Skip to main content

Abstract

Iron-57 Mössbauer spectroscopy has been used in three areas of analysis of precipitator ash and deposits resulting from the combustion of Victorian brown coals. The principal iron-containing constituents identified in the samples were two mixed oxides (calcium aluminoferrite and magnesioaluminum ferrite). The changes occurring in some of the phases by altering the combustion conditions and during wet agglomeration are described. This work is aimed at developing a systematic description of relative phase stabilities for different flyash compositions, based on chemical analysis of the coal.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J. D. Cashionr B. Maguire, and L. T. Kiss, in “Mössbauer Spectroscopy and Its Chemical Applications”, J. G. Stevens and G. K. Shenoy, eds., Am. Chem. Soc. Adv. Chem. Series, Vol. 194, p. 209 (1981).

    Google Scholar 

  2. P. S. Cook and J. D. Cashion, submitted for publication (1985).

    Google Scholar 

  3. J. D. Cashion, P. E. Clark, P. S. Cook, F. P. Larkins, and M. Marshall, in “Nuclear and Electron Resonance Spectroscopies Applied to Materials Science”, E. N. Kaufmann and G. K. Shenoy, eds., North Holland, New York, p. 277 (1981).

    Google Scholar 

  4. P. S. Cook, J. D. Cashion, and P. J. Cassidy, Fuel 64, 1121 (1985).

    Article  Google Scholar 

  5. F. E. Huggins and G. P. Huffman, in “Analytical Methods for Coal and Coal Products”, C. J. Karr, ed., vol. 3, p. 371, Academic Press, New York (1979).

    Google Scholar 

  6. C. C. Hinckley, G. V. Smith, H. Twardowska, M. Saporoschenko, R. H. Shiley, and R. A. Griffin, Fuel 59, 161 (1980).

    Article  Google Scholar 

  7. G. F. P. E. Huffman, F. E. Huggins, and G. R. Dunmyre, Huggins, D. A. Kosmack, and G. P. Huffman, Fuel 60, 585 (1981)

    Article  Google Scholar 

  8. G. F. P. E. Huffman, F. E. Huggins, and G. R. Dunmyre, Huggins, D. A. Kosmack, and G. P. Huffman, Fuel 60, 577 (1981).

    Article  Google Scholar 

  9. S. P. Taneja and C. H. W. Jones, Fuel 63, 695 (1984).

    Article  Google Scholar 

  10. M. D. Patil, H. C. Eaton, and M. E. Tittiebaum, Fuel 63, 788 (1984).

    Article  Google Scholar 

  11. T. L. H. Aikin, J. D. Cashion, and A. L. Ottrey, Fuel 63, 1269 (1984).

    Article  Google Scholar 

  12. J. S. Hall, C. S. Hannaford, J. D. Cashion, L. J. Brown, A. L. Ottrey, and D. Tang, 1985 Proc. 4th Int. Conf. on Agglomeration, Toronto, Nov. 1984.

    Google Scholar 

  13. S. Geller, R. W. Grant, and L. D. Fullmer, J. Phys. Chem. Solids 31, 793 (1970).

    Article  Google Scholar 

  14. E. de Grave, A. Govaert, D. Chambaere, and G. Robbrecht, Physica 96B, 103 (1979).

    Google Scholar 

  15. W. Kündig, H. Bommel, G. Constabaris, and R. H. Lindquist, Phys. Rev. 142, 327 (1966).

    Article  Google Scholar 

  16. J. M. Fortune and J. M. D. Coey, Cem. Concr. Res. 13, 696 (1983).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1986 Plenum Press, New York

About this chapter

Cite this chapter

Cashion, J.D., Brown, L.J., Ottrey, A.L. (1986). Iron Phases in Brown Coal Ashes. In: Long, G.J., Stevens, J.G. (eds) Industrial Applications of the Mössbauer Effect. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1827-9_27

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-1827-9_27

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9021-6

  • Online ISBN: 978-1-4613-1827-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics