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Kinetic Processes in Electrolyte Solutions in High Frequency Electric Fields

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Chemical Reactivity in Liquids

Summary

High frequency permittivity measurements (1 to 40 GHz) are analyzed to yield information on kinetic processes in aqueous and nonaqueous electrolyte solutions. Information is obtained on the low and high frequency relaxation times of the solvent and their shifts by addition of electrolytes, rotational relaxation times of ion pairs, association constants, rate constants of ion-pair formation and decomposition, and kinetic depolarization. Examples are given for each process.

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Author information

Authors and Affiliations

  1. Institut für Physkalische und Theoretische Chemie der Universität Regensburg, Federal Rebulic of Germany

    J. Barthel, K. Bachhuber & R. Buchner

Authors
  1. J. Barthel
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  2. K. Bachhuber
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  3. R. Buchner
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Editor information

Editors and Affiliations

  1. Pierre and Marie Curie University, Paris, France

    Michel Moreau  & Pierre Turq  & 

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© 1988 Plenum Press, New York

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Barthel, J., Bachhuber, K., Buchner, R. (1988). Kinetic Processes in Electrolyte Solutions in High Frequency Electric Fields. In: Moreau, M., Turq, P. (eds) Chemical Reactivity in Liquids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1023-5_4

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  • DOI: https://doi.org/10.1007/978-1-4613-1023-5_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8297-6

  • Online ISBN: 978-1-4613-1023-5

  • eBook Packages: Springer Book Archive

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