Skip to main content

Some Novel Diene Polymers Prepared with Lanthanide Catalysts

  • Chapter
Advances in Polymer Synthesis

Part of the book series: Polymer Science and Technology ((POLS,volume 31))

  • 255 Accesses

Abstract

In recent years a great number of reports on the stereospecific polymerization of 1,3-dienes with lanthanide catalysts have been published.1–6 The lanthanide coordination catalysts are known to be highly stereospecific for producing high-cis polybutadiene and high-cis polyisoprene as well as high-cis copolymerization of the two monomers.1 In addition, the polymerizations of other conjugated dienes such as trans-piperlene, 2,4-hexadiene, and 2,3-dimethyl-1,3-butadiene to stereoregular polymers by lanthanide catalysts have also been reported.7–9

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Z. Shen, J. Ouyang, F. Wang, Z. Hu, and B. Qian, J. Polym. Sci.,Polym. Chem. Ed., 18, 3345 (1980).

    Article  Google Scholar 

  2. J. H. Yang, M. Tsutsui, Z. Chen, and D. E. Bergbreiter, Macromolecules, 15, 230 (1982).

    Article  ADS  Google Scholar 

  3. J. Ouyang, F. Wang, and Z. Shen, in “Proceedings of China-U.S. Bilateral Symposium on Polymer Chemistry and Physics,” p. 382, Science Press (1981).

    Google Scholar 

  4. J. Witte, Angew. Makromol. Chem., 94, 119 (1981).

    Article  Google Scholar 

  5. A. Mazzei, Makromol. Chem. Suppl., 4, 61 (1981).

    Article  Google Scholar 

  6. S.R. Rafikov, Y.B. Monakov, Y. Bieshev, J. Valitova, Y. Murinov, G. Tolstikov, and Y. Nikitin, Dokl. Akad. Nauk SSSR, 229, 1174 (1976).

    Google Scholar 

  7. D. M. Xie, C. Zhong, N. Yuan, Y. Sun, S. Xias, and J. Ouyen, Gaofenzi Tongxun, August (4), 233 (1979).

    Google Scholar 

  8. F. Wong, A. Bolognesi, A. Immirzi, and L. Porri, Makromol. Chem., 182, 3617 (1981).

    Article  Google Scholar 

  9. F. Wong, and A. Bolognesi, Gaofenzi Tongxun, June (3), 238 (1982).

    Google Scholar 

  10. H. L. Hsieh and H. C. Yeh, Rubber Chem. Technol., (1984) in press.

    Google Scholar 

  11. G. Natta, L. Porri, G. Stoppa, G. Allegra, and F. Ciampelli, J. Polymer Sci., Polymer Letters, B1, 67 (1963).

    Article  ADS  Google Scholar 

  12. M. Kamachi, N. Wakabayashi, and S. Murahashi, Macromolecules, 7, 744 (1974).

    Article  ADS  Google Scholar 

  13. T. F. Yen, J. Polymer Sci., 35, 533 (1959).

    Article  ADS  Google Scholar 

  14. L. Porri, in “Structural Order in Polymers”, F. Ciardelli, and P. Giusti, Eds., p. 51, Pergamon Press, Oxford (1981).

    Google Scholar 

  15. Ph. Teyssie, in “The Stereo Rubbers”, W. M. Saltman, Ed., p. 79, John Wiley and Sons, NY(1977).

    Google Scholar 

  16. W. Cooper, Ind. Eng. Chem. Prod. Res. Develop., 9 (4), 457 (1970).

    Article  Google Scholar 

  17. P. Cossee, in “Stereochemistry of Macromolecules”, A. D. Ketley, Ed., Vol. 1, p. 145, M. Dekker, NY (1967).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1985 Plenum Press, New York

About this chapter

Cite this chapter

Yeh, H.C., Hsieh, H.L. (1985). Some Novel Diene Polymers Prepared with Lanthanide Catalysts. In: Culbertson, B.M., McGrath, J.E. (eds) Advances in Polymer Synthesis. Polymer Science and Technology, vol 31. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2121-7_24

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-2121-7_24

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9254-8

  • Online ISBN: 978-1-4613-2121-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics