Functional, Telechelic Polymers Derived from Reactions of Nucleophilic Oligomers and Alkeynl Azlactones, Part I: Telechelic Acrylamides Derived from Reactions of Alkeynl Azlactones and Amine-Terminated Oligomers

  • Steven M. Heilmann
  • Jerald K. Rasmussen
  • Larry R. Krepski
  • Howell K. SmithII
Part of the Polymer Science and Technology book series (POLS, volume 31)


Because of their cost effectiveness and non-polluting nature, so-called 100% solids resin systems that can be converted to finished product on exposure to either electron beam or ultraviolet radiation are an important and permanent part of our present day technology. Applications for these curable systems are wide and extremely varied, from use as protective coatings on wood, metal, glass, and plastics to adhesives and restoratives used in the repair of teeth2.


Equivalent Weight Mercuric Acetate Ethyl Chloroformate TELECHELIC Polymer ORTEP Plot 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Chemistry of Alkenyl Azlactones. For part IV in the series, see S.M. Heilmann, J.K. Rasmussen, L.R. Krepski, and H.K. Smith II, J. Polymer Sci.: Polymer Chem.Ed., 22(11), 3149 (1984).ADSCrossRefGoogle Scholar
  2. 2.
    G.E. Green, B.P. Stark, and S.A. Zahin, J. Macro. Sei.-Revs. Macro. Chem., C21, 187 (1981–82).Google Scholar
  3. 3.
    C.B. Rybny, C.A. DeFazio, J.K. Shahidi, J.C. Trebellas, and J.A. Vona, J. Paint Tech., 46, 60 (1974).Google Scholar
  4. 4.
    L.D. Taylor and T.E. Platt, J. Polymer Sei.: Polymer Lett., 7, 597 (1969).ADSCrossRefGoogle Scholar
  5. 5.
    H.C. Haas, U.S. Patent 3,396,030 (1968); Chem. Abstr., 69, 101768n (1968).Google Scholar
  6. 6.
    Y. Iwakura, F. Toda, H. Suzuki, J. Org. Chem. 32, 440 (1967).CrossRefGoogle Scholar
  7. 7.
    J.K. Rasmussen, S.M. Heilmann, L.R. Krepski, F.J. Palensky, and H.K. Smith II, Makromol. Chem., Rapid Commun., 5, 169 (1984).CrossRefGoogle Scholar
  8. 8.
    R. Korus and K.F. O’Driscoll, “Polymer Handbook”, 2nd edition by J. Brandrup and E.H. Immergut, Wiley-Interscience: New York (1975), pp. II–45ff.Google Scholar
  9. 9.
    L.D. Taylor, H.S. Kolesinki, A.C. Mehta, L. Locatell, and P.S. Larson, Makromol. Chem., Rapid Commun., 3, 779 (1982).CrossRefGoogle Scholar
  10. 10.
    S.M. Heilmann and H.K. Smith II, J. Appl. Polymer Sci., 24, 1551 (1979).Google Scholar
  11. 11.
    K. Hubner, F. Kollinsky, G. Market, and H. Pennewiss, Angew. Makromol. Chem., 11, 109 (1970).Google Scholar
  12. 12.
    J.S. Fritz, “Acid-Base Titrations in Nonaqueous Solvents”, Published by the G. Frederick Smith Chemical Company, Columbus (OH), 1952, p. 13.Google Scholar
  13. 13.
    “Jeffamine Polyoxypropyleneamines”, Technical Brochure, Jefferson Chemical Company (now Texaco Chemical Company (a Division of Texaco, Inc.)), 1978.Google Scholar
  14. 14.
    E.L. Yeakey, U.S. Patent 3,654,370, Apri 4, 1972; Chem. Abstr., 71, 50809g (1969).Google Scholar
  15. 14.
    H.G. Waddill and H. Schulz, U.S. Patent 4,178,427, December 11, 1979; Chem. Abstr., 92, 95128j (1980).Google Scholar
  16. 16.
    “The Dimer Acids”, E.C. Leonard, Ed., Humko Sheffield Chemical, Conn., 1975.Google Scholar
  17. 17.
    “1981 Annual Book of ASTM Standards”, Part 30, Published by the American Society for Testing and Materials, Philadelphia (PA), E 441–74, pp. 1027–1030.Google Scholar
  18. 18.
    E. Shchori, J. Polymer Sci.: Polymer Lett. Ed., 21, 413 (1983).ADSCrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1985

Authors and Affiliations

  • Steven M. Heilmann
    • 1
  • Jerald K. Rasmussen
    • 1
  • Larry R. Krepski
    • 1
  • Howell K. SmithII
    • 1
  1. 1.Central Research Laboratories3M Company 3M CenterUSA

Personalised recommendations