Abstract
In order to combine the desirable properties of synthetic polymers (elasticity and water, chemical, and biological resistance) with those of animal hide (strength, flexibility, and dyability), composites can be formed between the two types of material. Actually, adding materials to hide has long been an aspect of traditional leathermaking, usuaslly to increase thermal stability and to make the hide more hydrophobic. Newer uses for hide material require it to be stable but compatible with aqueous environments. Appropriate compositions can be formed from leather and hydrophilic polymers. Composites of collagen with poly(hydroxyethyl methacrylate) (polyHEMA or pHEMA) (1), with starch (2), or with Polyacrylamide (3) have been described for surgical implants with blood compatibility and lack of tissue inflammatory reactions. Other uses for these compositions may be found as substrata for cells and enzymes in biotechnology.
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References
M. Chvapil, R. Holusa, K. Kliment, and M. Stoll, Some chemical and biological characteristics of a new collagen-polymer compound material, J. Biomed. Mater. Res. 3: 315 (1969).
P. N. Sawyer, B. Staczewski, and D. Kirschenbaum. The development of polymeric cardiovascular collagen prostheses, Artif. Organs 1: 83 (1977).
K. P. Rao, K. T. Joseph, and Y. Nayudamma, Characterization of the collagen-vinyl copolymers prepared by the eerie ion method. I. Solution properties, J. Polym. Sci., Part A1, 9: 3199 (1971).
E. F. Jordan, Jr., B. Artymyshyn, and S. H. Feairheller, Polymer-leather composites. IV. Mechanical properties of selected acrylic polymer-leather composites, J. Appl. Polym. Sci., 26: 463 (1981).
R. E. Baier and W. A. Zisman, Wetting properties of collagen and gelatin surfaces, in Applied Chemistry and Protein Interfaces, R. E. Baier, Ed., Advances in Chemistry Series 145, 155–174 (1975).
M. M. Taylor, E. J. Diefendorf, M. V. Hannigan, B. Artymyshyn, J. G. Phillips, S. H. Feairheller, and D. G. Bailey, Wet process technology. III. Development of a standard process, J. Amer. Leather Chem. Assn. (In Press).
W. V. Gerasimowicz, K. B. Hicks, and P. E. Pfeffer, Macromolecules (In press).
P. E. Pfeffer, D. G. Bailey, and E. F. Jordan, Evidence for limited phase homogeneity in PMMA “grafted” chrome-tanned leather by 13C CP-MAS, NMR, 25th Experimental NMR Conference, Wilmington, DE 8–12 April, 1984:
M. J. Sullivan, and G. E. Maciel, Anal. Chem. 54: 1601 (1982).
A. Pines, M. G. Gibby, and J. S. Waugh, J. Chem. Phys., 59: 569 - 590 (1973).
S. J. Opella and M. H. Frey, J. Am. Chem. Soc. 101: 5854 (1979).
M. Takayanagi, Viscoelastic properties of crystalline polymers, Mem. Fac. Eng, Kyushu Univ. 23: 41 (1963).
O. Wichterle and D. Lim, Hydrophilic gels for biological use, Nature, 185: 117 (1960).
O. Wichterle, Hydrogels, in “Encylopedia of Polymer Science and Technology,” N. M. Bikales, ed., Wiley, New York (1971).
P.L. Kronick, P. Buechler, Frank Scholnick, and Bohdan Artymyshyn, Dynamic mechanical properties of polymer-leather composites, J. Appl. Polym Sci. 30: 3095 (1985).
J. A. Lowell and P. B. Buechler, Studies on impregnation. Determination of the depth of polymer penetration, J. Am. Leather Chem. Assoc. 60: 519 (1965).
M. Takayanagi, S. Uemura, and S. Minimi, Application of the equivalent-model method to dynamic rheo-optical properties of crystalline polymer, J. Polym. Sci. Part C5, 113 (1964).
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© 1986 Plenum Press, New York
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Kronick, P.L., Artymyshyn, B., Buechler, P.R., Wise, W. (1986). Viscoelasticity of Calf Hide Impregnated with Radiation-Polymerized Polyhydroxyethyl Methacrylate. In: Carraher, C.E., Sperling, L.H. (eds) Renewable-Resource Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2205-4_19
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DOI: https://doi.org/10.1007/978-1-4613-2205-4_19
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