Abstract
Air pollutant samples are very complex in nature, containing chemical species which range in concentration from low ppt to high ppm levels.(1) Chemical compounds present in the atmosphere include both gaseous components and those present in dispersions of liquid or solid particles. Samples may be collected from ambient and interior (work space) air environments and mobile and stationary source emissions.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
D. Schuetzle, in Biochemical Applications of Mass Spectrometry(G. R. Waller and O. C. Dermer, eds.), Wiley-Interscience, New York, 1980, pp. 970–1001.
D.J. Robertson, R. H. Groth, D. G. Gardner, and E. G. Glastris, J. Air Pollut. Contr. Assoc. 29, 143 (1979).
W. D. Bowers, M. L. Parsons, R. E. Clement, G. A. Eiceman, and F. W. Karasek, J. Chromatogr. 206, 279 (1981).
A. Bjorseth and G. Eklund, HighResoln. Chromatogr./Chromatogr. Commun. 2, 22 (1979).
E. D. Pellizzari, J. E. Bunch, B. H. Carpenter, and E. Sawicki, Environ. Sci. Technol. 9, 553 (1975).
M. B. Neher and P. W. Jones, Anal. Chem. 49, 512 (1977).
C. V. Hampton, W. R. Pierson, T. M. Harvey, W. S. Updegrove, and R. S. Marano, Environ. Sci. Technol. 16, 287 (1981).
D. Schuetzle, Biomed. Mass Spectrom. 2, 288 (1975).
L. van Vaeck, G. Broddin, and K. van Cauwenberghe, Biomed. Mass Spectrom. 7, 473 (1980).
W. Cautreels and K. van Cauwenberghe, Atmos. Environ. 12, 1133 (1978).
R. A. Rasmussen and R. S. Hutton, Bioscience 22, 294 (1972).
E. D. Pellizzari, J. E. Bunch, R. E. Berkley, and J. T. Bursey, Biomed. Mass Spectrom. 3, 196 (1976).
E. D. Pellizzari, J. E. Bunch, R. E. Berkley, and J. McRae, Anal. Chem. 48, 803 (1976).
J. T. Bursey, E. D. Pellizzari, D. Smith, J. Bunch, R. Williams, and R. Berkley, Am. Lab. 35, 35 (1977).
E. D. Pellizzari, Measurement of Carcinogenic Vapors in Ambient Atmospheres, EPA 600/7- 78-062, Environmental Protection Agency, Washington, D.C. (1978).
J. A. Parsons and S. Mitzner, Environ. Sci. Technol. 9, 1053 (1975).
P. W.Jones, J. E. Wilkinson, and P. E. Strup, Measurement of Poly cyclic Organic Materials and other Hazardous Organic Compounds on Stack Gases, NTIS-U.S. Department of Commerce, PB-274013 Washington, D.C. (1977).
P. Ciccioli, G. Bertoni, E. Brancaleoni, R. Fratarcangeli, and F. Bruner, J Chromatogr. 126, 757 (1976).
J. N. Pitts, Jr., K. A. van Cauwenberghe, D. Grosjean, J. P. Schmid, D. R. Fitz, W. L. Belser, Jr., G. B. Knudson, and P. M. Hynds, Science 202, 515 (1978).
F. S.-C. Lee, T. M. Harvey, T. J. Prater, M. C. Paputa, and D. Schuetzle, Chemical Analysis of Diesel Particulate Matter and an Evaluation of Artifact Formation in Sampling and Analysis of Toxic Organics in the Atmosphere, ASTM STP 721, American Society for Testing and Materials, 1980, pp. 91–110.
W. G. Jennings, J. High Res. Chromatogr. 2, 221 (1979).
D. Schuetzle, T. J. Prater, T. M. Harvey, and D. E. Hagge, Adv. Mass Spectrom. 7, 231 (1977).
G. Chatot, Anal. Chem. Acta 53, 259 (1971).
C. Golden and E. Sawicki, Int. J. Environ. Anal. Chem. 4, 9 (1975).
D. Schuetzle, and F. S.-C. Lee, in Informational Report of the Measurement and Char-acterization of Diesel Exhaust Emission(J. M. Perez, F. J. Hills, D. Schuetzle, R. L. Williams, eds.), Coordinating Research Council, Atlanta, Georgia, 1981, pp. 65–92.
H. H. Hill, Jr., K. W. Chan, and F. W. Karasek, J. Chromatogr. 131, 245 (1977).
D. Schuetzle and J. Perez, Proceedings of the 74th Annual APCA Meeting, paper #81–56. 4, 1981.
F. S.-C. Lee and D. Schuetzle, in Handbook of Polycyclic Aromatic Hydrocarbons(A. Bjorseth, ed.), Marcel Dekker, New York, 1983, pp. 27–94.
E. D. Pellizzari, Analysis of Organic Air Pollutants by Gas Chromatography and Mass Spectroscopy, NTIS-U.S. Department of Commerce, PB-296 835 Washington, D.C., 1979.
M. Novotny, M. L. Lee, and K. D. Bartle, J. Chromatogr. Sci. 12, 606 (1974).
T. J. Hughes, E. Pellizzari, E. Little, C. Sparacino, and A. Kolber, Mutat. Res. 76(1), 51 (1980).
J. L. Epler, in Chemical Mutagens; Principles and Methods for Their Detection, Vol. 6 (F. J. de Serres, ed.), Plenum, New York, 1980, pp. 239–270.
C. E. Chrisp and G. L. Fisher, Mutation Research 76, 143 (1980).
D. Schuetzle, F. S.-C. Lee, T. J. Prater, and S. B. Tejada, Int. J. Environ. Anal. Chem. 9, 93 (1981).
I. Salmeen, A. M. Durison, T. J. Prater, T. Riley, and D. Schuetzle, Mut. Res. 104, 17 (1982).
D. Schuetzle, T. J. Prater, T. Riley, T. M. Harvey, and D. Hunt, Anal Chem. 54, 265 (1982).
F. W. Karasek, D. W. Denney, K. W. Chan, and R. E. Clement, Anal Chem. 50, 82 (1978).
J. Drozd, Chemical Derivatization in Gas Chromatography, Elsevier, New York, 1981.
F. Bruner, G. Grescentini, and F. Mangani, Anal Chem. 53, 798 (1981).
R. Eichmann, G. Ketseridis, G. Schebeske, R. Jaenicke, J. Hahn, P. Warneck, and C. Junge, Atmos. Environ. 14, 695 (1980).
L. L. Lamparski and T. J. Nestrick Anal Chem. 52, 2045 (1980).
J. Barkley, J. Bunch, J. T. Bursey, N. Castillo, S. D. Cooper, J. M. Davis, M. D. Erickson, B. S. H. Harris III, M. Kilpatrick, L. C. Michael, S. P. Parks, E. D. Pellizzari, M. Roy, D. Smith, K. T. Comer, R. Wagner, and R. H. Zweidinger, Biomed. Mass Spectrom. 7, 139 (1980).
A. Jonsson and S. Berg, J. Chromatogr., 180, 133 (1980).
G. A. Eiceman, R. E. Clement, and F. W. Karasek, Anal Chem. 51, 2343 (1979).
R. L. Hanson, R. E. Royer, R. L. Carpenter, and G.J. Newton, in Polynuclear Aromatic Hydrocarbons(P. W. Jones and P. Leber, eds.), Ann Arbor Science, Ann Arbor, MI, 1979, p. 3.
R. C. Lao and R. S. Thomas, in Polynuclear Aromatic Hydrocarbons(P. W. Jones and P. Leber, eds.), Ann Arbor Science, Ann Arbor, MI, 1979, p. 429.
R. F. Severson, W. S. Schlotzhauer, O. T. Chortyk, R. F. Arrendale, and M. E. Snook, in Polynuclear Aromatic Hydrocarbons(P. W. Jones and P. Leber, eds.), Ann Arbor Science, Ann Arbor, MI, 1979, p. 277.
A. Bjorseth and G. Eklund, Anal Chim. Acta 105, 119 (1979).
A. Bjorseth and G. Lunde, Atmos. Environ. 13, 45 (1979).
T. Fujii, T. Y. Yokouchi, and Y. Ambe J. Chromatogr. 176, 165 (1979).
J. C. Liao and R. F. Browner Anal Chem. 50, 163 (1978).
G. Broddin, L. van Vaeck, and K. van Cauwenberghe, Atmos. Environ. 11, 1061 (1978).
W. Giger and C. Schaffner, Anal Chem. 50, 245 (1978).
A. Bjorseth, in Carcinogenesis, Vol. 3 (P. W.Jones and R. I. Freudenthal, eds.), Raven Press, New York, 1978, p. 75.
M. D. Erickson, L. C. Michael, R. A. Zweidinger, and E. D. Pellizzari, Environ. Sci. Technol. 12, 927 (1978).
M. L. Lee, G. P. Prado, J. B. Howard, and R. A. Hites, Biomed. Mass Spectrom. 4, 182 (1977).
Holzer et al, J. Chromatogr. 142, 755 (1977).
W. Cautreels and K. van Cauwenberghe, Water, Air Soil Poll 6, 103 (1976).
W. Cautreels and K. van Cauwenberghe, Atmos. Environ. 10, 447 (1976).
M. Lee, M. Novotny, and K. D. Bartle, Anal Chem. 48, 405 (1976).
M. L. Lee and R. A. Hites, Anal Chem. 48, 1890 (1976).
R. F. Severson, M. E. Snook, H. C. Higman, O. T. Chortyk, and F. J. Akin, in Carcinogenesis, Vol. 1 (R. I. Freudenthal and P. W. Jones, eds.), Raven Press, New York, 1976, p. 253.
B. Versino, H. Knoeppel, M. DeGroot, A. Peil, J. Poelman, H. Schavenberg, H. Vissers, and F. Geiss, J. Chromatogr. 122, 373 (1976).
R. C. Pierce and M. Katz, Anal Chem. 47, 1743 (1976).
G. Ketseridis, J. Hahn, R. Jaenicke, and C. Junge, Atmos. Environ. 10, 603 (1976).
R. C. Lao, R. S. Thomas, and J. L. Monkman, J. Chromatogr. 112, 681 (1975).
E. P. Grimsrud and R. A. Rasmussen, Atmos. Environ. 9, 1010, 1014 (1975).
K. W. Boyer and H. A. Laitinen, Environ. Sci. Technol 9, 457 (1975).
T. Doran and N. G. McTaggart, J Chromatogr. Sci. 12, 715 (1974).
F. W. Karasek, R.J. Smythe, and R.J. Laub, J. Chromatogr. 101, 125 (1974).
W. Bertsch, R. C. Chang, and A. Zlatkis, J. Chromatogr. Sci. 12, 175 (1974).
A. Raymond and G. Guiochon, Environ. Sci. Technol. 8, 143 (1974).
R. C. Lao, R. S. Thomas, H. Oja, and L. Dubois, Anal. Chem. 45, 908 (1973).
A. Herlan, Erdgas. Petrochem. Brennst.-Chem. 27, 138 (1974).
G. Grimmer and H. Bohnki, Z. Anal Chem. 261, 310 (1972).
S. P. Pavlou and D. Schuetzle, Finnigan Spectra 2, 1 (1972).
K. Grob and G. Grob, J. Chromatogr. 62, 1 (1971).
D. Grosjean, K. van Cauwenberghe, J. P. Schmid, P. E. Kelley, and J. N. Pitts, Jr., Environ. Sci. Technol 12, 313 (1978).
G. Schomburg, R. Dielmann, H. Bowvitzky, and H. Husmann J. Chromatogr., 167, 337 (1978).
K. Grob and K. Grob, Jr., J. High Resoln. Chromatogr./Chromatogr. Commun. 1, 57 (1978).
K. Grob and K. Grob, Jr., J. Chromatogr. 151, 311 (1978).
K. Grob and G. Grob, Chromatographia 4, 422 (1971).
K. Grob and G. Grob, Chromatographia 5, 3 (1972).
K. Grob and H. Jaeggi, Chromatographia 5, 382 (1972).
K. Grob, Chromatographia 7, 94 (1974).
K. Grob and G. Grob, J. High Resoln. Chromatogr. 2, 109 (1970).
R. D. Dandeneau and E. H. Zerenner, J. High Resoln. Chromatogr./Chromatogr. Commun. 2, 351 (1979).
S. R. Lipsky, W. J. McMurray, M. Hernandez, J. E. Purcell, and K. A. Billeb, J. Chromatogr. Sci. 18, 1 (1980).
W. Cautreels and K. van Cauwenberghe, J. Chromatogr., 131, 253 (1977).
S. G. Wakeham, Environ. Sci. Technol 13, 1118 (1979).
W. H. McFadden, J. Chromatogr. Sci. 17, 2 (1979).
R. Ryhage, Anal Chem. 36, 759 (1964).
P. M. Llewellyn and D. P. Littlejohn, Proceedings of the Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, 1966.
R. C. Doughtery, Anal Chem. 53, 625A (1981).
T. M. Harvey, D. Schuetzle, and S. P. Levine, in Monitoring of Toxic Substances, ACS Symposium Series, No. 94, (D. Schuetzle, ed.), American Chem. Society, Washington, D.C., 1979, p. 195.
F. W. Karasek, Res./Dev. 25, 30 (1974).
A. L. Burlingame, R. W. Olsen, and R. McPherron, Adv. Mass Spectrom 6, 1053 (1974).
D. Schuetzle, D. G. Cronn, A. L. Crittenden, and R.J. Charlson, Environ. Sci. Technol. 9, 838 (1975).
D. Schuetzle, T. J. Prater, D. E. Hagge, and R. L. Knights, Proceedings of the 23rd Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1975, p. 208.
T. J. Prater, T. M. Harvey, and D. Schuetzle, Proceedings of the 24th Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1975, p. 625.
J. Meili, F. C. Walls, R. McPherron, and A. L. Burlingame, J. Chromatogr. Sci. 17, 29 (1979).
B. Crathorne, M. W. Edwards, N. R. Jones, C. L. Walters, and G. Woolford, J. Chromatogr. 115, 213 (1975).
D. Schuetzle and D. E. Hagge, Proceedings of the 24th Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1976, p. 115.
B. A. Petersen, C. C. Chuang, G. W. Kinzer, P. W. Meeham, R. M. Riggin, and D. A. Trayser, “Polynuclear Aromatic Hydrocarbon Emissions from Diesel Engines,” Coordinating Research Council Project CAPE-24-72 Progress Report, Atlanta, Georgia, 1980.
F. W. McLafferty and R. Venkataraghavan, J. Chromatogr. Sci. 17, 24 (1979).
D. Rosenthal and W. F. Hargrove, Jr., Proceedings of the 28th Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1979, p. 266.
J. Slayback, J. Jugovich, and M. N. Kan, Proceedings of the 27th Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1979, p. 269.
H. S. Hertz, R. A. Hites, and K. Biemann, Anal. Chem. 43, 681 (1971).
F. W. Karasek, Res./Dev. 27, 42 (1976).
M. L. Lee, D. L. Vassilaros, C. M. White, and M. Navotny, Anal Chem. 51, 768 (1979).
K. R. Betty and F. W. Karasek, J Chromatogr 166, 111 (1978).
G. I. Spivakovskii, A. I. Tishcanko, I. I. Zaslavskii, and N. S. Wilfson, J. Chromatogr. 144, 1 (1977).
M. Randic, J. Chromatogr. 161, 1 (1978).
F. T. Eggertsen, S. Groernings, and J. J. Hoist, Anal. Chem. 32, 904 (1960).
C. L. Stuckey J. Chromatogr. Sci. 16, 482 (1978).
R. A. Hites and K. Biemann, Anal. Chem. 42, 855 (1970).
D. H. Smith, M. Achenbach, W. J. Yeager, P. J. Anderson, W. L. Fitch, and T. C. Rindfleisch, Anal. Chem. 49, 1623 (1977).
S. C. Gates, M. J. Smisko, C. L. Ashendel, N. D. Young, J. F. Holland, and C. C. Sweeley, Anal. Chem. 350, 433 (1978).
J. E. Ryan, R. A. Novak, B. J. Dowty, and R. M. Segesta, Proceedings of the 28th Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1979, p. 343.
J. F. Ryan, R. A. Novak, and W. A. Farr, Proceedings of the 28th Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1979, p. 212.
G. I. Ouchi, Proceedings of the 28th Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1980, p. 129.
A. Cornu and R. Massot, Compilation of Mass Spectral Data, 2nd ed., Heydon, London, 1975.
D. Souter, C. Kieda, R. Devine, and H. Nowicki, ASTM Spec. Tech. Publ. STP 686, Meas. Org. Pollut. Water Wastewater, 221–233 (1978).
K. B. Tomer, J. T. Bursey, and E. D. Pellizzari, Proceedings of the 28th Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1980, p. 165.
W. L. Budde and J. W. Eichelberger, An EPA Manual for Organics Analysis Using Gas Chromatography-Mass Spectrometry, EPA-600/8-79-006, 1979.
A. Shatkay and S. Flavian, Anal. Chem. 49, 2222 (1977).
A. Shatkay, Anal. Chem. 50, 1423 (1978).
B. N. Colby and M. W. McCaman, Biomed. Mass Spectrom. 6, 225 (1979).
D. A. Schoeller, Biomed. Mass. Spectrom. 7, 457 (1980).
F. C. Falkner, Biomed. Mass Spectrom. 8, 43 (1981).
M. Claeps, S. P. Markey, and W. Maenkaut, Biomed. Mass Spectrom. 4, 122 (1977).
M. N. Kan, J. Jogovich, and J. Slayback, Proceedings of the 27th Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1979, p. 269.
M. Weiss and S. Sokolow, Proceedings of the 28th Annual Conference on Mass Spectrometry, American Society of Mass Spectrometry, 1980, p. 183.
J. E. Biller and K. Biemann, Anal. Lett. 7, 515 (1974).
M. L. Lee, M. V. Novotny, and K. D. Battle, Mass Spectrometry in Analytical Chemistry of Polycyclic Aromatic Compounds, Academic Press, New York, 1981, pp. 242–289.
D. Schuetzle and T. E. Jensen, in Nitrated Polycyclic Aromatic Hydrocarbons( C. M. White, ed.), Huthig Verlag, Heidelberg, 1984.
T. Ramdahl, Environ. Set. Technol. 17, 666(1983).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1985 Plenum Press, New York
About this chapter
Cite this chapter
Schuetzle, D., Hampton, C.V. (1985). Gas Chromatography/Mass Spectrometry in Air Pollution Studies. In: Karasek, F.W., Hutzinger, O., Safe, S. (eds) Mass Spectrometry in Environmental Sciences. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2361-7_9
Download citation
DOI: https://doi.org/10.1007/978-1-4613-2361-7_9
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-9445-0
Online ISBN: 978-1-4613-2361-7
eBook Packages: Springer Book Archive