Skip to main content

Part of the book series: Polymer Science and Technology ((POLS,volume 37))

Abstract

The absorption of water by the organic polymeric materials employed in adhesive and surface coating systems is generally considered harmful. Disadvantageous effects resulting from exposure to warm/moist environments can include plasticization, lowering of glass temperature and disruption of the interfacial region between substrate and organic phase. One approach to alleviate such effects concerns the use of polymers having a high degree of hydrophobicity. In recent years fluorinated epoxy resins have been developed at the Naval Research Laboratory (NRL) offering this capability. This paper briefly discusses the underlying principles of fluoroepoxy resin chemistry followed by a discussion concerning the water absorption characteristics of various NRL developed formulations. An attempt is made to correlate this behavior with changes in formulation variables. The mechanical and fracture properties of the various fluoroepoxy systems are also discussed and compared with properties generally found with non-fluorinated epoxy resins.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. CE Browning, Polym. Eng. Sci., 18, 16, 1978.

    Article  CAS  Google Scholar 

  2. C. Carfagna, A. Apicella, L. Nicolais, J. Appl. Polym. Sci., 27, 105, 1982.

    Article  CAS  Google Scholar 

  3. DM Brewis, J. Comyn, RJA Shalash, Int. J. Adhes. and Adhes., 215, Oct. 1982.

    Google Scholar 

  4. DM Brewis, J. Comyn, RJA Shalash, Polym. Comm., 24, 67, 1983.

    CAS  Google Scholar 

  5. EL McKague, JD Reynolds, FE Halkais, J. Appl. Polym. Sci., 22, 1643, 1978.

    Article  CAS  Google Scholar 

  6. T.S. Ellis, F.E. Karasz, Polymer, 25, 664, 1984.

    Article  CAS  Google Scholar 

  7. J. Mijovic, SA Weinstein, Polym. Comm., 26, 237, 1985.

    CAS  Google Scholar 

  8. RA Gledhill, AJ Kinloch, J. Adhes., 6, 315, 1974.

    Article  CAS  Google Scholar 

  9. MK Antoon, JL Koenig, J. Macromol. Sci..-Rev. Macromol. Chem., C19(1), 135, 1980.

    Article  Google Scholar 

  10. W.C. Wake, Adhesion and the Formulation of Adhesives, Applied Science, London, p. 174, 1982.

    Google Scholar 

  11. JR Griffith, JE Quick, Adv. Chem. Ser., 92, 8, 1970.

    Article  CAS  Google Scholar 

  12. R. Griffith, AG Sands, J. Cowling, Adv. Chem. Ser., 99, 471, 1971.

    Article  CAS  Google Scholar 

  13. J.R. Griffith, J.G. O’Rear, S.A. Reines, CHEMTECH, 311, 1972.

    Google Scholar 

  14. DL Hunston, JR Griffith, RC Bowers, Ind. Eng. Chem. Prod. Res. Dev., 17, 10, 1978.

    Article  CAS  Google Scholar 

  15. J.R. Griffith, CHEMTECH, 290, 1982.

    Google Scholar 

  16. J. Goobich, G. Marom, Polym. Eng. Sci., 22, (16), 1052, 1982.

    Article  CAS  Google Scholar 

  17. P. Johncock, GF Tudgey, Br. Polym. J., 15, 14, 1983.

    Article  CAS  Google Scholar 

  18. J.A. Barrie, P.S. Sagoo, P. Johncock., Polymer, 26, 1167, 1985.

    Article  CAS  Google Scholar 

  19. J.F. Knott, Fundamentals of Fracture Mechanics, Butterworths, London, 1973.

    Google Scholar 

  20. ASTM Standard D790-71, 1973.

    Google Scholar 

  21. H. Fujita, Adv. Polym. Sci., 3, 1, 1961.

    Article  CAS  Google Scholar 

  22. JB Enns, JK Gillham, J. Appl. Polym. Sci., 28, 2831, 1983.

    Article  CAS  Google Scholar 

  23. W.G. Potter, Epoxide Resins, Illiffe, London, 1970.

    Google Scholar 

  24. W.W. Wright, Composites, 12, 201, 1981.

    Article  CAS  Google Scholar 

  25. FR Dammont, TK Kwei, J. Polym. Sci., 5, 761, 1967.

    Article  CAS  Google Scholar 

  26. O. Delatycki, JC Shaw, JG Williams, J. Polym. Sci., 7, 753, 1969.

    CAS  Google Scholar 

  27. R.G.C. Arridge, J.H. Speake, Polymer, 13, 44, 3 1972.

    Google Scholar 

  28. T. Hirai, DE Kline, J. Appl. Polym. Sci., 17, 31, 1973.

    Article  CAS  Google Scholar 

  29. JG Williams, J. Appl. Polym. Sci., 23, 3433, 1979.

    Article  CAS  Google Scholar 

  30. CW May, FE Weir, S.P.E. Trans., 2, (3), 201, 1962.

    Google Scholar 

  31. E.F. Cuddihy, J. Moacanin, J. Polym. Sci., A2, 8, 1637, 1970.

    Google Scholar 

  32. R.J. Young, Developments in Polymer Fracture-1, E.H. Andrews Ed., Applied Science, London, p. 183, 1979.

    Google Scholar 

  33. S. Yamini, RJ Young, J. Mater Sci., 14, 1609, 1979.

    Article  CAS  Google Scholar 

  34. R.J. Young, Developments in Reinforced Plastics-1, G. Pritchard Ed., Applied Science, London, p. 257, 1980.

    Google Scholar 

  35. A.J. Kinloch, R.J. Young, Fracture Behaviour of Polymers, Applied Science, London. p. 293, 1983.

    Google Scholar 

  36. A.J. Kinloch, S.J. Shaw, D.A. Tod, D.L. Hunston, Polymer, 24, 1341, 1981.

    Article  Google Scholar 

  37. S.J. Shaw, The Fracture of Epoxy Resins and the Effects of Rubber Inclusions, Ph.D Thesis, City University, London, 1984.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1988 Plenum Press, New York

About this chapter

Cite this chapter

Shaw, S.J., Tod, D.A., Griffith, J.R. (1988). The Mechanical and Water Absorption Behaviour of Fluoroepoxy Resins. In: Lee, LH. (eds) Adhesives, Sealants, and Coatings for Space and Harsh Environments. Polymer Science and Technology, vol 37. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1047-1_4

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-1047-1_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8308-9

  • Online ISBN: 978-1-4613-1047-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics