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Phosphorus to Bismuth

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Abstract

Phosphorus-31 is spin 1/2, 100% abundant and has a receptivity relative to the proton of 0.0663. In consequence, this is an easy nucleus to observe, and even prior to 1970 a great deal of information had been obtained for simple compounds using continuous wave instruments. The advent of pulsed NMR techniques has greatly accelerated development of the field (especially in coordination chemistry and biochemistry), and 31P is now one of the most common of all NMR experiments. With the additional constraints imposed by the dearth of recent comprehensive review literature, it is impossible to provide comprehensive coverage within a single chapter of limited length. I will aim at an outline of the main developments with sufficient lead references to enable individuals to trace details applicable to their own work; but I apologize in advance for the inevitable omissions and personal bias in the selection of material. Literature coverage in the present article extends to about the end of 1982 with minor additions during the prolonged development of the book.

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Dixon, K.R. (1987). Phosphorus to Bismuth. In: Mason, J. (eds) Multinuclear NMR. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1783-8_13

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