Skip to main content
SpringerLink
Log in
Book cover

Fundamentals of Adsorption pp 417–424Cite as

Thermodynamically Consistent Analysis of Silica Surface Heterogeneity Using Alkane and Alkene Adsorption Isotherms

  • Chapter

Part of the book series: The Kluwer International Series in Engineering and Computer Science ((SECS,volume 356))

Abstract

Adsorption isotherms for butane and butene, measured on silica samples at different temperatures, are used as a data base for describing these gas-solid adsorption systems. Data are analyzed using non-parametric regression and the stable numerical method for solving the adsorption integral equation. The adsorption energy scale of the calculated distributions is assessed on the basis of its consistency with the isosteric heats of adsorption. The effect of lateral interactions between adsorbed molecules on the results obtained is discussed. The adsorption properties of the initial and heat treated silica samples are discussed in terms of their butane and butene adsorption energy distributions.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. M. Jaroniec, R. Madey, Physical Adsorption on Heterogeneous Solids, Elsevier, Amsterdam, 1988.

    Google Scholar 

  2. W. Rudzinski, D. H. Everett, Adsorption of Gases on Heterogeneous Surfaces, Academic Press, London, 1991.

    Google Scholar 

  3. A. N. Tikhonov, Dokl. Akad. Nauk USSR, 39, 195 (1943).

    Google Scholar 

  4. J. Jagiełło, Langmuir 10, 2778 (1994).

    Article  Google Scholar 

  5. L. Czepirski, J. Jagiełło, Chem. Eng. Sci. 44, 797 (1989).

    Article  CAS  Google Scholar 

  6. J. Jagiełło, P. Sanghani, T. J. Bandosz, and J. A. Schwarz, Carbon 30, 507 (1992).

    Article  Google Scholar 

  7. T. J. Bandosz, J. Jagiełło, and J.A. Schawrz, Langmuir 9, 2518 (1993).

    Article  CAS  Google Scholar 

  8. C. De Boor, A practical Guide to Splines, Springer-Verlag, New York, 1978.

    Google Scholar 

  9. B. W. Silverman, J. R. Statist. Soc. B 47, 1 (1985).

    Google Scholar 

  10. P. Craven, G. Whaba, Numer. Math. 31, 377 (1979).

    Article  Google Scholar 

  11. G. Wahba, J. R. Statist. Soc. B 45, 1333 (1983)

    Google Scholar 

  12. W. A. House, M. Jaycock, J. Colloid Polym. Sci. 256, 52 (1978)

    Article  CAS  Google Scholar 

  13. R. K. Iler, The Colloid Chemistry of Silica and Silicates, Cornell University Press, Ithaca, New York, 1955, pp. 233–275.

    Google Scholar 

  14. J. Jagiełło, G. Ligner, E. Papirer, J. Colloid Interface Sci. 137, 128 (1990).

    Article  Google Scholar 

  15. I. Tijburg, J. Jagiełło, A. Vidal, E. Papirer, Langmuir 7, 2243 (1991).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Energochemistry of Coal and Physical Chemistry of Sorbents, University of Mining and Metallurgy, 30-059, Krakow, Poland

    Jacek Jagiello

  2. Institute of Inorganic Chemistry, Slovak Academy of Sciences, 842 36, Bratislava, Slovakia

    Karol Putyera

  3. Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, NY, 13244, USA

    Jacek Jagiello, Teresa J. Bandosz, Karol Putyera & James A. Schwarz

Authors
  1. Jacek Jagiello
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Teresa J. Bandosz
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Karol Putyera
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. James A. Schwarz
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. University of Virginia, USA

    M. Douglas LeVan

Rights and permissions

Reprints and permissions

Copyright information

© 1996 Kluwer Academic Publishers

About this chapter

Cite this chapter

Jagiello, J., Bandosz, T.J., Putyera, K., Schwarz, J.A. (1996). Thermodynamically Consistent Analysis of Silica Surface Heterogeneity Using Alkane and Alkene Adsorption Isotherms. In: LeVan, M.D. (eds) Fundamentals of Adsorption. The Kluwer International Series in Engineering and Computer Science, vol 356. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1375-5_52

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-1375-5_52

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8594-6

  • Online ISBN: 978-1-4613-1375-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation