Synthesis of Titanium, Zirconium and Hafnium Modified Polysaccharides

  • Yoshinobu Naoshima
  • Charles E. CarraherJr.
  • Koichi Matsumoto

Abstract

Dextran has been modified employing the classical interfacial polycondensation technique through reaction with Group IV B bicyclopentadienylmetallocene dichlorides. Product yields, both percentage and weight, follow the general trend Hf>Zr>Ti consistent with the Hard-Soft Acid Base theory. Dextran is employed as a representative polysaccharide.

Keywords

Cellulose Titanium Sucrose Zirconium Saccharide 

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Copyright information

© Plenum Press, New York 1986

Authors and Affiliations

  • Yoshinobu Naoshima
    • 1
  • Charles E. CarraherJr.
    • 2
    • 3
  • Koichi Matsumoto
    • 1
  1. 1.Department of ChemistryOkayama University of ScienceOkayamaJapan
  2. 2.Department of ChemistryWright State UniversityDaytonUSA
  3. 3.Department of ChemistryFlorida Atlantic UniversityBoca RatonUSA

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