Abstract
Iron-57 Mössbauer spectroscopy has been used in three areas of analysis of precipitator ash and deposits resulting from the combustion of Victorian brown coals. The principal iron-containing constituents identified in the samples were two mixed oxides (calcium aluminoferrite and magnesioaluminum ferrite). The changes occurring in some of the phases by altering the combustion conditions and during wet agglomeration are described. This work is aimed at developing a systematic description of relative phase stabilities for different flyash compositions, based on chemical analysis of the coal.
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J. D. Cashionr B. Maguire, and L. T. Kiss, in “Mössbauer Spectroscopy and Its Chemical Applications”, J. G. Stevens and G. K. Shenoy, eds., Am. Chem. Soc. Adv. Chem. Series, Vol. 194, p. 209 (1981).
P. S. Cook and J. D. Cashion, submitted for publication (1985).
J. D. Cashion, P. E. Clark, P. S. Cook, F. P. Larkins, and M. Marshall, in “Nuclear and Electron Resonance Spectroscopies Applied to Materials Science”, E. N. Kaufmann and G. K. Shenoy, eds., North Holland, New York, p. 277 (1981).
P. S. Cook, J. D. Cashion, and P. J. Cassidy, Fuel 64, 1121 (1985).
F. E. Huggins and G. P. Huffman, in “Analytical Methods for Coal and Coal Products”, C. J. Karr, ed., vol. 3, p. 371, Academic Press, New York (1979).
C. C. Hinckley, G. V. Smith, H. Twardowska, M. Saporoschenko, R. H. Shiley, and R. A. Griffin, Fuel 59, 161 (1980).
G. F. P. E. Huffman, F. E. Huggins, and G. R. Dunmyre, Huggins, D. A. Kosmack, and G. P. Huffman, Fuel 60, 585 (1981)
G. F. P. E. Huffman, F. E. Huggins, and G. R. Dunmyre, Huggins, D. A. Kosmack, and G. P. Huffman, Fuel 60, 577 (1981).
S. P. Taneja and C. H. W. Jones, Fuel 63, 695 (1984).
M. D. Patil, H. C. Eaton, and M. E. Tittiebaum, Fuel 63, 788 (1984).
T. L. H. Aikin, J. D. Cashion, and A. L. Ottrey, Fuel 63, 1269 (1984).
J. S. Hall, C. S. Hannaford, J. D. Cashion, L. J. Brown, A. L. Ottrey, and D. Tang, 1985 Proc. 4th Int. Conf. on Agglomeration, Toronto, Nov. 1984.
S. Geller, R. W. Grant, and L. D. Fullmer, J. Phys. Chem. Solids 31, 793 (1970).
E. de Grave, A. Govaert, D. Chambaere, and G. Robbrecht, Physica 96B, 103 (1979).
W. Kündig, H. Bommel, G. Constabaris, and R. H. Lindquist, Phys. Rev. 142, 327 (1966).
J. M. Fortune and J. M. D. Coey, Cem. Concr. Res. 13, 696 (1983).
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© 1986 Plenum Press, New York
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Cashion, J.D., Brown, L.J., Ottrey, A.L. (1986). Iron Phases in Brown Coal Ashes. In: Long, G.J., Stevens, J.G. (eds) Industrial Applications of the Mössbauer Effect. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1827-9_27
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DOI: https://doi.org/10.1007/978-1-4613-1827-9_27
Publisher Name: Springer, Boston, MA
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