Skip to main content
SpringerLink
Log in

Rearrangements, Intramolecular Exchanges, and Isomerizations of Organometallic Compounds

  • Chapter
Mechanisms of Inorganic and Organometallic Reactions

  • 132 Accesses

Abstract

Cis/trans isomerizations of square-planar d8 complexes normally involve consecutive displacement of coordinated ligands by solvent or other ligand molecules. Stereochemical nonrigidity of a five-coordinate transient adduct or dissociative mechanisms have been less clearly defined.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. H. Azizian, K. R. Dixon, C. Eaborn, A. Pidcock, N. M. Shuaib, and J. Vinaixa, J. Chem. Soc., Chem. Commun., 1020 (1982).

    Google Scholar 

  2. Yu. K. Grishin, V. A. Roznyatovsky, Yu. A. Ustynyuk, S. N. Titova, G. A. Domrachev, and G. A. Razuvaev, Polyhydron, 2, 895 (1983).

    Google Scholar 

  3. A. Goodacre and K. G. Orrell, J. Chem. Soc., Dalton Trans., 153 (1983).

    Google Scholar 

  4. D. R. Anton and R. H. Crabtree, Organometallics, 2, 621 (1983).

    Google Scholar 

  5. J. M. Brown, F. M. Dayrit, and D. Lightowler, J. Chem. Soc., Chem. Commun., 414 (1983).

    Google Scholar 

  6. M. Kotzian, C. G. Kreiter, G. Michael, and S. Özkar, Chem. Ber., 116, 3637 (1983).

    Google Scholar 

  7. S. Özkar and C. G. Kreiter, J. Organomet. Chem., 256, 57 (1983).

    Google Scholar 

  8. C. G. Kreiter and S. Özkar, Z. Naturforsch. B, 38, 1424 (1983).

    Google Scholar 

  9. O. Schneidsteger, G. Huttner, V. Bejenke, and W. Gartzke, Z. Naturforsch. B, 38, 1598 (1983).

    Google Scholar 

  10. D. L. Reger, C. A. Swift, and L. Lebioda, J. Am. Chem. Soc., 105, 5343 (1983).

    Google Scholar 

  11. J. A. L. Palmer and S. B. Wild, Inorg. Chem., 22, 4054 (1983).

    Google Scholar 

  12. S. L. Hawthorne, A. H. Bruder, and R. C. Fay, Inorg. Chem., 22, 3368 (1983).

    Google Scholar 

  13. R. C. Fay and A. F. Lindmark, J. Am. Chem. Soc., 105, 2118 (1983).

    Google Scholar 

  14. C. G. Kreiter and U. Koemm, Z Naturforsch. B, 38, 943 (1983).

    Google Scholar 

  15. U. Koemm and C. G. Kreiter, J. Organomet. Chem., 240, 27 (1982).

    Google Scholar 

  16. J. A. K. Howard, P. Mitrprachachon, and A. Roy, J. Organomet. Chem., 235, 375 (1982).

    Google Scholar 

  17. M. Cosandey, M. von Biiren, and H.-J. Hansen, Helv. Chim. Acta, 66, 1 (1983).

    Google Scholar 

  18. M. R. Burke, J. Takats, F.-W. Grevels, and J. G. A. Reuvers, J. Am. Chem. Soc., 105, 4092 (1983).

    Google Scholar 

  19. M. A. Arthers and S. M. Nelson, J. Coord. Chem., 13, 29 (1983).

    Google Scholar 

  20. D. Parker, J. Organomet. Chem., 240, 83 (1982).

    Google Scholar 

  21. H. Lehmkuhl, J. Grundke, and R. Mynott, Chem. Ber., 116, 159 (1983).

    Google Scholar 

  22. H. Lehmkuhl, S. Pasynkiewicz, R. Benn, and A. Rufinska, J. Organomet. Chem., 240, C27 (1982).

    Google Scholar 

  23. N. M. Boag, R. J. Goodfellow, M. Green, B. Hessner, J. A. K. Howard, and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 2585 (1983).

    Google Scholar 

  24. J.M. Brown, P. A. Chaloner, and G. A. Morris, J. Chem.Soc., Chem. Commun., 664 (1983).

    Google Scholar 

  25. P. B. Winston, S. J. Nieter Burgmayer, and J. L. Templeton, Organometallics, 2, 167 (1983).

    Google Scholar 

  26. R. S. Herrick, S. J. Nieter Burgmayer, and J. L. Templeton, Inorg. Chem., 22, 3275 (1983).

    Google Scholar 

  27. M. H. Chisholm, K. Folting, D. M. Hoffman, J. C. Huffman, and J. Leonelli, J. Chem. Soc., Chem. Commun., 589 (1983).

    Google Scholar 

  28. H. G. Alt and H. I. Hayen, Angew. Chem. Int. Ed. Engl, 22, 1008 (1983).

    Google Scholar 

  29. D. F. R. Gilson, G. Gomez, I. S. Butler, and P. J. Fitzpatrick, Canad. J. Chem., 61, 737 (1983).

    Google Scholar 

  30. A. Shaver, A. Eisenberg, K. Yamada, A. J. F. Glark, and S. Farrokyzad, Inorg. Chem., 22, 4154 (1983).

    Google Scholar 

  31. D. F. R. Gilson and G. Gomez, J. Organomet. Chem., 240, 41 (1982).

    Google Scholar 

  32. M. J. McGlinchey, J. L. Fletcher, B. G. Sayer, P. Bougeard, R. Faggiani, G. J, L. Lock, A. D. Bain, C. Rodger, E. P. Kündig, D. Astruc, J.-R. Hamon, P. Le Maux, S. Top, and G. Jaouen, J. Chem. Soc., Chem., Commun., 634 (1983).

    Google Scholar 

  33. D. R. Wilson, R. D. Ernst, and T. H. Cymbaluk, Organometallics, 2, 1220 (1983).

    Google Scholar 

  34. M. Moll and H.-J. Seibold, J. Organomet. Chem., 248, 343 (1983).

    Google Scholar 

  35. A. Scrivanti, G. Carturan, and B. Crociani, Organometallics, 2, 1612 (1983).

    Google Scholar 

  36. A. T. Patton, C. E. Strouse, C. B. Knobler, and J. A. Gladysz, J. Am. Chem. Soc., 105, 5804 (1983).

    Google Scholar 

  37. W. A. Kiel, G.-Y. Lin, A. G. Constable, F. B. McCormick, C. E. Strouse, O. Eisenstein, and J. A. Gladysz, J. Am. Chem. Soc., 104, 4865 (1982).

    Google Scholar 

  38. A. Wong and J. A. Gladysz, J. Am. Chem. Soc., 104, 4948 (1982).

    Google Scholar 

  39. M. Luksza, S. Himmel, and W. Malisch, Angew. Chem. Int. Ed. Engl, 22, 416 (1983).

    Google Scholar 

  40. J. R. Sweet and W. A. G. Graham, J. Am. Chem. Soc., 105, 305 (1983

    Google Scholar 

  41. J. R. Sweet and W. A. G. Graham, Organometallics, 2, 135 (1983).

    Google Scholar 

  42. W. D. Jones and F. J. Feher, J. Am. Chem. Soc., 104, 4240 (1982).

    Google Scholar 

  43. M. J. Hails, B. E. Mann, and C. M. Spencer, J. Chem. Soc., Chem. Commun., 120 (1983).

    Google Scholar 

  44. T. A. Albright, P. Hofmann, R. Hoffmann, C. P. Lillya, and P. A. Dobosh, J. Am. Chem. Soc., 105, 3396 (1983).

    Google Scholar 

  45. L. K. K. LiShingMan, J. G. A. Reuvers, J. Takats, and G. Deganello, Organometallics, 2, 28 (1983).

    Google Scholar 

  46. H. Lehmkuhl and C. Naydowski, J. Organomet. Chem., 240, C30 (1982).

    Google Scholar 

  47. H. Werner, H.-J. Krans, V. Schubert, K. Ackermann, and P. Hofmann, J. Organomet. Chem., 250, 517 (1983).

    Google Scholar 

  48. C. A. Ghilardi, P. Innocenti, S. Midollini, and A. Orlandini, J. Organomet. Chem., 231, C78 (1982).

    Google Scholar 

  49. M. Y. Dahrensbourg, R. Bau, M. W. Marks, R. R. Burch, J. C. Deaton, and S. Slater, J. Am. Chem. Soc., 104, 6961 (1982).

