Abstract
Commercial production of Ryton®, the engineering plastic poly(phenylene sulfide) or (PPS), began in 1973 by Phillips Petroleum Company. Phillips used the process disclosed in 1967 by Edmonds and Hill,1 i.e., the reaction of 1,4-dichlorobenzene with sodium sulfide in a polar organic solvent to produce PPS. This was the first practical preparation of PPS of sufficiently high molecular weight to be useable. The patent literature is now voluminous. An excellent comprehensive review article on the properties, fabrication, and uses of PPS was published by Hill and Brady.2 This paper is a brief overview of the preparation and properties of PPS and is not intended to be a comprehensive review.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J.T.Edmonds, Jr. and H.W. Hill, Jr., U.S. Pat. 3,354,129 (to Phillips Petroleum Co.) Nov. 21, 1967.
H.W. Hill, Jr. and D.G. Brady, “Poly(Phenylene Sulfide)” in “Kirk-Othmer Encyclopedia of Chemical Technology” Wiley-Interscience, New York, 1982, pps. 793–814.
R.W. Lenz, C.E. Handlovits, and H.A. Smiths, J. Polymer Sei., 58, 351–67 (1962).
R.W. Lenz, C.E. Handlovits, and W.K. Carrington, U.S. Pat. 3,274,165 (to Dow Chemical Co.) Sept. 20, 1966.
A.D. MacaHum, J. Org. Chem., 13, 154–9 (1948).
A.D. Macallum, U.S. Pat. 2,538,941, Jan. 23, 1951.
R.W. Lenz and C.E. Handlovits, J. Polymer Sci., 43, 167–81 (1960).
M. Schmidt, Macromolecular Reviews, 1, (2), 110–3 (1970); Chem. Abstr., 68, 69536a (1968).
M. Schmidt, Brit. Pat. 1,100,273 (to Sulfur Inst.) Jan. 24, 1968; Chem Abstr., 68, 60201e (1968).
M. Schmidt, U.S. Pat. 3,578,718 (to Research Corp.) May 11, 1971; Chem. Abstr., 71., 49563r (1969).
R.W. Lenz and W.K. Carrington, J. Polymer Sci., 41, 333–58 (1959).
J.W. Cleary, Polymer Preprints, 25 (2), 36–40 (1984).
V.A. Sergeev, V.L. Nedel’kin, and R.G. Gasanov, Vosokomol. Soedin., Ser B 25, (10), 789–92 (1983); Chem. Abstr., 100, 52112r (1984).
V.A. Sergeev, V.L. Nedel’kin, V.F. Sizoi, Yu. S. Nekrasov, and V.A. Tsyrapkin, Dokl. Akad. Nauk SSSR, 1984, 227 (4), 913–6 [Phys. Chem.]; Chem. Abstr., 101, 231,233 (1984).
H.B. Glass and E.E. Reid, J. Am. Chem. Soc., 51., 3428–30 (1929).
M. Wejchan-Judek and E. Rogal, Polymer Comm., 25 (2), 53–4 (1984).
M. Wejchan-Judek, E. Rogal, and A. Zuk, Polymer, 22 (6), 845–7 (1981).
H.A. Smith, U.S. Pat. 4,178,433 (to Dow Chemical Co.) Dec. 11, 1979.
T. Fujisawa and M. Kakutani, J. Polymer Sci., Part B., 8, (1), 19–24 (1970).
Asahi Glass K. K., Jap. Kokai T. K. 58–185, 626, Oct. 29, 1983; Chem. Abstr., 100 19256t (1984).
Asahi Glass K. K., Jap. Kokai T. K. 58–185,626, Oct. 29, 1983; Chem. Abstr., 100, 192566s (1984).
Asahi Glass K. K., Jap. Kokai T. K. 59–081, 334, May 11, 1984; Chem. Abstr., 100, 152549c (1984).
Asahi Glass K. K., Jap. Kokai T. K. 59–081, 335, May 11, 1984; Chem. Abstr., 100, 152550w (1984).
R.G. Gaughan, unpublished results.
“Ryton”; Polyphenylene Sulfide Compounds Engineering Properties”, Bulletin TSM-266, Phillips Chemical Co., Bartlesville, OK, 1983.
G. Kraus and W.M. Whitte, Proceedings of the 28th Macromolecular Symposium of the IUPAC, Amherst, MA., July 12, 1982, p. 558.
C.J. Stacy, Polymer Preprints, 26 (1), 180 (1985).
J.E. Trommer, R.L. Elsenbaumer, and R.R. Chance, “A Novel Phase of Organic Conductors: Conducting Polymer Solutions” in “Polymers in Electronics”, T. Davidson, ed., American Chemical Society, Washington, D.C., 1984, pps. 447–59: cf also “Conductive Polymers,” pps. 423–584.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1985 Plenum Press, New York
About this chapter
Cite this chapter
Cleary, J.W. (1985). Poly(Phenylene Sulfide). In: Culbertson, B.M., McGrath, J.E. (eds) Advances in Polymer Synthesis. Polymer Science and Technology, vol 31. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2121-7_8
Download citation
DOI: https://doi.org/10.1007/978-1-4613-2121-7_8
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-9254-8
Online ISBN: 978-1-4613-2121-7
eBook Packages: Springer Book Archive