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Transition Metal Substitution in Fe7 5TM5 B2 0 Amorphous Alloys. Effect on Structure, Thermal Stability, and Structural Relaxation

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Industrial Applications of the Mössbauer Effect

Abstract

A series of amorphous alloys of Fe80B20, with a constant amount of transition metal substitution and the nominal composition Fe75TM5B20, have been obtained by the “melt-spinning” technique. Differential scanning calorimetry, resistivity, small angle x-ray scattering measurements, and Mössbauer spectroscopy have been utilized to study the substitution-induced modification of the behavior, in both the amorphous and annealed states, of the temperature and enthalpy of crystallization, the activation energy for crystallization, the electrical resistivity, the local magnetic and electronic properties, and the structural homogeneity. The effects of substitution on the electronic structure and hyperfine field at the iron atoms are also discussed.

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References

  1. L. Granasy, A. Lovas, L. Kiss, T. Kemeny, and E. Kisdi-Koszo, J. Magn. Magn. Mater. 26, 109 (1982).

    Article  Google Scholar 

  2. A. Lovas, L. Granasy, K. Zambo-Balla, and J. Kiraly, in Proceedings Conference on “Metallic Glasses: Science and Technology”, CRIP Budapest, vol. II, p. 291 (1980).

    Google Scholar 

  3. J. L. Walter, Mater. Sei. Eng. 50, 137 (1981).

    Article  Google Scholar 

  4. M. Naka, U. Gonser, C. Gorlitz, and H. Ruppersberg, J. Non-Cryst. Solids 45, 99 (1981).

    Article  Google Scholar 

  5. I. W. Donald and M. A. Davies, in “Proc. Third Int. Conf. on Rapidly Quenched Metals”, B. Cantor, ed., vol. I, The Metals Society, London, p. 273 (1978).

    Google Scholar 

  6. R. Ray, R. Hasegawa, C. P. Chou, and L. A. Davis, Scripta Met. 11, 973 (1977).

    Article  Google Scholar 

  7. G. Cocco, S. Enzo, C. Antonione, G. Riontino, G. Venturello, Solid State Comm. 51, 771 (1984).

    Article  Google Scholar 

  8. J. M. Greneche and F. Varret, J. Phys. C 15, 5333 (1982).

    Article  Google Scholar 

  9. J. Hesse and A. Rubartsch, J. Phys. E 7, 526 (1974).

    Article  Google Scholar 

  10. G. Le Caer and J. M. Dubois, J. Phys. E 12, 1083 (1979).

    Article  Google Scholar 

  11. S. L. Ruby, Mössbauer Effect Meth. 8, 263 (1973).

    Google Scholar 

  12. T. Ozawa, J. Therm. Anal. 2, 301 (1970).

    Article  Google Scholar 

  13. M. Naka, J. Non-Cryst. Solids 41, 71 (1980).

    Article  Google Scholar 

  14. R. Hultgren, R. L. Orr, P. D. Anderson, and K. K. Kelley, in “Selected Values of Thermodynamic Properties of Metals and Alloys”, J. Wiley and Sons, N. Y., 1963.

    Google Scholar 

  15. H. W. King, J. Mater. Sei. 1, 79 (1966).

    Article  Google Scholar 

  16. C. Antonione, G. Deila Gatta, A. Lucci, G. Riontino, and G. Venturello, Acta Met. 18, 1169 (1970).

    Article  Google Scholar 

  17. C. Antonione, L. Battezzati, A. Lucci, G. Riontino, and G. Venturello, Scripta Met. 12, 1011 (1978).

    Article  Google Scholar 

  18. L. Battezzati, A. Lucci, and G. Riontino, Thermochem. Acta 23, 213 (1978).

    Article  Google Scholar 

  19. A. L. Greer, Acta Met. 30, 171 (1982).

    Article  Google Scholar 

  20. A. S. Schaafsma, H. Snijders, F. van der Woude, J. W. Drijver, and S. Radelaar, Phys. Rev. B 20, 4423 (1979).

    Article  Google Scholar 

  21. F. E. Luborsky and H. H. Liebermann, Appl. Phys. Lett. 33, 233 (1978).

    Article  Google Scholar 

  22. J. Borchardt and F. Daniels, J. Am. Chem. Soc. 79, 41 (1957).

    Article  Google Scholar 

  23. J. Colmenero, J. Ilarraz, and J. M. Barandiaran, Thermochim. Acta 35, 381 (1980).

    Article  Google Scholar 

  24. S. Ranganathan and M. Von Heimendhai, J. Mat. Sei. 16, 2401 (1981).

    Article  Google Scholar 

  25. A. Lucci, G. Riontino, F. Marino, C. Antonione, and G. Cocco, Materials Chemistry and Physics 10, 549 (1984).

    Article  Google Scholar 

  26. R. W. Cahn, Contemp. Phys. 21, 43 (1980).

    Article  Google Scholar 

  27. T. Egami, K. Maeda, and V. Vitek, Phil. Mag. 41, 883 (1980).

    Article  Google Scholar 

  28. T. Egami, Ann. N. Y. Acad. Sei. 371, 236 (1981).

    Google Scholar 

  29. P. Allia, D. Andreone, R. Sato Turtelli, F. Vinai, and G. Riontino, J. Appl. Phys. 53, 8798 (1982).

    Article  Google Scholar 

  30. L. Battezzati and G. Riontino, to be published.

    Google Scholar 

  31. R. P. Messmer, in “Amorphous Metallic Alloys”, F. E. Luborsky, eds., Butterworths, London p. 114 (1983).

    Google Scholar 

  32. I. Vincze, F. Van Der Woude, T. Kemeny, and A. S. Schaafsma, J. Magn. Magn. Mater. 15-18, 1336 (1980).

    Article  Google Scholar 

  33. P. Allia, R. Sato Turtelli, F. Vinai, and G. Riontino, Solid State Commun. 43, 821 (1982).

    Article  Google Scholar 

  34. L. Takacs, A. Vertes, A. Lovas, E. Kovacs, J. Farkas, and L. Kiss, Nuclear Instruments and Methods 199, 281 (1982).

    Article  Google Scholar 

  35. L. R. Walker, G. K. Wertheim, and V. Jaccarino, Phys. Rev. Letters 6, 3 (1961).

    Article  Google Scholar 

  36. L. Cser, I. Gladkin, and C. Hargitai, Phys. Stat. Sol. (b) 124, 271 (1984).

    Article  Google Scholar 

  37. S. M. Dubiel and J. Zukrowski, J. Magn. Magn. Mater. 23, 214 (1981).

    Article  Google Scholar 

  38. S. M. Dubiel and W. Zinn, J. Magn. Magn. Mater. 45, 298 (1984).

    Article  Google Scholar 

  39. R. C. O’Handley, Solid State Comm. 38, 703 (1981).

    Article  Google Scholar 

  40. T. Kemeny, B. Fogarassy, I. Vincze, I. W. Donald, M. J. Besnus, and H. A. Davies, Proc. 4th Int. Conf. on Rapidly Quenched Metals, T. Masumoto and K. Suzuki, eds., The Japan Institute of Metals, Sendai, Japan, p. 851 (1982).

    Google Scholar 

  41. E. Nold, P. Lamparter, H. Olbrich, A. Rainier-Harbach, and S.Steeb, Z. Naturforsch. 36a, 1032 (1981).

    Google Scholar 

  42. K. Osamura, K. Shibue, R. Suzuki, and Y. Murakami, J. Mat. Sei. 16, 957 (1981).

    Article  Google Scholar 

  43. E. Nold, S. Steeb, and P. Lamparter, Z. Naturforsch 35a, 610 (1980).

    Google Scholar 

  44. J. L. Walter, S. F. Bartram, and I. Mello, Mater. Sei. Eng. 36, 193 (1978).

    Article  Google Scholar 

  45. J. M. Dubois and G. Le Caer, in “The Structure of Non-Crystalline Materials”, P. H. Gaskell, ed., Taylor & Francis, London, p. 206 (1982)

    Google Scholar 

  46. J. Durand, in “Glassy Metals: Magnetic, Chemical and Structural Proper ties”, R. Hasegawa, ed., CRC Press, Inc., Florida (USA), p. 109 (1983).

    Google Scholar 

  47. J. L. Walter and A. E. Berkowitz, in “Rapidly Quenched Metals”, S. Steeb and H. Warlimont, eds., Elsevier Science Publishers B.V., New York, p. 1303 (1985).

    Google Scholar 

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© 1986 Plenum Press, New York

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Matteazzi, P., Cocco, G., Le Caer, G., Riontino, G. (1986). Transition Metal Substitution in Fe7 5TM5 B2 0 Amorphous Alloys. Effect on Structure, Thermal Stability, and Structural Relaxation. In: Long, G.J., Stevens, J.G. (eds) Industrial Applications of the Mössbauer Effect. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1827-9_17

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  • DOI: https://doi.org/10.1007/978-1-4613-1827-9_17

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9021-6

  • Online ISBN: 978-1-4613-1827-9

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