Skip to main content
SpringerLink
Log in

Interaction Induced Light Scattering from Tetrahedral Molecules

  • Chapter
Phenomena Induced by Intermolecular Interactions

Part of the book series: NATO ASI series ((ASIB,volume 127))

Abstract

Collision induced light scattering from tetrahedral molecules is an highly collective N-body process and depends — in principle — on the full charge distribution of the molecules and, consequently, on the full orientation dependent pair potentials and induced pair polarizabilities. The pair potential is usually treated in terms of many-center Lennard-Jones potentials. For the calculation of the collision induced pair polarizabilities an interacting point atom polarizability model is introduced, the properties of which are discussed. It may be cast into a form most suitable for molecular dynamics simulations of condensed phases. As an illustration of the applicability of these models a computer simulation for dense fluids resembling CF4 (for two different densities) and CCl4 are presented.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 69.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 89.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • An, S. C., 1975, Depolarized Rayleigh scattering in simple fluids, Dissertation, The Catholic University of America, Washington D. C

    Google Scholar 

  • An, S. C., Montrose, C. J., and Litovitz, T. A., 1976, Low-frequency structure in the depolarized spectrum of argon, J. Chem. Phys., 64: 3717

    Article  Google Scholar 

  • An, S. C., Fishman, L., Litovitz, T. A., Montrose, C. J., and Posch, H. A., 1979, Depolarized light scattering from dense noble gases, J. Chem. Phys., 70: 4626

    Article  Google Scholar 

  • Applequist, J., Carl, J. R., and Fung, K. K., 1972, An atom dipole interaction model for molecular polarizability. Application to polyatomic molecules and determination of atom polarizabilities, J. Am. Chem. Soc., 94: 2952

    Article  Google Scholar 

  • Applequist, J., 1977, An atom dipole interaction model for molecular optical properties, Accts. Chem. Res., 10: 79

    Article  Google Scholar 

  • Barocchi, F., and McTague, J. P., 1974, Binary collision induced light scattering in liquid CH4, Opt. Commun., 12: 202

    Article  Google Scholar 

  • Barocchi, F., and McTague, J. P., 1975, Collision induced light scattering in gaseous CH4, Phys. Lett., A53: 488

    Google Scholar 

  • Barocchi, F., Zoppi, M., Shelton, D. P., and Tabisz, G. C., 1977, A comparison of the spectral features of the collision-induced light scattering by the molecular gases CH4 and CF4 and by argon, Can. J. Phys., 55: 1962

    Article  Google Scholar 

  • Barron, L. D., and Buckingham, A. D., 1975, Rayleigh and Raman optical activity, Ann. Rev. Phys. Chem., 26: 381

    Article  Google Scholar 

  • Bucaro, J. A., and Litovitz, T. A., 1971, Rayleigh scattering: collisional motions in liquids, J. Chem. Phys., 54: 3846

    Article  Google Scholar 

  • Bucaro, J. A., and Litovitz, T. A., 1971, Molecular motions in CCl4: light scattering and infrared absorption, J. Chem. Phys., 55: 3585

    Google Scholar 

  • Buckingham, A. D., and Tabisz, G. C., 1977, Collision-induced rotational Raman scattering, Optics Letters, 1: 220

    Article  Google Scholar 

  • Buckingham, A. D., and Tabisz, G. C., 1978, Collision-induced rotational Raman scattering by tetrahedral and octahedral molecules, Molec. Phys., 36: 583

    Google Scholar 

  • Buckingham, A. D., and Clarke Hunt, K. L., 1980, The pair polarizability anisotropy of SF6 in the point-atom-polarizability approximation, Molec. Phys., 40: 643

    Google Scholar 

  • Frommhold, L., 1981, Collision-induced scattering and the diatom-polarizabilities, Adv. Chem. Phys., 46: 1

    Google Scholar 

  • Frommhold, L., 1984, this volume

    Google Scholar 

  • Gabelnick, H. S., and Strauss, H. L., 1968, Low-frequency motions in liquid carbon-tetrachloride. II The Raman spectrum, J. Chem. Phys., 49: 2334

    Google Scholar 

  • Gharbi, A., and Le Duff, 1977, Collision-induced scattering for molecules, Physica, 87A: 177

    Article  Google Scholar 

  • Gharbi, A., and Le Duff, 1978, Line shape of the collision-induced scattering in CF4, Physica, 90A: 619

    Article  Google Scholar 

  • Gharbi, A., and Le Duff, 1980, Many-body correlations for Raman and Rayleigh collision induced scattering, Molec. Phys., 40: 545

    Google Scholar 

  • Gornall, W. S., Howard-Lock, H. E., and Stoicheff, B. P., 1970, Induced anisotropy and light scattering in liquids, Phys. Rev. A, 1: 1288

    Google Scholar 

  • Guillot, B., Bratos, S., and Birnbaum, G., 1980, Theoretical study of spectra of depolarized light scattering from dense rare-gas fluids, Phys. Rev. A, 22: 2230

    Article  Google Scholar 

  • Ho, J. H. K., and Tabisz, G. C., 1973, Collision-induced light scattering in liquids and the binary collision model, Can. J. Phys., 51: 2025

    Google Scholar 

  • Howard-Lock, H. E., and Taylor, R. S., 1974, Induced anisotropy and light scattering in liquids. II., Can. J. Phys., 52: 2436

    Google Scholar 

  • Keyes, T., and Ladanyi, B. M., 1977, The role of local fields and interparticle pair correlations in light scattering by dense fluids II. The depolarized spectrum for non-spherical molecules, Molec. Phys., 33: 1099

    Google Scholar 

  • Ladanyi, B. M., and Keyes, T., 1979, Effect of internal fields on depolarized light scattering from n-alkane gases, Molec. Phys., 37: 1809

    Article  Google Scholar 

  • Ladanyi, B. M., 1983, Molecular dynamics study of Rayleigh light scattering from molecular fluids, J. Chem. Phys., 78: 2189

    Google Scholar 

  • Ladd, A. J. C., Litovitz, T. A., and Montrose, C. J., 1979, Molecular dynamics studies of depolarized light scattering from argon at various fluid densities, J. Chem. Phys., 71: 4242

    Google Scholar 

  • Ladd, A. J. C., Litovitz, T. A., Clarke, J. H. R., and Woodcock, L. V., 1980, Molecular dynamics simulations of depolarized Rayleigh scattering from liquid argon at the triple point, J. Chem. Phys., 72: 1759

    Google Scholar 

  • Lallemand, P. M., 1970, Spectral distribution of double light scattering by gases, Phys. Rev. Lett., 25: 1079

    Google Scholar 

  • Leite, R. C. C., Moore, R. S., and Porto, S. P. S., 1964, Use of gas lasers in studies of the depolarization of the Rayleigh scattering from simple liquids, J. Chem. Phys., 40: 3741

    Google Scholar 

  • Levine, H. B., and Birnbaum, G., 1968, Collision-induced light scattering, Phys. Rev. Lett., 20: 439

    Article  Google Scholar 

  • Madden, P. A., 1977, The lineshape of the depolarised Rayleigh scattering from liquid argon, Chem. Phys. Lett., 47: 174

    Google Scholar 

  • Madden, P. A., 1978, The depolarized Rayleigh scattering from fluids of spherical molecules, Molec. Phys., 36: 365

    Google Scholar 

  • Neumann, M., 1984, in preparation

    Google Scholar 

  • Oxtoby, D. W., 1978, The calculation of pair polarizabilities through continuum electrostatic theory, J. Chem. Phys., 69: 1184

    Google Scholar 

  • Posch, H. A., 1979, Collision-induced light scattering from fluids composed of tetrahedral molecules. I. Molec. Phys., 37: 1059

    Google Scholar 

  • Posch, H. A., 1980, Collision induced light scattering from fluids composed of tetrahedral molrcules. II. Intensities, Molec. Phys., 40: 1137

    Google Scholar 

  • Posch, H. A., 1982, Collision induced light scattering from fluids composed of tetrahedral molecules. III. Neopentane vapour, Molec. Phys., 46: 1213

    Google Scholar 

  • Prasad, P. L., and Nafie, L. A., 1979, The atom dipole interaction model of Raman optical activity: Reformulation and comparison to the general two-group model, J. Chem. Phys., 70: 1979

    Google Scholar 

  • Prengel, A. T., and Gornall, W. S., 1976, Raman scattering from colliding molecules and Van der Waals dimers in gaseous methane, Phys. Rev. A, 13: 253

    Google Scholar 

  • Shelton, D. P., and Tabisz, G. C., 1975, Moment analysis of collision-induced light scattering from compressed CF4, Phys. Rev. A., 11: 1571

    Google Scholar 

  • Shelton, D. P., Mathur, M. S., and Tabisz, G. C., 1975, Collision-induced light scattering by compressed CF4 and CF4-He mixtures, Phys. Rev. A, 11: 834

    Article  Google Scholar 

  • Shelton, D. P., and Tabisz, G. C., 1980, Binary collision induced light scattering by isotropic molecular gases. II. Molecular spectra and induced rotational Raman scattering, Molec. Phys., 40: 299

    Article  Google Scholar 

  • Shelton, D. P., Tabisz, G. C., Barocchi, F., and Zoppi, M., 1982, The three body correlation spectrum in collision induced light scattering by isotropic molecular gases, Molec. Phys., 46: 21

    Article  Google Scholar 

  • Treitl, K., Pleich, R., and Posch, H. A., 1984, in preparation

    Google Scholar 

  • Varshneya, D., Shirron, S. F., Litovitz, T. A., Zoppi, M., and Barocchi, F., 1981, Collision-induced light scattering: Integrated intensity of argon, Phys. Rev. A, 23: 77

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Experimentalphysik, Universität Wien, Strudlhofgasse 4, A-1090, Vienna, Austria

    M. Neumann & H. A. Posch

Authors
  1. M. Neumann
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. A. Posch
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. U.S. Department of Commerce, National Bureau of Standards, Gaithersburg, Maryland, USA

    G. Birnbaum

Rights and permissions

Reprints and permissions

Copyright information

© 1985 Plenum Press, New York

About this chapter

Cite this chapter

Neumann, M., Posch, H.A. (1985). Interaction Induced Light Scattering from Tetrahedral Molecules. In: Birnbaum, G. (eds) Phenomena Induced by Intermolecular Interactions. NATO ASI series, vol 127. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2511-6_24

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-2511-6_24

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9518-1

  • Online ISBN: 978-1-4613-2511-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation