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Evidence from T ll and Related Phenomena for Local Structure in the Amorphous State of Polymers

  • Chapter
Order in the Amorphous “State” of Polymers

Abstract

We have recently completed what we conceived as a definitive review of T ll and related liquid state transitions (relaxations) in the T>T g region of atactic polymers and the T>T m region of crystalline polymers.1 A table of contents appears on page 233 of that article. In general the subject matter covered definition of terms, history, theories for T ll , experimental techniques, practical significance, and a guide to the literature.

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References

  1. R.F. Boyer, in “Polymer Yearbook,” Vol. 2 ,R.A. Pethrick, Ed., Harwood Academic Publishers, New York, 1985, pp. 233–343.

    Google Scholar 

  2. J.K. Gillham and R.F. Boyer, J. Macromol. Sci. ,Phys. ,B13, 497–535 (1977).

    CAS  Google Scholar 

  3. R.F. Boyer, J. Macromol. Sci. ,Phys. ,B18, 461–553 (1980).

    Google Scholar 

  4. R.F. Boyer and J.B. Enns, J. Appl. Polym. Sci. ,31, 0000–0000 (1986).

    CAS  Google Scholar 

  5. K. Ueberreiter and J. Naghizadeh, Kolloid Z.Z. Polym. ,250, 927–931 (1972).

    Article  CAS  Google Scholar 

  6. L.R. Denny, K.M. Panichella, and R.F. Boyer, J. Polym. Sci. ,Polym. Symp. ,71, 39–58 (1984).

    Article  CAS  Google Scholar 

  7. R.F. Boyer, Eur. Polym. J. ,17, 661–673 (1981).

    Article  CAS  Google Scholar 

  8. R.F. Boyer, J.B. Enns, and J.K. Gillham, Polym. Prepr., Am. Chem. Soc., Div. Polym. Chem. ,18(1), 629–634 (1977).

    Google Scholar 

  9. R.F. Boyer, J.B. Enns, and J.K. Gillham, Polym. Prepr., Am. Chem. Soc., Div. Polym. Chem. ,18(2), 475–480 (1977).

    Google Scholar 

  10. C. Lacabanne, P. Goyaud, and R.F. Boyer, J. Polym. Sci. ,Polym. Phys. Ed. ,18, 277–284 (1980).

    CAS  Google Scholar 

  11. S.J. Stadnicki, J.K. Gillham, and R.F. Boyer, J. Appl. Polym. Sci. ,20, 1245–1275 (1976).

    Article  CAS  Google Scholar 

  12. L.R. Denny, K.M. Panichella, and R.F. Boyer, J. Polym. Sci. ,Polym. Lett. Ed. ,23, 267–271 (1985).

    Article  Google Scholar 

  13. M.L. Wagers and R.F. Boyer, Rheol. Acta ,24, 232–242 (1985).

    Article  CAS  Google Scholar 

  14. R.F. Boyer, manuscript submitted to J. Appl. Polym. Sci. ,Reinterpretation of DSC data in ref. 11.

    Google Scholar 

  15. R.F. Boyer, Rubber Chem. Technoi ,36, 1303–1421 (1963). See especially Fig. 17, p. 1338.

    Article  CAS  Google Scholar 

  16. R.F. Boyer, J.P. Heeschen, and J.K. Gillham, J. Polym. Sci. ,Polym. Phys. Ed. ,19, 13–21 (1981).

    CAS  Google Scholar 

  17. D.E. Axelson and L. Mandelkern, J. Polym. Sci. ,Polym. Phys. Ed. ,16, 1135–1138 (1978).

    CAS  Google Scholar 

  18. A. Dekmezian, D.E. Axelson, J.J. Dechter, B. Borah, and L. Mandelkern, J. Polym. Sci.Polym. Phys. Ed. ,23, 367–385 (1985).

