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Oxidations using Palladium Compounds

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Organic Syntheses by Oxidation with Metal Compounds

Abstract

The advent of the Wacker process in the 1950s for the preparation of acetaldehyde from ethylene on an industrial scale using palladium chloride focused attention on the potential of compounds of this metal as oxidants for organic reactions.* The field has expanded greatly since then and Pd(II) is now used for the formation of ketones, esters, ethers, acetals from olefins as well as in olefin coupling reactions. Pd(II) is also active in promoting the coupling of arenes, benzylic oxidation, the oxidation of alcohols, and of oxidative carbonylation. In each case there are many variations which have been explored in order to make the reactions more specific. In addition a wide variety of co-oxidants have been explored; these are used in order to make the reactions catalytic in palladium.

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  1. Department of Chemistry, The University of Sheffield, S3 7HF, Sheffield, England

    Suzanne F. Davison & Peter M. Maitlis

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  1. Suzanne F. Davison
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  1. Corporate Research Department, Akzo Research, Arnhem, The Netherlands

    W. J. Mijs  & C. R. H. I. de Jonge  & 

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Davison, S.F., Maitlis, P.M. (1986). Oxidations using Palladium Compounds. In: Mijs, W.J., de Jonge, C.R.H.I. (eds) Organic Syntheses by Oxidation with Metal Compounds. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2109-5_9

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  • DOI: https://doi.org/10.1007/978-1-4613-2109-5_9

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