration,” J. Non-Cryst. Solids 8–10, 892–898 (1972).

    Article  Google Scholar 

  37. Ovshinsky, S.R., “Electronic and Structural Changes in Amorphous Materials as a Means of Information Storage and Imaging,” in Proc. of the Fourth Int. Congress for Reprography and Information, Hanover, Germany, (1975) 109–114.

    Google Scholar 

  38. Ovshinsky, S.R., “Amorphous Materials as Optical Information Media,” J. Appl. Photographic Eng. 3, 35–39 (1977).

    Google Scholar 

  39. Ovshinsky, S.R., “Amorphous Materials—Past, Present and Future,” Problems and Prospects for 2004, Symposium on Glass Science and Technology, Vienna, Austria, July 3, 1984; J. Non-Cryst. Solids (in press). (Kreidl Festschrift.)

    Google Scholar 

  40. Guth, A.H., “Inflationary Universe: A Possible Solution to the Horizon and Flatness Problems,” Phys. Rev. D 23, 347–356 (1981).

    Article  ADS  Google Scholar 

  41. Guth, A.H. and Steinhardt, P.J., “The Inflationary Universe,” Sci. Am. 250, 116–128 (1984).

    Article  ADS  Google Scholar 

  42. Anderson, P.W., “Model for the Electronic Structure of Amorphous Semiconductors,” Phys. Rev. Lett. 34, 953–955 (1973).

    Article  ADS  Google Scholar 

  43. Ovshinsky, S.R., “The Physical Base of Intelligence-Model Studies,” presented at the Detroit Physiological Society (1959).

    Google Scholar 

  44. Southworth, M.P., “The Threshold Switch: New Component for Ac Control,” Control Engineering 11, 69–72 (1964).

    Google Scholar 

  45. Ovshinsky, S.R., “Nerve Impulse,” (1955). Unpublished.

    Google Scholar 

  46. Bionics Meeting, Dayton, Ohio, Spring 1960.

    Google Scholar 

  47. Mott, N.F., “Electrons in Glass,” 1977 Nobel Prize Lecture, Science 201, 871–875 (1978).

    Article  ADS  Google Scholar 

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Ovshinsky, S.R. (1985). Chemistry and Structure in Amorphous Materials: The Shapes of Things to Come. In: Adler, D., Fritzsche, H., Ovshinsky, S.R. (eds) Physics of Disordered Materials. Institute for Amorphous Studies Series. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2513-0_4

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  • DOI: https://doi.org/10.1007/978-1-4613-2513-0_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9519-8

  • Online ISBN: 978-1-4613-2513-0

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