    Article  CAS  Google Scholar 

  19. R.E. Robertson, Ann. Rev. Mater. Sci. ,5, 73–97 (1975).

    Article  CAS  Google Scholar 

  20. A.M. Lobanov and S.Ya. Frenkel, Polym. Sci. ,USSR ,22, 1150–1163 (1980)

    Article  Google Scholar 

  21. P.J. Flory, “Principles of Polymer Chemistry,” Cornell University Press, Ithaca, New York, 1953, p. 602.

    Google Scholar 

  22. P.J. Flory, in “Macromolecular Chemistry-8,” K. Saarela, Ed., Butterworths, London, 1973, pp. 1–15.

    Google Scholar 

  23. PJ. Flory, J. Macromol. Sci., Phys. ,B12, 1–11 (1976).

    CAS  Google Scholar 

  24. PJ. Flory, Proc. Royal Soc. ,A234, 60 (1956).

    Article  Google Scholar 

  25. S.A. Arzhakov, N.F. Bakeyev, and V.A. Kabanov, Polym. Sci. ,USSR ,A15, 1296–1313 (1973)

    Article  Google Scholar 

  26. S.A. Arzhakov, N.F. Bakeyev, and V.A. Kabanov, Vysokomol. Soyed. ,A15, 1154–1167 (1973).

    Google Scholar 

  27. R.F. Boyer, J. Macromol. Sci. ,Phys. ,B12, 253–301 (1976).

    CAS  Google Scholar 

  28. R.F. Boyer, Ann. N.Y. Acad. Sci. ,279, 223–233 (1976).

    Article  CAS  Google Scholar 

  29. W.W. Graesley, Adv. Polym. Sci. ,16, 3–179 (1974), see especially Section 2.

    Google Scholar 

  30. R.L. Miller and R.F. Boyer, J. Polym. Sci., Polym. Phys. Ed. ,22, 2043–2050 (1984).

    CAS  Google Scholar 

  31. R.L. Miller, R.F. Boyer, and J. Heijboer, J. Polym. Sci., Polym. Phys. Ed. ,22, 2021–2041 (1984).

    CAS  Google Scholar 

  32. R.L. Miller, contribution in this volume.

    Google Scholar 

  33. J.K. Kruger and M. Pietralla, contribution in this volume.

    Google Scholar 

  34. R.F. Boyer, E. Baer, and A. Hiltner, Macromolecules ,18, 427–434 (1985).

    Article  CAS  Google Scholar 

  35. A. Hiltner, contribution in this volume.

    Google Scholar 

  36. Y.C. Yang and P.H. Geil, J. Macromol. Sci. ,Phys. ,B22,463–488 (1983).

    CAS  Google Scholar 

  37. G. Charlet, H. Phuong-Nguyen, and G. Delmas, Macromolecules ,17, 1200–1208 (1984).

    Article  CAS  Google Scholar 

  38. C.W. Bunn, in “Fibers from Synthetic Polymers,” R. Hill, Ed., Elsevier, Amsterdam, 1953, p. 324 ff.

    Google Scholar 

  39. R.E. Robertson, J. Phys. Chem. ,69, 1575–1578 (1965).

    Article  CAS  Google Scholar 

  40. L. Mandelkern, “Crystallization of Polymers,” McGraw-Hill, New York, 1964, Table B-4.

    Google Scholar 

  41. J.D. Hoffman, G.J. Davies, and J.I. Lauritzen, Jr., in “Treatise on Solid State Chemistry,” Vol. 3 ,N.B. Hannay, Ed., Plenum Press, New York, 1975, Chap. 6.

    Google Scholar 

  42. R.F. Boyer, in Encycl. Polym. Sci. ,Technol, Suppl. Vol. 2 ,N. Bikales, Ed., Wiley-Interscience, New York, 1977, p. 769.

    Google Scholar 

  43. J.B. Enns and R.F. Boyer, contribution in this volume.

    Google Scholar 

  44. E.W. Fischer, J.H. Wendorff, H. Dettenmaier, G. Lieser, and I. Voigt-Martin, J. Macromol. Sci. ,Phys. ,B12, 41–59 (1976).

    CAS  Google Scholar 

  45. V.P. Privalko and Y.S. Lipatov, Makromol. Chem. ,175, 641–654 (1974). .

    Article  CAS  Google Scholar 

  46. R.F. Boyer and R.L. Miller, Macromolecules ,10, 1167–1169 (1977).

    Article  CAS  Google Scholar 

  47. K. Ueberreiter, Kolloid Z. ,102, 272 (1943).

    Article  CAS  Google Scholar 

  48. K. Ueberreiter, Z. Physik. Chem. ,B45, 361 (1940)

    CAS  Google Scholar 

  49. K. Ueberreiter, Z. Physik. Chem. ,B46, 157 (1940)

    CAS  Google Scholar 

  50. K. Ueberreiter, Kautschuk ,19, 12 (1943)

    Google Scholar 

  51. K. Ueberreiter and G. Kanig, J. Chem. Phys. ,18, 399–406 (1950).

    Article  CAS  Google Scholar 

  52. K. Ueberreiter, in Adv. Chem. Ser. ,48, 35–48 (1965).

    Article  Google Scholar 

  53. K. Ueberreiter, Colloid Polym. Sci. ,258, 92–94 (1980).

    Article  CAS  Google Scholar 

  54. K. Ueberreiter, Colloid Polym. Sci. ,261, 565–570 (1983).

    Article  CAS  Google Scholar 

  55. F.E. Karasz and W.J. MacKnight, Macromolecules ,1, 537–540 (1968).

    Article  CAS  Google Scholar 

  56. E.V. Thompson, J. Polym. Sci., Part A-2 ,4, 199–208 (1966).

    Article  CAS  Google Scholar 

  57. L.R. Denny, R.F. Boyer, and H.-G. Elias, J. Macromol. Sci., Phys. ,B25, 227–265 (1986).

    CAS  Google Scholar 

  58. A. Gourari, M. Bendaoud, C. Lacabanne, and R.F. Boyer, J. Polym. Sci., Polym. Phys. Ed. ,23, 889–916 (1985).

    Article  CAS  Google Scholar 

  59. K. Ueberreiter and H.-J. Orthmann, Kunststoffe ,48, 525–530 (1958).

    CAS  Google Scholar 

  60. V.A. Kargin, J. Polym. Sci. ,30, 247–258 (1958).

    Article  CAS  Google Scholar 

  61. V.A. Kargin and T.I. Sogolova, Zhur. Fiz. Khim. ,23, 530 (1949).

    CAS  Google Scholar 

  62. H.-G. Elias, “Macromolecules,” (in two volumes), Plenum Press, New York, 1984.

    Google Scholar 

  63. B. Vollmert, “Polymer Chemistry,” Springer-Verlag, New York, Heidelberg, Berlin, 1973.

    Book  Google Scholar 

  64. K. Ueberreiter and D. Buhlke, Berichte Bunsenges., Phys. Chem. ,75, 1221 (1971).

    CAS  Google Scholar 

  65. D.W. Van Krevelen and P.J. Hoftyzer, Angew. Makromol Chem. ,52, 101–109 (1971).

    Google Scholar 

  66. D.W. Van Krevelen “Properties of Polymers,” 2nd ed. ,Elsevier Scientific Publishing Company, New York, 1976. See especially pp. 341–345.

    Google Scholar 

  67. R.F. Boyer, J. Polym. Sci. ,Polym. Phys. Ed. ,23, 1–12 (1985).

    Article  CAS  Google Scholar 

  68. J. Eliassaf, A. Silberberg, and A. Katchalsky, Nature ,176, 1119 (1955).

    Article  CAS  Google Scholar 

  69. A. Silberberg, J. Eliassaf, and A. Katchalsky, Suppl. A., La Ricerca, Scientifica, Anna ,25, 3 (1955).

    Google Scholar 

  70. J. Eliassaf and A. Silberberg, Polymer ,3, 555–564 (1962).

    Article  CAS  Google Scholar 

  71. A. Priel and A. Silberberg, J. Polym. Sci. ,PartA-2 ,8, 713–726 (1970).

    Article  CAS  Google Scholar 

  72. A. Silberberg and P.F. Mijnlieff, J. Polym. Sci. ,PartA-2 ,8, 1089–1110 (1970).

    Article  CAS  Google Scholar 

  73. L.A. Utracki, J. Macromol. Sci. ,Phys. ,B10, 477–505 (1974).

    CAS  Google Scholar 

  74. R.F. Boyer, J. Polym. Sci. ,Part C ,14, 267–281 (1966).

    Google Scholar 

  75. R.S. Spencer and R.E. Dillon, J. Colloid Sci. ,4, 241 (1949).

    Article  CAS  Google Scholar 

  76. M. Pfandl, G. Link, and F.R. Schwarzl, Rheol. Acta ,23, 277–290 (1984).

    Article  CAS  Google Scholar 

  77. R.F. Boyer, J. Polym. Sci. ,Polym. Phys. Ed ,23, 21–40 (1985). See especially pp. 37–38.

    CAS  Google Scholar 

  78. J.D. Ferry and G.S. Parks, Physics ,6, 356–362 (1935).

    Article  CAS  Google Scholar 

  79. P.G. de Gennes, J. Chem. Phys., 55, 572–579 (1971).

    Article  Google Scholar 

  80. P.G. de Gennes, “Scaling Concepts in Polymer Physics,” Cornell University Press, Ithaca, New York, 1979. See also specific citations in refs. 80 through 84.

