Abstract
Conversion of solar energy into storable chemical energy sustains life on earth and constitutes a scientific problem of fundamental interest which might also have long-term technical importance. The most attractive reaction is the photoinduced evolution of H2 and 02 from water according to the mechanism (n = number of photons)
In part presented as a lecture at the Conference “Fundamental Research Strategy on the Innovative Low-Energy Synthesis through Catalytic and Photo-Assisted Processes,” Tokyo, July 1983.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
A. Fujishima and K. Honda, Nature 238 (1972) 37.
M. S. Wrigthon, A. B. Ellis, P. T. Wolczanski, D. L. Morse, H. B. Abrahamson, and D. S. Ginley, J. Am. Chem. Soc. 98 (1976) 2774.
J. G. Mavroides, J. A. Kafalas, and D. F. Kolesar, Appl. Phys. Lett. 28 (1971) 241.
C. Leygraf, M. HendeWerk, and F. A. Somorjai, J. Catal. 78 (1982) 341.
H. S. Jarrett, A. W. Sleight, H. H. Rung, and H. L. Gilson, J. Appl Phys. 51 (1981) 3916.
A. Heller and R. G. Vadimsky, Phys. Rev. Lett. 46 (1981) 1153.
M. Noda, Int. J. Hydrogen Energy 7 (1982) 311.
H. P. Maruska and A. K. Ghosh, Solar Energy 20 (1978) 443.
H. Gerischer, Solar Photoelectrolysis with Semiconductor Electrodes, in Solar Energy Conversion, Ed. B. O. Seraphin, Topics of Applied Physics, Springer, New York, 1979, p. 115.
J. Mamassen, D. Cahen, G. Hodes, and A. Sofer, Nature 263 (1976) 97.
A. J. Nozik, Nature 257 (1975) 383; Appl Phys. Lett. 29 (1976) 150.
H. Gerischer, J. Vac. Sei Technol. 8 (1978) 1422.
H. Tributsch, J. Electrochem. Soc. 128 (1981) 1261.
P. Riietschi and P. Delahay, J. Chem. Phys. 23 (1955) 556.
M. A. Butler and D. S. Ginley, J. Mater. Sci. 15 (1980) 1; and references therein.
H. P. Maruska and A. K. Ghosh, J. Electrochem. Soc. 124 (1977) 1516.
G. Campet, M. P. Dare-Edwards, A. Hamnet, and J. B. Goodenough, Nouv. J. Chem. 4 (1980) 501.
G. Campet, J. Verniolle, J. P. Doumerc, and J. Claverie, Mat. Res. Bull. 15 (1980) 1135.
A. Mackor and G. Blasse, Chem. Phys. Lett. 77 (1981) 6.
P. Salvador, C. Gutimerrez, and J. B. Goodenough, J. Appl. Phys. 53 (1982) 7003.
Y. Nakato, T. Obnishi, and H. Tsubomura, Chem. Lett. 19 (1975) 838.
L. A. Harris, M. E. Gerstner, and R. H. Wilson, J. Electrochem. Soc. 124 (1977) 1511.
R.-R. F. Fan, G. A. Hope, and A. J. Bard, J. Electrochem. Soc. 129 (1982) 1647.
F.-R. F. Fan, R. G. Keil, and A. J. Bard, J. Electrochem. Soc. 105 (1983) 220.
H. Tributsch, Z. Naturforsch. 32a (1977) 972; Structure Bonding 49 (1982) 127.
H. Tributsch and J. C. Bennett, J. Electroanal. Chem. 81 (1977) 97.
H. Tributsch and U. Gorochov, J. Electrochim. Acta 27 (1982) 215.
H. Ezzaouia, R. Heindl, R. Parsons, and H. Tributsch, J. Electroanal. Chem. 145 (1983) 279.
H. Ezzaouia, R. Heindl, R. Parsons, and H. Tributsch, J. Electroanal. Chem. 165 (1984) 155.
H.-M. Kühne and H. Tributsch, J. Electrochem. Soc. 130 (1983) 1448.
H.-M. Kühne and H. Tributsch, Ber. Bunsenges. Phys. Chem. 88 (1984) 10.
H.-M. Kühne and H. Tributsch, J. Electroanal. Chem., in press.
W. Jaegermann and H. Tributsch, J. Appl. Electrochem. 13 (1983) 743.
A. Ennaoui, S. Fiechter, W. Jaegermann, and H. Tributsch, J. Electrochem. Soc., 133 (1986) 97; A. Ennaoui and H. Tributsch, Solar Cells 13 (1984) 179.
M. Calvin, Science 184 (1974) 375; Kemia-Kemi 2 (1975) 46; Faraday Discussion 70 (Photoelectrochemistry) (1980).
F. Hulliger, Structure Bonding, 4 (1968) 83.
H.-M. Kühne, Ph.D. thesis, Free University of Berlin, 1985.
W. Jaegermann, J. Phys. Chem., 88 (1984) 5309.
Measurements by Horkaus and Schafter reproduced in J. W. Schultze, Chem. Ing. Tech. 52 (1980) 447.
Measurement by Schultze and Haga reproduced in J. W. Schultze, Chem. Ing. Tech. 52 (1980) 447.
W. Jaegermann, unpublished measurements.
W. Jaegermann, T. Sakata, E. Janata, and H. Tributsch, J. Electroanal Chem. 189 (1985) 65.
J. Koutecky and G. Pacchioni, Ber. Bunsenges. Phys. Chem. 88 (1984) 233; G. Pacchioni, D. Plavsic, and J. Koutecky, ibid. 87 (1983) 503.
H. Vahrenkamp, in Sulfur, its Significance for Chemistry, for the Geo-, Bio- and Cosmosphere and Technology, Eds. A. Müller and B. Krebs, Studies in Inorganic Chemistry, Vol. 5, Elsevier, Amsterdam, 1984.
F. Richter and H. Vahrenkamp, Chem. Ber. 115 (1982) 3224.
L. Marko, B. Markö-Monostory, T. Madach, and H. Vahrenkamp, Angew. Chem. 92 (1980) 225.
R. R. Dogonadze, J. Ulstrup, and Yu. I. Kharkats, J. Electroanal. Chem. 39 (1972) 47.
T. A. Pecoraro and R. R. Chianelli, J. Catal 67 (1981) 430.
S. Harris and R. R. Chianelli, Chem. Phys. Lett. 101 (1983) 603; J. Catal 86 (1984) 400.
H.-M. Kühne, W. Jaegermann, and H. Tributsch, Chem. Phys. Lett. 112 (1984) 89.
J. O’M. Bockris and T. Otagawa, J. Phys. Chem. 87 (1983) 2960.
J. O’M. Bockris and T. Otagawa, J. Electrochem. Soc. 131 (1984) 290.
J. P. Hoare, The Electrochemistry of Oxygen, Interscience, New York, 1968.
J. P. Hoare, Encyclopedia of Electrochemistry of the Elements, Vol. 2, Ed. A. J. Bard, Marcel Dekker, New York, 1974, p. 191.
A. Damjanovic, Modern Aspects of Electrochemistry, Vol. 5, Eds. J. O’M. Bockris and B. E. Conway, Plenum, New York, 1969, p. 369.
A. J. Appleby, Modern Aspects of Electrochemistry, Vol. 9, Eds. J. O’M. Bockris and B. E. Conway, Plenum, New York, 1973, p. 369.
J. Horiuti, Physical Chemistry. An Advanced Treatise, Vol. 9B, Ed. H. Eyring, Academic, New York, 1970, p. 532.
S. Trasatti and G. Lodi, Electrodes of Conductive Metallic Oxides, Part A, Ed., S. Trasatti, Elsevier, New York, 1980, p. 301; Part B, 1981, p. 521.
M. H. Miles, E. A. Klaus, B. P. Gunn, J. R. Locker, W. E. Serafín, and S. Srinivasan, Electrochim. Acta 23 (1978) 521.
K. Doblhofer, M. Metikes, Z. Ogumi, and H. Gerischer, Ber. Bunsenges. Phys. Chem. 82, (1978) 1046.
A. Damjanovic and B. Javanovic, J. Electrochem. Soc. 123 (1976) 374.
R. F. Scarr, J. Electrochem. Soc. 116 (1969) 1526.
L. D. Burke, O. J. Murphy, J. F. O’Neill, and S. Venkatesan, J. Chem. Soc. Faraday Trans. 1, 73 (1977) 1659.
A. G. C. Kobussen and G. H. J. Broers, J. Electroanal. Chem. 126 (1981) 221.
P. Salvador, J. Electrochem. Soc. 129 (1981) 1895.
P. Clechet, C. Martelet, J. R. Martin, and R. Olier, Electrochim. Acta 24 (1979) 457.
F. A. Cotton and F. R. Walton, Multiple Bonds Between Metal Atoms, Wiley, New York, 1982; F. A. Cotton and T. E. Haas, Inorg. Chem. 3 (1964) 10.
H. Schäfer and H. G. v. Schnering, Angew. Chem. 76 (1964) 833.
Ø. Fischer and M. B. Maple, Topics of Current Physics, Vol. 32, Chap. I, Eds., Ø. Fischer, M. B. Maple, Springer, Berlin, 1982.
H.-Y. Chen, R. T. Tuenge, and H. F. Franzen, Inorg. Chem. 12 (1973) 552.
A. Simon, Naturwissenschaften 71 (1984) 171; H. Imoto and A. Simon, Inorg. Chem. 21 (1982) 308.
H. Tributsch and H. Gerischer, J. Appl. Chem. Biotechnol. 26 (1976) 747.
H. Tributsch and W. Hönle, J. Electroanal. Chem., in press.
W. Hönle, MPI für Festkörperforschung, personal communication.
N. A. Goryunova, V. M. Orlov, V. I. Sokolova, G. P. Shpenkov, and E. V. Tsvetkova, Phys. Stat. Sol. (a) 3 (1970) 75.
W. Hönle and H. G. v. Schnering, Z. Kristallogr. 153 (1980) 339.
N. W. Alcock and A. Kjekshus, Acta Chem. Scand. 19 (1965) 79.
Crystals prepared by Dr. W. Jaegermann.
R. Chevrel, Superconductor Materials Science, Metallurgy, Fabrication and Applications, Eds., S. Fouer and B. B. Schwartz, Plenum Press, New York, 1981.
A. Perrin, M. Sergent, and Ø. Fischer, Mater. Res. Bull. 13 (1978) 259.
A. Perrin, R. Chevrel, M. Sergent, and Ø. Fischer, J. Solid State Chem. 33 (1980) 43.
W. Hönle and K. Yvon, Z. Kristallogr. 23 (1983) Diskussionstagung 103.
P. Engel and W. Nowacki, Neues Jahrb. Mineral Monatsh. 6 (1966) 181.
Crystals donated by Dr. W. Hönle, MPI Stuttgart. Photoelectrolysis and Photoelectrochemical Catalysis
Unpublished observations.
J. O’M. Bockris and S. U. M. Khan, Appl. Phys. Lett. 45 (8) (1984) 913.
K. R. Mann, N. S. Lewis, V. M. Miskowski, D. K. Erwin, G. S. Hammond, and H. B. Gray, J. Am. Chem. Soc. 98 (1977) 16, 5525.
M. Kunst and H. Tributsch, Chem. Phys. Lett. 105/2 (1984) 123.
M. Kunst, G. Beck, and H. Tributsch, J. Electrochem. Soc. 131 (1984) 954.
L. Vaska, Acc. Chem. Res. 9 (1976) 175.
A. J. Wilson and A. D. Yoffe, Adv. Phys. 18 (1969) 193.
A. Ennaoui and H. Tributsch, J. Electroanal. Chem., in press.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1986 Plenum Press, New York
About this chapter
Cite this chapter
Tributsch, H. (1986). Photoelectrolysis and Photoelectrochemical Catalysis. In: Bockris, J.O., Conway, B.E., White, R.E. (eds) Modern Aspects of Electrochemistry. Modern Aspects of Electrochemistry, vol 17. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2133-0_4
Download citation
DOI: https://doi.org/10.1007/978-1-4613-2133-0_4
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-9260-9
Online ISBN: 978-1-4613-2133-0
eBook Packages: Springer Book Archive