    Google Scholar 

  50. M. F. Lappert, A. Singh, J. L. Atwood, W. E. Hunter, J. Chem. Soc., Chem. Commun., 206 (1983).

    Google Scholar 

  51. J. C. Bommer and K. W. Morse, Inorg. Chim. Acta, 74, 25 (1983).

    Google Scholar 

  52. J. Browning, G. W. Bushnell, K. R. Dixon, and A. Pidcock, Inorg. Chem., 22, 2226 (1982).

    Google Scholar 

  53. E. W. Abel, G. D. King, K. G. Orrell, G. M. Pring, V. Sik, and T. S. Cameron, Polyhedron, 2, 1117 (1983).

    Google Scholar 

  54. E. W. Abel, G. D. King, K. G. Orrell, and V. Sik, Polyhedron, 2, 1363 (1983).

    Google Scholar 

  55. P. J. Pogorzelec and D. H. Reid, J. Chem. Soc., Chem. Commun., 289 (1983).

    Google Scholar 

  56. S. G. Davies and S. J. Simpson, J. Organomet. Chem., 240, C48 (1982).

    Google Scholar 

  57. A. J. Canty, N. J. Minchin, J. M. Patrick, and A. H. White, Aust. J. Chem., 36, 1107 (1983).

    Google Scholar 

  58. P. Braunstein, D. Matt, and Y. Dusausoy, Inorg. Chem., 22, 2043 (1983).

    Google Scholar 

  59. R. B. A. Pardy, M. J. Taylor, E. C. Constable, J. D. Merch, and J. K. M. Sanders, J. Organomet. Chem., 231, C25 (1982).

    Google Scholar 

  60. M. Brookhart, M. L. H. Green, and R. B. A. Pardy, J. Chem. Soc., Chem. Commun., 691 (1983).

    Google Scholar 

  61. M. Brookhart, W. Lamanna, and A. R. Pinhas, Organometallics, 2, 638 (1983).

    Google Scholar 

  62. M. Brookhart and A. Lukacs, Organometallics, 2, 649 (1983).

    Google Scholar 

  63. R. J. Kazlauskas and M. S. Wrighton, J. Am. Chem. Soc., 104, 6005 (1982).

    Google Scholar 

  64. C. Roe, J. Am. Chem. Soc., 105, 7770 (1983).

    Google Scholar 

  65. W. G. Hatton and J. A. Gladysz, J. Am. Chem. Soc., 105, 6157 (1983).

    Google Scholar 

  66. H. W. Turner, R. R. Shrock, J. D. Fellmann, and S. J. Holmes, J. Am. Chem. Soc., 105, 4942 (1983).

    Google Scholar 

  67. S. J. Holmes, D. N. Clark, H. W. Turner, and R. R. Schrock, J. Am. Chem. Soc., 104, 6322 (1982).

    Google Scholar 

  68. M. D. Curtis, N. A. Fotinos, L. Messerle, and A. P. Sattelberger, Inorg. Chem., 22, 1559 (1983).

    Google Scholar 

  69. J.-P. Lecomte, J.-M. Lehn, D. Parker, J. Guilhem, and C. Pascard, J. Chem. Soc., Chem. Commun., 296 (1983).

    Google Scholar 

  70. S. Okeya, B. F. Taylor, and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 971 (1983).

    Google Scholar 

  71. R. J. Puddephatt, K. A. Azam, R. H. Hill, M. P. Brown, C. D. Nelson, R. P. Moulding, K. R. Seddon, and M. C. Grossel, J. Am. Chem. Soc., 105, 5642 (1983).

