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Peroxo heteroligand vanadates(V): Synthesis, spectra-structure relationships, and stability toward decomposition

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Vanadium Compounds: Biochemical and Therapeutic Applications

Part of the book series: Developments in Molecular and Cellular Biochemistry ((DMCB,volume 16))

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Abstract

Effect of heteroligands (L) on the properties of vanadium peroxides was investigated by preparing a number of peroxo vanadium complexes, which were characterized by analysis, IR, UV/V and NMR spectra. X-ray structures for some were obtained. The vanadates(V) contain the cation M(I) = Na, K, NH4, Rb or Cs. Diperoxo complexes include M(I)[VO(O2)2 L], where L = dipyridyl, o-phenanthroline; M(I)3[VO(O2)2(C2O4)]; K2[(nicotinic acid){VO(O2)2}2]H2O;M(I)4[O{VO(O2)2}2cystine]2H2O; H4[O{VO(O2)2(adenine)2)2]2H2O; and K2H2[O{VO(O2)2(adenosine)}2]2H2O. Monoperoxo vanadates(V) correspond to the formula M(I)2[VO(O2)L]2 for L = citrate and malate; M(I)2[VO(O2)L] for L = nitrilotriacetate; M(I)[VO(O2)L] for L = iminodiacetate, tartrate and EDTA; and [HVO2(O2)(adenosine)]2H2O. Syntheses of these heteroligand peroxovanadium compounds are sensitive to pH, temperature and the concentration of the components. The stability towards decomposition in solid state, mother-liquid and pure water solutions depends upon the heteroligand. Characteristic (V=0) and (O-O) stretching frequency bands in IR can be correlated with the corresponding bond lengths and the [peroxo∼V(V)] charge transfer bands in UV/V spectra. Intramolecular one-electron transfer in peroxo vanadates(V) can trigger the generation of radicals, and its dependency upon the nature of the heteroligand is discussed.

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Authors and Affiliations

  1. Department of Chemistry, The College of William and Mary, Williamsburg, VA, 23187-8795, USA

    Cirila Djordjevic

  2. Institute of Tobacco, 41000, Zagreb, Croatia

    Nikola Vuletic

  3. Kaiser M. D. Associated, Los Angeles, CA, 90274, USA

    Myunghi Lee Renslo

  4. Department of Anesthesiology, College of Medicine, University of Florida, Gainesville, FL, 32610, USA

    Bruce C. Puryear

  5. Medical College of Virginia, VCU, Richmond, VA, 23298-0462, USA

    Ramin Alimard

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  1. Cirila Djordjevic
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  2. Nikola Vuletic
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  3. Myunghi Lee Renslo
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  4. Bruce C. Puryear
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  5. Ramin Alimard
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  1. Centre de Recherche, Hotel-Dieu de Montreal, 3850, rue Saint Urbain, Pavillion Marie de la Ferre, Montreal, Quebec, H2W 1T8, Canada

    Ashok K. Srivastava  & Jean-Louis Chiasson  & 

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© 1995 Kluwer Academic Publishers

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Djordjevic, C., Vuletic, N., Renslo, M.L., Puryear, B.C., Alimard, R. (1995). Peroxo heteroligand vanadates(V): Synthesis, spectra-structure relationships, and stability toward decomposition. In: Srivastava, A.K., Chiasson, JL. (eds) Vanadium Compounds: Biochemical and Therapeutic Applications. Developments in Molecular and Cellular Biochemistry, vol 16. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1251-2_3

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  • DOI: https://doi.org/10.1007/978-1-4613-1251-2_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8533-5

  • Online ISBN: 978-1-4613-1251-2

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