    Google Scholar 

  81. R. Bacchus and R. Kimmich, Polymer ,24, 964–970 (1983).

    Article  Google Scholar 

  82. J. Klein, Macromolecules ,14, 460–461(1981).

    Article  CAS  Google Scholar 

  83. O. Kramer, R. Greco, R.A. Niera, and J.D. Ferry, J. Polym. Sci. ,Polym. Phys. Ed. ,12, 2361–2374(1974).

    Article  CAS  Google Scholar 

  84. M. Antonietti, J. Coutandin, R. Grutter, and H. Sillescu, Macromolecules ,17, 798–802 (1984).

    Article  CAS  Google Scholar 

  85. M. Antonietti, J. Coutandin, and H. Sillescu, Makromol. Chem., Rapid Commun. ,5, 525 (1984).

    Article  CAS  Google Scholar 

  86. J.P. Ibar, contribution in this volume.

    Google Scholar 

  87. C. Reiss, J. Chim. Phys. ,63, 1299,1307, 1399 (1966).

    CAS  Google Scholar 

  88. C. Reiss and H. Benoit, J. Polym. Sci. ,Part C ,16, 3079–3088 (1968).

    Google Scholar 

  89. M. Kobayashi, K. Akita, and H. Tadokoro, Makromol. Chem. ,118, 324–342 (1968).

    Article  CAS  Google Scholar 

  90. H.-G. Kilian and F. Boueke, J. Polym. Sci. ,58, 311–333 (1962).

    Article  Google Scholar 

  91. S.K. Burley and G.A. Petsko, Science ,229, 23–28 (1985).

    Article  CAS  Google Scholar 

  92. G.R. Mitchell and A.H. Windle, Polymer ,25, 906–920 (1984).

    Article  CAS  Google Scholar 

  93. J.B. Enns, R.F. Boyer, K. Ishida, and J.L. Koenig, Polym. Eng. Sci. ,19, 756–759 (1979).

    Article  CAS  Google Scholar 

  94. S. Krimm and A.V. Tobolsky, Text. Res. J. ,21, 805 (1951).

    Article  CAS  Google Scholar 

  95. S. Krimm and A.V. Tobolsky, J. Polym. Sci. ,6, 667–668 (1951).

    Article  CAS  Google Scholar 

  96. S. Krimm, J. Phys. Chem. ,57, 22–25 (1953).

    Article  CAS  Google Scholar 

  97. J. Schaefer, E.O. Stejskal, D. Perchak, J. Skolnick, and R. Yaris, Macromolecules ,18, 368–373 (1985).

    Article  CAS  Google Scholar 

  98. C.W. Bunn and E.R. Howells, J. Polym. Sci. ,18, 307–310 (1955).

    Article  CAS  Google Scholar 

  99. G. Allen and S.E.B. Petrie, J. Macromol. Sci., Phys. ,B12, 1–301 (1976).

    Google Scholar 

  100. P.H. Lindenmeyer, J. Macromol Sci. ,Phys. ,B8, 361–366 (1973).

    Google Scholar 

  101. P.H. Lindenmeyer, J. Appl. Phys. ,46, 4235–4236 (1975).

    Article  Google Scholar 

  102. G.S.Y. Yeh, J. Macromol. Sci. ,Phys. ,B6, 451–464 (1972).

    Google Scholar 

  103. G.S.Y. Yeh, J. Macromol. Sci. ,Phys. ,B6, 465–478 (1972).

    Google Scholar 

  104. E.S. Hsiue, R.E. Robertson, and G.S.Y. Yeh, J. Macromol. Sci. ,Phys. ,B22, 305–320 (1983).

    CAS  Google Scholar 

  105. S.M. Aharoni, J. Macromol. Sci. ,Phys. ,B7, 73–103 (1973).

    Google Scholar 

  106. M.L. Mansfield, Macromolecules ,19, 851–854 (1986).

    Article  CAS  Google Scholar 

  107. J. Schelten, D.G.H. Ballard, G.D. Wignall, G. Longman, and W. Schmatz, Polymer ,17, 751–757 (1976).

    Article  CAS  Google Scholar 

  108. R.L. Miller, Michigan Molecular Institute, Midland, Michigan, private communication.

    Google Scholar 

  109. J.D. Hoffman, Michigan Molecular Institute, Midland, Michigan, private communication.

    Google Scholar 

  110. J.D. Hoffman, Polymer ,23, 656–670 (1982).

    Article  CAS  Google Scholar 

  111. P.H. Geil, contribution in this volume.

    Google Scholar 

  112. R.F. Boyer and R.G. Snyder, J. Polym. Sci. ,Polym. Lett. Ed. ,15, 315–320 (1977).

    Article  CAS  Google Scholar 

  113. R.F. Boyer and R.L. Miller, Polymer ,27, 0000–0000 (1986).

    CAS  Google Scholar 

  114. M. Shen, Macromolecules ,2, 358–364 (1969).

    Article  CAS  Google Scholar 

  115. S.E. Keinath and R.F. Boyer, J. Appl. Polym. Sci. ,26, 2077–2085 (1981).

    Article  CAS  Google Scholar 

  116. S.E. Keinath, contribution in this volume.

    Google Scholar 

  117. N.G. McCrum, B.E. Read, and G. Williams, “Anelastic and Dielectric Effects in Polymeric Solids,” Wiley, New York, 1967.

    Google Scholar 

  118. T.G. Fox and P.J. Flory, J. Appl. Phys. ,21, 581 (1950).

    Article  CAS  Google Scholar 

  119. W.A. Lee and G.J. Knight, Brit. Polym. J. ,2, 73–80 (1970).

    Article  CAS  Google Scholar 

  120. R.F. Boyer, J. Polym. Sci., Polym. Symp. ,50, 189–242 (1975).

    Article  CAS  Google Scholar 

  121. R.F. Boyer, Brit. Polym. J. ,14, 163–172 (1982).

    Article  CAS  Google Scholar 

  122. R.F. Boyer and R.L. Miller, Michigan Molecular Institute, Midland, Michigan, unpublished manuscript. Because we were anticipated by Privalko and Lipatov (ref. 44), this material was never published. See, however, Appendix V.

    Google Scholar 

  123. M. Kurata and W.H. Stockmayer, Adv. Polym. Sci. ,3, 196–312 (1963).

    Article  CAS  Google Scholar 

  124. J. Brandrup and E.H. Immergut, Eds., “Polymer Handbook,” 2nd ed. ,Wiley-Interscience, New York, 1975. Section IV-1.

    Google Scholar 

  125. S.M. Aharoni, Macromolecules ,16, 1722–1728 (1983).

    Article  CAS  Google Scholar 

  126. R.O. Loutfy and D.M. Teegarden, Macromolecules ,16, 452–456 (1983).

    Article  CAS  Google Scholar 

  127. E.R. Fitzgerald, L.D. Grandine, and J.D. Ferry, J. Appl. Phys. ,24, 650–655 (1953).

    Article  CAS  Google Scholar 

  128. R.S. Porter and J.F. Johnson, J. Polym. Sci. ,Part C ,15, 373–380 (1966).

    Google Scholar 

  129. V.P. Privalko and Y.S. Lipatov, J. Polym. Sci. ,Polym. Phys. Ed. ,14, 1725–1727 (1976).

    Article  CAS  Google Scholar 

  130. J.-S. Wang, R.S. Porter, and J.R. Knox, J. Polym. Sci. ,Polym. Lett. Ed. ,8, 671–675 (1970).

    Article  CAS  Google Scholar 

  131. K.L. Ngai and D.J. Plazek, J. Polym. Sci. ,Polym. Phys. Ed. ,23, 2159–2180 (1985).

    Article  CAS  Google Scholar 

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  1. Michigan Molecular Institute, 1910 West St. Andrews Road, Midland, Michigan, 48640, USA

    Raymond F. Boyer

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  1. Raymond F. Boyer
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  1. Michigan Molecular Institute, 1910 West St. Andrews Road, Midland, Michigan, 48640, USA

    Steven E. Keinath  & Robert L. Miller  & 

  2. Dow Chemical Company, 1702 Building, Midland, Michigan, 48674, USA

    James K. Rieke

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Boyer, R.F. (1987). Evidence from T ll and Related Phenomena for Local Structure in the Amorphous State of Polymers. In: Keinath, S.E., Miller, R.L., Rieke, J.K. (eds) Order in the Amorphous “State” of Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1867-5_7

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