Abstract
Cr(III) fumarato coordination compound is a successful coupling agent for aluminum-polyethylene adhesion. When an aluminum foil was pretreated with the Cr(III) fumarato coupling agent and coated with polyethylene, the aluminum-polyethylene composite films demonstrated extraordinary water-resistance and stability in chemically aggressive environments. The formation of chemical bonding between Cr(III) fumarato coordination compound and aluminum oxide was studied by Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS). The AES studies also demonstrated that the bonding between Cr(III) fumarato coordination compound and aluminum oxide was stable in water at room temperature, but underwent hydrolysis at elevated temperature.
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© 1988 Plenum Press, New York
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Yang, C.Q., Rusch, T.W., Clough, S.P., Fateley, W.G. (1988). The Bonding and Hydrolysis of the Cr (III) Fumarato Coupling Agent on Aluminum Surfaces Studied by Auger Electron Spectroscopy and X-Ray Photoelectron Spectroscopy. In: Lee, LH. (eds) Adhesives, Sealants, and Coatings for Space and Harsh Environments. Polymer Science and Technology, vol 37. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1047-1_14
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DOI: https://doi.org/10.1007/978-1-4613-1047-1_14
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