    Google Scholar 

  72. K. A. Azam and R. J. Puddephatt, Organometallics, 2, 1396 (1983).

    Google Scholar 

  73. M. C. Grossel, R. P. Moulding, and K. R. Seddon, J. Organomet. Chem., 247, C32 (1983).

    Google Scholar 

  74. H. C. Aspinall, A. J. Deeming, and S. Donovan-Mtunzi, J. Chem. Soc., Dalton Trans., 2669 (1983).

    Google Scholar 

  75. A. F. Dyke, S. A. R. Knox, M. J. Morris, and P. J. Naish, J. Chem. Soc., Dalton Trans., 1417 (1983).

    Google Scholar 

  76. K.-H. Franzreb and C. G. Kreiter, J. Organomet. Chem., 246, 189 (1983).

    Google Scholar 

  77. P. O. Nubel and T. L. Brown, Organometallics, 3, 29 (1984)

    Google Scholar 

  78. P. O. Nubel and T. L. Brown, J. Am. Chem. Soc., 106, 644 (1984).

    Google Scholar 

  79. R. D. Adams, D. A. Katahira, and L.-W. Yang, Organometallics, 1, 231 (1982).

    Google Scholar 

  80. J. A. King and K. P. C. Vollhardt, J. Am. Chem. Soc., 105, 4846 (1983).

    Google Scholar 

  81. T. V. O’Halloran and S. J. Lippard, J. Am. Chem. Soc., 105, 3341 (1983).

    Google Scholar 

  82. B. Knobler, H. D. Kaesz, G. Minghetti, A. L. Bandini, G. Banditelli, and F. Bonati, Inorg. Chem., 22, 2324 (1983).

    Google Scholar 

  83. K. H. Theopold and R. G. Bergman, J. Am. Chem. Soc., 105, 464 (1983).

    Google Scholar 

  84. W. J. Laws and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1020 (1983).

    Google Scholar 

  85. R. E. Colborn, A. F. Dyke, S. A. R. Knox, K. A. Mead, and P. Woodward, J. Chem. Soc., Dalton Trans., 2099 (1983).

    Google Scholar 

  86. B. E. Hanson and J. S. Mancini, Organometallics, 2, 126 (1983).

    Google Scholar 

  87. D. M. Hoffman, R. Hoffmann, and C. R. Fisel, J. Am. Chem. Soc., 104, 3858 (1982).

    Google Scholar 

  88. M. J. McGlinchey, M. Mlekuz, P. Bougeard, B. G. Sayer, A. Marinetti, J.-Y. Saillard, and G. Jaouen, Can. J. Chem., 61, 1319 (1983).

    Google Scholar 

  89. D. M. Hoffman and R. Hoffmann, J. Chem. Soc., Dalton Trans., 1471 (1982).

    Google Scholar 

  90. M. J. Freeman, M. Green, A. G. Orpen, I. D. Slater, and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1332 (1983).

    Google Scholar 

  91. B. T. Heaton, L. Strona, R. Delia Pergola, J. L. Vidal, and R. C. Schoening, J. Chem. Soc., Dalton Trans., 1941 (1983).

    Google Scholar 

  92. Granozzi, E. Tondello, M. Casarin, S. Aime, and D. Osella, Organometallics, 2, 430 (1983).

    Google Scholar 

  93. J. K. Kouba, E. L. Muetterties, M. R. Thompson, and V. W. Day, Organometallics,2, 1065 (1983).

    Google Scholar 

  94. J. T. Park, J. R. Shapley, M. R. Churchill, and C. Bueno, Inorg. Chem., 22, 1579 (1983).

    Google Scholar 

  95. R. D. Barr, M. Green, J. A. K. Howard, T. B. Marder, F. G. A. Stone, J. Chem. Soc., Chem., Commun., 759 (1983).

    Google Scholar 

  96. B. E. Mann, C. M. Spencer, and A. K. Smith, J. Organomet. Chem., 244, C17 (1983).

    Google Scholar 

  97. S. Aime, D. Osella, R. Gobetto, B. F. G. Johnson, and L. Milone, Inorg. Chim. Acta, 68, 141 (1983).

    Google Scholar 

  98. Richter, H. Beurich, M. Müller, N. Gärtner, and H. Vahrenkamp, Chem. Ber., 116, 3774 (1983).

    Google Scholar 

  99. A. Ceriotti, G. Longoni, R. Delia Pergola, B. T. Heaton, and D. O. Smith, J. Chem. Soc., Dalton Trans., 1433 (1983).

    Google Scholar 

  100. J. B. Keister and J. R. Shapley, Inorg. Chem., 21, 3304 (1982).

    Google Scholar 

  101. A.C. Wills, F. W. B. Einstein, R. M. Ramadan, and R. K. Pomeroy, Organometallics, 2, 935 (1983).

    Google Scholar 

  102. N. J. Forrow, S. A. R. Knox, M. J. Morris, and A. G. Orpen, J. Chem. Soc., Chem. Commun., 234 (1983).

    Google Scholar 

  103. L. Busetto, J. C. Jeffery, R. M. Mills, F. G. A. Stone, M. J. Went, and P. Woodward, J. Chem. Soc., Dalton Trans., 101 (1983).

    Google Scholar 

  104. R. J. Goudsmit, B. F. G. Johnson, J. Lewis, P. R. Raithby, and M. J. Rosales, J. Chem. Soc., Dalton Trans., 2257 (1983).

    Google Scholar 

  105. S. Aime and A. J. Deeming, J. Chem. Soc., Dalton Trans., 1807 (1983).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Imperial Chemical Industries P.L.C., Billingham, Cleveland, UK

    M. V. Twigg

Authors
  1. M. V. Twigg
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Imperial Chemical Industries P.L.C., Billingham, Cleveland, UK

    M. V. Twigg

Rights and permissions

Reprints and permissions

Copyright information

© 1985 Plenum Press, New York

About this chapter

Cite this chapter

Twigg, M.V. (1985). Rearrangements, Intramolecular Exchanges, and Isomerizations of Organometallic Compounds. In: Twigg, M.V. (eds) Mechanisms of Inorganic and Organometallic Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2479-9_13

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-2479-9_13

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9503-7

  • Online ISBN: 978-1-4613-2479-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation