Abstract
Pyrite, an impurity commonly found in coal, will react with air to form sulfur oxides, which are poisonous to humans and can cause severe damage to industrial equipment. Because of the relatively high percentage of pyrite found in many coals, it is necessary to treat coal to satisfy environmental regulations. Mössbauer spectroscopy can be effectively used to monitor the pyrite and other iron sulfides through various coal treatment processes.
Mechanical treatment of coal, such as froth flotation and float-sink Separation, is today the most commonly used procedure. For pulverized coal, it is possible to use magnetic desulfurization in which pyrite is transformed into pyrrhotite. This enhances the magnetic susceptibility of the inorganic sulfur containing material.
Other treatment processes include several chemical methods and biological leaching, which still needs development, but is very promising. One of the chemical methods is the Meyer’s process, TWR, and is perhaps the best because it recycles the chemical, it does not require fine crushing of the coal, and sulfur removal is very efficient.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Unleashing A Black Beauty, Air Magazine, April, pp. 5–11 (1978).
H. Heidenreich, Wissenschaftliche und wirtschaftliche Untersuchungen in der Steinkohleaufbereitung, Glueckauf 65 (28), 13 (1929)
H. Heidenreich, Wissenschaftliche und wirtschaftliche Untersuchungen in der Steinkohleaufbereitung, Glueckauf 6.5 (29), 20 (1929).
C. Wolf, Rev. Ind. Min., 326 (1934).
K. F. Tromp, Neue Wege für die Beurteilung der Aufbereitung von Steinkohlen, Glueckauf 33, 60 (1937).
A. Terra, Rev. Ind. Min., 411 (1937).
P. Belugou and J. Ulmo, in First International Conference on Coal Preparation, Paris (1950).
P. A. Montano, in Coal Structure, M. L. Gorbaty and K. Ouchi, eds., Advances in Chemistry Series, No. 192, 338 (1979).
P. A. Montano, in Nuclear and Electron Resonance Spectroscopies Applied to Materials Science, E. Kaufman and G. K. Shenoy, eds., pp. 171–183 (1981).
D. L. Williamson, T. W. Guettinger, and D. W. Dickerhoof, in Mössbauer Spectroscopy and Its Chemical Applications, J. G. Stevens and G. K. Shenoy, eds., Advances in Chemistry, No. 194, pp. 179–208 (1981).
L. Wuckowska, in Solid Fuels, Prace Glownego Insyytutu Gorniectwa, Wydawnictwo Slak, Katowice, pp 3–12 (1984).
L. M. Levinson and I. S. Jacobs, Fuel 56, 453 (1977).
C. G. Clayton, A. M. Hassan, and M. R. Wormald, Int. J. Appl. Radiat. Isot. 34 (1), 83 (1893).
P. R. Solomon and A. V. Manzione, Coal and Char. Fuel 56, 393 (1977).
M. Berman and S. Ergun, Analysis of Sulphur in Coals by X-Ray Fluorescence (1967).
S. S. Pollack, Fuel 50, 453 (1971).
F. E. Huggins, D. A. Kosmack, G. P. Huffman, and R. J. Lee, 1, 531 (1980).
G. P. Huffman and F. E. Huggins, Fuel 57, 592 (1978).
P. A. Montano, Application of Mössbauer Spectroscopy to Goal Characterization and Utilization, in Mössbauer Spectroscopy and Its Chemical Applications, J. G. Stevens and G. K. Shenoy, ed., Advances in Chemistry, No. 194, pp. 135–175 (1981).
Methodes de Reduction de la Teneur en Soufre des Combustibles Solides, Commission Economique pour l’Energie, Comite du Charbon, Rapport ST/ECE/Coal/63, pp. 29, Released on August 17, 1973.
J. W. Tieman, The Sulphur Problem in Coal: What’s being done to get rid of it, Industrial Coal Conference, University of Kentucky, April 12–13 (1967).
F. M. Monstry, Glueckauf 115 (18), 420 (1979).
Multi-Stream Coal Cleaning System promises Help with Sulfur Problem, Coal Age (January), pp. 86–88 (1976).
T. D. Wheelock, Coal Desulfurization, Chemical and Physical Methods, in ACS Symposium Series 64, R. F. Gould ed., American Chemical Society, Washington D. C., p. 332 (1977).
Will Chemicals Replace Crushing?, Coal Age (Febuary), pp. 176–179 (1978).
Solvent Refining gets the Sulphur out of Coal, World Mining (June), 32–33 (1973).
L. Lorenzie Jr., J. S. Land, L. J. Van Nice, E. P. Koustoudoand, R. A. Meyers, Coal Age, 76 (1972).
R. A. Meyers, Hydrocarbon Processes, 123 (1979).
J. C. Agarwal, R. A. Giberti, P. F. Irminger, L. F. Petrovic, and S. S. Sareen, Mining Congress J. 61, 40 (1975).
A. R. Bommannavar and P. A. Montano, Fuel 61, 523 (1982).
C. R. Porter and D. N. Goens, Mining Engineering (Febuary), 175 (1979).
D. Ashmead, Colliery Guardian J. Coal Iron Trades 190, 694 (1955).
C. E. Capes, A. E. Mclliney, A. F. Puddington, and I. E. Puddington, The Canadian Mining and Metallurgical Bulletin (November), 88 (1973).
M. P. Silverman, M. H. Rogoff, and I. Wender, Fuel 41, 113, (1963).
R. B. Baker, Water Research 6, 9 (1972).
R. von Der Gathem, Glueckauf 115 (3), 52 (1979).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1986 Plenum Press, New York
About this chapter
Cite this chapter
Pollak, H., Stevens, J.G. (1986). Coal Treatment and Desulfurization. In: Long, G.J., Stevens, J.G. (eds) Industrial Applications of the Mössbauer Effect. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1827-9_26
Download citation
DOI: https://doi.org/10.1007/978-1-4613-1827-9_26
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-9021-6
Online ISBN: 978-1-4613-1827-9
eBook Packages: Springer Book Archive